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At least 19 records

Electric field gradients at rubidium sites in rubidium uranyl nitrate and quadrupole moments of 85 Rb and 87 Rb

The electronic structure along the axial direction of the uranyl ion in rubidium uranyl nitrate (RbUO 2 (NO 3 ) 3 ) has been studied by nuclear quadrupole resonance and nuclear magnetic resonance measurements of 85 Rb and 87 Rb quadrupole couplings. Here, the parameter of interest in these experiments is the electric field gradient at the Rb sites, which may be compared with values com- puted by various theoretical approaches. From this analysis an accurate ratio of the quadrupole moments of 85 Rb and 87 Rb has also been obtained.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Sporadic History of Rubidium and its Role in Corrosion of Steel Related to Nuclear Material Storage

The influence of rubidium (Rb), both in its metallic and oxidized states, on the corrosion resistance of steels has direct relevance to the storage of radioactive Kr-85 containing nuclear materials. Kr-85 undergoes a ß-decay to generate stable, metallic Rb. The literature to date is sparse, contained primarily in company reports and divisive as to whether Rb metal, or its oxides, can lead to corrosion of steel materials. In both the direct storage of Kr-85 and used nuclear fuel that will contain Kr-85, if Rb is corrosive then continual decay of the Kr-85 will generate an increasingly corrosive environment for the steel canister it is stored in. This review was written to consolidate the known data to date on Rb corrosion of steels to identify consistencies, contradictions and remaining gaps in our understanding of the Rb : steel system.

krypton, corrosion, steel, Rubidium↗

Phase equilibria and crystal chemistry of rubidium niobates and rubidium tantalates

The phase equilibria relations and crystal chemistry of portions of the Rb2O-Nb2O5 and Rb2O-Ta2O5 systems were investigated for structures potentially useful as ionic conductors. A hexagonal tungsten bronze-type (HTB) structure was found in both systems as well as three hexagonal phases with mixed HTB-pyrochlore type structures. Ion exchange experiments between various alkali ions are described for several phases. Unit cell dimensions and X-ray diffraction powder patterns are reported.

Minor, D. B.↗

Observations on the Reliability of Rubidium Frequency Standards on Block 2/2A GPS Satellites

Currently, the block 2/2A Global Positioning System (GPS) satellites are equipped with two rubidium frequency standards. These frequency standards were originally intended to serve as the back-ups to two cesium frequency standards. As the constellation ages, the master Control Station is forced to initialize and increasing number or rubidium frequency standards. Unfortunately the operational use of these frequency standards has not lived up to initial expectations. Although the performance of these rubidium frequency standards has met and even exceeded GPS requirements, their reliability has not. The number of unscheduled outage times and the short operational lifetimes of the rubidium frequency standards compare poorly to the track record of the cesium frequency standards. Only a small number of rubidium frequency standards have actually been made operational. Of these, a large percentage have exhibited poor reliability. If this trend continues, it is unlikely that the rubidium frequency standards will help contribute to the navigation payload meeting program specification.

Dieter, Gary L.↗

Operational stability of rubidium and cesium frequency standards

In the course of testing various rubidium and cesium frequency standards under operational conditions for use in NASA tracking stations, about 55 unit-years of relative frequency measurements for averaging times from 10 to 10 to the 7th power have been accumulated at Goddard Space Flight Center (GSFC). Statistics on the behavior of rubidium and cesium standards under controlled laboratory conditions have been published, but it was not known to what extent the lesser controlled environments of NASA tracking stations affected the performance of the standards. The purpose of this report is to present estimates of the frequency stability of rubidium and cesium frequency standards under operational conditions based on the data accumulated at GSFC.

Lavery, J. E.↗

Discovery of interstellar rubidium

Interstellar rubidium is detected through observations of the resonance line of Rb I at 7800 A towards zeta Oph. The abundance ratio of rubidium to potassium is estimated to be approximately solar, and if rubidium is generally found to have an abundance similar to potassium, it is indicated that the local interstellar medium is well mixed with a wide variety of the products of nucleosynthesis.

