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Annual FEC-PTC Report - CDRL F.70

The U.S. Department of Energy (DOE) Idaho National Laboratory (INL) Site operates facilities with potential emissions of criteria and hazardous air pollutants. This report documents the calendar year 2021 criteria and hazardous air pollutants emissions and has been prepared to comply with permit to construct (PTC) P-2015.0023 for the period of 1-1-2021 up to the effective date of PTC P 2020.0045 (1-29-2021), and PTC P-2020.0045 for the period from 1-29-2021 through 12-31-2021. The Idaho Administrative Procedures Act (IDAPA) 58.01.01.178, Standard Contents of Permits Establishing a Facility Emissions Cap (FEC) requires that all permits establishing a FEC shall include sufficient reporting to assure compliance with the permit establishing the FEC. Total hazardous air pollutant (HAP) emissions for the year were 0.10 tons in aggregate and the maximum individual HAP was toluene at 0.04 tons. Criteria pollutant emissions were 0.75 tons for sulfur dioxide, 24.33 tons for oxides of nitrogen, 6.07 tons of carbon monoxide, 2.53 tons of total particulate matter and 0.99 tons of volatile organic compounds (VOC).

99 GENERAL AND MISCELLANEOUS↗

Selected Area Deposition of PtC x Nanostructures: Implications for Functional Coatings of 3D Nanoarchitectures

Here, we report that selected area deposition of 3D nanostructures is induced via a pyrolytic laser chemical vapor deposition (CVD) process where selected area heating results from the unique photothermal transport regime that is intrinsic to 3D nanostructures. PtC x composite nanostructures were deposited by focused electron beam-induced deposition (FEBID) and used as 3D templates. Subsequent simultaneous localized delivery of an organometallic PtC x precursor and pulsed 915 nm laser irradiation to the pre-defined nanostructures results in selected area deposition on the FEBID features. Results indicate the ability to initiate the process on sub-diffraction-limit nanoscale features. To elucidate the mechanisms that are operative in the selected area deposition, we analyze the effects of the laser repetition rate, power, and pulse duration. Thermal simulations corroborate that the pseudo-1D thermal transport of the nanostructure geometry coupled with the optical and thermal properties of the nanostructure governs the CVD reaction. The results demonstrated here suggest that controlling the thermal transport in nanomaterial architectures could be a useful means to spatially control localized photothermally stimulated chemical reactions and induce selected area reactions.

36 MATERIALS SCIENCE↗

Materials Data on PtC by Materials Project

PtC is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pt2- is bonded in a body-centered cubic geometry to eight equivalent C2+ atoms. All Pt–C bond lengths are 2.44 Å. C2+ is bonded in a body-centered cubic geometry to eight equivalent Pt2- atoms.

36 MATERIALS SCIENCE↗

Materials Data on PtC by Materials Project

PtC is Tungsten Carbide structured and crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Pt2- is bonded to six equivalent C2+ atoms to form a mixture of distorted edge, face, and corner-sharing PtC6 pentagonal pyramids. All Pt–C bond lengths are 2.27 Å. C2+ is bonded to six equivalent Pt2- atoms to form a mixture of distorted edge, face, and corner-sharing CPt6 pentagonal pyramids.

36 MATERIALS SCIENCE↗

Materials Data on PtC by Materials Project

PtC is Zincblende, Sphalerite structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Pt2- is bonded to four equivalent C2+ atoms to form corner-sharing PtC4 tetrahedra. All Pt–C bond lengths are 2.05 Å. C2+ is bonded to four equivalent Pt2- atoms to form corner-sharing CPt4 tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on PtC by Materials Project

PtC is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Pt2- is bonded to six equivalent C2+ atoms to form a mixture of edge and corner-sharing PtC6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Pt–C bond lengths are 2.24 Å. C2+ is bonded to six equivalent Pt2- atoms to form a mixture of edge and corner-sharing CPt6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

Organochlorine pesticides and risk of papillary thyroid cancer in U.S. military personnel: a nested case-control study

