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Results for “PtN4(ClO)2”

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DOE OSTI2020

Materials Data on PtN4(ClO)2 by Materials Project

Pt(N2OCl)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two platinum molecules and four N2OCl ribbons oriented in the (0, 1, 0) direction. In each N2OCl ribbon, N1+ is bonded in a distorted single-bond geometry to one O2- and one Cl1- atom. The N–O bond length is 1.39 Å. The N–Cl bond length is 2.13 Å. O2- is bonded in a water-like geometry to two equivalent N1+ atoms. Cl1- is bonded in a 2-coordinate geometry to two equivalent N1+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on PtN4(Cl2O)2 by Materials Project

PtCl2(N2)2(ClO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules, four nitrogen molecules, and two platinum(ii) chloride molecules.

36 MATERIALS SCIENCE↗