Jura, M.↗

Radiation hardness of Efratom M-100 rubidium frequency standard

The effects of nuclear radiation on rubidium gas cell frequency standards and components are presented, including the results of recent tests where a continuously operating rubidium frequency standard (Effratom, Model M-100) was subjected to simultaneous neutron/gamma radiation. At the highest neutron fluence 7.5 10 to the 12th power n/sq cm and total dose 11 krad(Si) tested, the unit operated satisfactorily; the total frequency change over the 2 1/2 hour test period due to all causes, including repeated retraction from and insertion into the reactor, was less than 1 x 10 to the -10th power. The effects of combined neutron/gamma radiation on rubidium frequency standard physics package components were also studied, and the results are presented.

English, T. C.↗

On-orbit frequency stability analysis of the GPS NAVSTAR-1 quartz clock and the NAVSTARs-6 and -8 rubidium clocks

An on-orbit frequency stability performance analysis of the GPS NAVSTAR-1 quartz clock and the NAVSTARs-6 and -8 rubidium clocks is presented. The clock offsets were obtained from measurements taken at the GPS monitor stations which use high performance cesium standards as a reference. Clock performance is characterized through the use of the Allan variance, which is evaluated for sample times of 15 minutes to two hours, and from one day to 10 days. The quartz and rubidium clocks' offsets were corrected for aging rate before computing the frequency stability. The effect of small errors in aging rate is presented for the NAVSTAR-8 rubidium clock's stability analysis. The analysis includes presentation of time and frequency residuals with respect to linear and quadratic models, which aid in obtaining aging rate values and identifying systematic and random effects. The frequency stability values were further processed with a time domain noise process analysis, which is used to classify random noise process and modulation type.

Mccaskill, T. B.↗

The physics of the environmental sensitivity of rubidium gas cell atomic frequency standards

Environmental sensitivity is often the most significant limitation to the practical stability of rubidium frequency standards (RFS). For example, temperature sensitivity can cause a rapid frequency change of several parts in 10(exp 10) for a tactical RFS that has an aging of only 1 times 10(exp -11)/month. Other important environmental factors are barometric pressure, vibration, magnetic field, and nuclear radiation. The physical mechanisms that lie behind these environmental sensitivities are considered. These physical mechanisms are related to the performance of actual rubidium frequency standards. For the user of these devices, a better knowledge of the causes for Rb clock instability will aid in their testing and proper application. For the time frequency specialist, a review of these factors may prove useful toward improving RFS design. Some of the RFS environmental sensitivities are due to simple physical mechanisms like the effect of dc magnetic field on the Rb hyperfine resonance frequency. For these, an analysis can be based on physical principles and straightforward design factors. Other environment factors, like temperature sensitivity, are more complex combinations of many effects, both physical and practical, and the analysis often takes the form of an error budget with large unit-to-unit variations. Today's rubidium frequency standards span a wide performance range from small, inexpensive units with pp 10(exp 10) error budgets to larger, higher performance versions offering pp 10(exp 10) stabilities. For both extremes, however, environmental sensitivity can be the most significant performance limitation. Why this is the case and how to make improvements are discussed.

Riley, William J.↗

High Pressure Synthesis of Rubidium Superhydrides

Through laser-heated diamond anvil cell experiments, we synthesize a series of rubidium superhydrides and explore their properties with synchrotron x-ray powder diffraction and Raman spectroscopy measurements, combined with density functional theory calculations. Upon heating rubidium monohydride embedded in H 2 at a pressure of 18 GPa, we form RbH 9 − I , which is stable upon decompression down to 8.7 GPa, the lowest stability pressure of any known superhydride. At 22 GPa, another polymorph, RbH 9 − II is synthesised at high temperature. Unique to the Rb-H system among binary metal hydrides is that further compression does not promote the formation of polyhydrides with higher hydrogen content. Instead, heating above 87 GPa yields RbH 5 , which exhibits two polymorphs ( RbH 5 − I and RbH 5 − II ). All of the crystal structures comprise a complex network of quasimolecular H 2 units and H − anions, with RbH 5 providing the first experimental evidence of linear H 3 − anions. Published by the American Physical Society 2025

Kuzovnikov, Mikhail A.↗

Operational frequency stability of rubidium and cesium frequency standards

The frequency stabilities under operational conditions of several commercially available rubidium and cesium frequency standards were determined from experimental data for frequency averaging times from 10 to the 7th power s and are presented in table and graph form. For frequency averaging times between 10 to the 5th power and 10 to the 7th power s, the rubidium standards tested have a stability of between 10 to the minus 12th power and 5 x 10 to the minus 12th power, while the cesium standards have a stability of between 2 x 10 to the minus 13th power and 5 x 10 to the minus 13th power.

