Materials Data on PtN4Cl2O by Materials Project
PtN4OCl2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Pt2+ is bonded in a square co-planar geometry to four equivalent N+0.50+ atoms. All Pt–N bond lengths are 1.96 Å. N+0.50+ is bonded in a 5-coordinate geometry to one Pt2+ and four equivalent Cl1- atoms. All N–Cl bond lengths are 2.53 Å. O2- is bonded in a 4-coordinate geometry to four equivalent Cl1- atoms. All O–Cl bond lengths are 2.88 Å. Cl1- is bonded in a 8-coordinate geometry to eight equivalent N+0.50+ and two equivalent O2- atoms.
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