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Materials Data on PuIn by Materials Project

PuIn is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Pu is bonded to four equivalent Pu and eight equivalent In atoms to form PuPu4In8 cuboctahedra that share corners with twelve equivalent PuPu4In8 cuboctahedra, edges with eight equivalent PuPu4In8 cuboctahedra, edges with sixteen equivalent InPu8In4 cuboctahedra, faces with eight equivalent InPu8In4 cuboctahedra, and faces with ten equivalent PuPu4In8 cuboctahedra. All Pu–Pu bond lengths are 3.22 Å. All Pu–In bond lengths are 3.36 Å. In is bonded to eight equivalent Pu and four equivalent In atoms to form InPu8In4 cuboctahedra that share corners with twelve equivalent InPu8In4 cuboctahedra, edges with eight equivalent InPu8In4 cuboctahedra, edges with sixteen equivalent PuPu4In8 cuboctahedra, faces with eight equivalent PuPu4In8 cuboctahedra, and faces with ten equivalent InPu8In4 cuboctahedra. All In–In bond lengths are 3.22 Å.

36 MATERIALS SCIENCE↗

Materials Data on PuIn by Materials Project

PuIn crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pu is bonded to six equivalent Pu and six equivalent In atoms to form a mixture of distorted corner, edge, and face-sharing PuPu6In6 cuboctahedra. There are four shorter (3.31 Å) and two longer (3.47 Å) Pu–Pu bond lengths. There are four shorter (3.37 Å) and two longer (3.38 Å) Pu–In bond lengths. In is bonded in a 12-coordinate geometry to six equivalent Pu and six equivalent In atoms. There are four shorter (3.31 Å) and two longer (3.47 Å) In–In bond lengths.

36 MATERIALS SCIENCE↗