Lavery, J. E.↗

A rubidium clock for GPS

The design objectives and approach; the more important design features; the signal parameters and error budget; and early test results in the development of a second-source rubidium frequency standard for use in the GPS navigation satellites are discussed. Tests of a breadboard version of the RFS show that the measured time-domain stability is within the goal specification. The results are uncorrected for the conribution of the reference and are probably limited by the reference stability in the medium term region. The Rb reference is bbetter in the medium term region, but the Cs reference is etter at 10,000 seconds and longer, probably because of the barometric sensitivity of the rubidium reference unit.

Riley, W. J.↗

A rubidium clock for SEEK-TALK

The development of a tactical rubidium frequency standard (TRFS) for the SEEK-TALK program is discussed. This effort, which is entering the prototype stage, is directed toward the establishment of a production capability for miniature rubidium clocks of medium stability capable of fast warmup and extreme ruggedness for military avionics applications. The overall unit consists of an ultraminiature physics package and four plug-in circuit boards inside a 2 1/2-inch square by 4-inch box. This size is achieved without the extensive use of hybrid microcircuitry, yet is believed to be the smallest atomic frequency standard yet developed.

Riley, W. J.↗

The Rubidium-Crystal Oscillator Hybrid Development Program

The rubidium-crystal oscillator hybrid (RbXO) will make precise time available to systems that lack the power required by atomic frequency standards. The RbXO consists of two subassemblies in separate enclosures. One contains a small rubidium frequency standard (RFS) without its internal oven-controlled crystal oscillator (OCXO), plus interface circuits. The second contains a low-power OCXO, and additional interface circuits. The OCXO is on continuously. Periodically, e.g., once a week, the user system applies power to the RFS. After the few necessary for the warmup of the RFS, the interface circuits adjust the frequency of the OCXO to the RFS reference, then shut off the RFS. The OCXO enclosure is separable from the RFS enclosure so that manpacks will be able to operate with minimum size, weight, and power consumption, while having the accuracy of the RFS for the duration of a mission. A prototype RbXO's RFS has operated successfully for 4200 on-off cycles. Parallel efforts on a Phase 2 RbXO development are in progress. Two sources for the RbXO are scheduled to be available during 1986.

Vig, J. R.↗

On the detection of rubidium in diffuse interstellar clouds

A search for absorption from neutral rubidium at 7800 A was conducted. No evidence for absorption to a 3 sigma limit of less than 1.5 mA was seen in the diffuse interstellar gas toward the stars omicron Persei, zeta Persei, and zeta Ophiuchi. Present results do not confirm the detection by Jura and Smith (1981) toward zeta Oph. A possible reason for the discrepancy is presented. In light of the present measurements, the abundance of interstellar rubidium in reconsidered.

Federman, S. R.↗

Rubidium atomic frequency standards for GPS Block IIR

The Rubidium Atomic Frequency Standards (RAFS) were provided for the GPS Block IIR NAVSTAR satellites. These satellites will replenish and upgrade the space segment of the Global Positioning System in the mid 1990s. The GPS RAFS Rb clocks are the latest generation of the high-performance rubidium frequency standards. They offer an aging rate in the low pp 10(exp 14)/day range and a drift-corrected 1-day stability in the low pp 10(exp 14) range. The Block IIR version of these devices will have improved performance, higher reliability, smaller size, and greater radiation hardness. The GPS Block IIR atomic clocks have a natural frequency configuration whereby they output a frequency of about 13.4 MHz that is a submultiple of the atomic resonance of Rb (or Cs). The RAFS operates at a low, fixed C-field for increased stability. The GPS Block IIR RAFS design, including the changes and improvements made, and the test results obtained are described.

Riley, William J.↗

Disciplined rubidium oscillator with GPS selective availability

A U.S. Department of Defense decision for continuous implementation of GPS Selective Availability (S/A) has made it necessary to modify Rubidium oscillator disciplining methods. One such method for reducing the effects of S/A on the oscillator disciplining process was developed which achieves results approaching pre-S/A GPS. The Satellite Hopping algorithm used in minimizing the effects of S/A on the oscillator disciplining process is described, and the results of using this process to those obtained prior to the implementation of S/A are compared. Test results are from a TrueTime Rubidium based Model GPS-DC timing receiver.

Dewey, Wayne P.↗