Background: The effects of organochlorine pesticide (OCP) exposure on the development of human papillary thyroid cancer (PTC) are not well understood. A nested case-control study was conducted with data from the U.S. Department of Defense Serum Repository (DoDSR) cohort between 2000 and 2013 to assess associations of individual OCPs serum concentrations with PTC risk. Methods: This study included 742 histologically confirmed PTC cases (341 females, 401 males) and 742 individually-matched controls with pre-diagnostic serum samples selected from the DoDSR. Associations between categories of lipid-corrected serum concentrations of seven OCPs and PTC risk were evaluated for classical PTC and follicular PTC using conditional logistic regression, adjusted for body mass index category and military branch to compute odds ratios (OR) and 95% confidence intervals (CIs). Effect modification by sex, birth cohort, and race was examined. Results: There was no evidence of associations between most of the OCPs and PTC, overall or stratified by histological subtype. Overall, there was no evidence of an association between hexachlorobenzene (HCB) and PTC, but stratified by histological subtype HCB was associated with significantly increased risk of classical PTC (third tertile above the limit of detection (LOD) vs. <LOD, OR = 1.61, 95% CI, 1.09, 2.38; p for trend = 0.05) and significantly decreased risk of follicular variant PTC (third tertile above the limit of detection (LOD) vs. <LOD, OR = 0.38, 95% CI, 0.16, 0.91; p for trend = 0.04). Further stratified by sex, risk of classical PTC was higher for females (third tertile above LOD vs. <LOD, OR = 2.23, 95% CI: 1.23, 4.06; p-trend = 0.02) than for males (OR = 1.22, 95%CI: 0.72–2.08; p-trend = 0.56), though the test for interaction by sex was not statistically significant (p-interaction = 0.30). Similarly, β-hexachlorocyclohexane (β-HCCH) was associated with a higher risk for classical PTC for women with concentrations ≥LOD versus <LOD (OR = 1.76, 95% CI: 1.07, 2.89), while the effects were null for men. There were no consistent trends when stratified by race or birth year. Conclusions: The U.S. Environmental Protection Agency has classified HCB and other OCPs we studied here as probable human carcinogens. Our findings of increased risks for classical PTC associated with increased concentrations of HCB and β-HCCH, which were stronger among females, should be replicated in future studies of other populations.

60 APPLIED LIFE SCIENCES↗

Implication of production tax credit on economic dispatch for electricity merchants with storage and wind farms

The production tax credit (PTC) promotes wind energy development, reduces power generation costs, and can affect merchants’ joint economic dispatch, particularly for electricity merchants with both energy storage and wind farms. Two common PTC policies are studied – in the first policy, a wind farm receives PTC by selling wind generation to the market and its storage can be used to store energy from the wind generation and energy purchased from the grid but the energy released from the storage cannot receive PTC; in the second policy, the energy released from the storage can also qualify for PTC but purchasing energy from the grid is not allowed. We then employ dynamic programming to study merchants' optimal decision-making while considering PTC and the physical characteristics of storage systems. We analytically show that the state of charge (SOC) range can be segmented into different regions by SOC reference points under two PTC policies. The merchant's optimal action can be conveniently and uniquely determined based on the region within which the current SOC falls. Moreover, this study illustrates that PTC could substantially alter the optimal scheduling policy structures by affecting reference points and their relationships. The results showed that the frequencies for charging and discharging storage decisions decreased with an increase in PTC subsidy. Last, we confirm that, although the first policy allows merchants to buy electricity from the market, the second policy can bring more profits when the PTC is large at the current PTC rates. Furthermore, the findings can provide multistage decision-making guidance to electricity merchants in the wholesale power market.

17 WIND ENERGY↗

Hydrokinetic energy harvesting from slow currents using flow-induced oscillations

To harness marine hydrokinetic energy from slow flows, which constitute the majority of currents, tides, and rivers, new Passive Turbulence Control (PTC), consisting of large turbulence stimulators, is tested experimentally on circular cylinders on springs. Here, this study experimentally investigates the effect of PTC on the onset of Flow-Induced Oscillations (FIO) and particularly the relative onset of Vortex-Induced Vibrations (VIV) and galloping. Experiments are conducted in the Low Turbulence Free Surface Water Channel, University of Michigan. Fixed are: mass ratio m* = 1.48, aspect ratio l/D = 10.29, and total damping ratio ζ = 0.04. Parameters are: cylinder diameter D, spring stiffness K, PTC location and height, and flow speed U$\in$[0.36 m/s-1.45 m/s]. Placing the leading edge of PTC at 40–60° induces high amplitude FIO while placement at 10–20° suppresses FIO. As PTC height increases, VIV and galloping initiate earlier and exhibit higher amplitude with a steeper slope. Lower spring stiffness initiates VIV earlier by reducing the oscillator natural frequency in water. Even though large PTC maintained its effectiveness in initiating galloping early, it has no effect on the earlier initiation of VIV, which starts at a nearly fixed reduced velocity. Lower spring stiffness and large PTC enable power generation at low current speed (0.2 m/s).

16 TIDAL AND WAVE POWER↗

Hydrokinetic energy conversion using flow induced oscillations of single-cylinder with large passive turbulence control

Various types of flow-induced oscillations (FIOs) have been implemented in development of marine hydrokinetic (MHK) energy converters. With passive turbulence control (PTC), energy harvesting starts at a flow speed of about 0.5 m/s. However, there is worldwide MHK energy available in even slower currents. In the present study, the effect of damping on FIO and power extraction is investigated for a converter with large turbulence stimulation (PTC) consisting of straight strips with a height of 15% of the cylinder diameter and placed symmetrically on the cylinder surface. The oscillating amplitude decreases, as the damping ratio increases, with unchanged sinusoidal pattern of the displacement time-history. The frequency ratio is also affected by damping especially in the VIV initial branch and transition region between VIV and galloping. An important flow characteristic of the large-PTC cylinder is that a recirculation region is formed behind the PTC, causing appreciable disturbance to the flow past the cylinder. Power can be harvested in the whole FIO range and the harnessed power maximum appears at the largest inflow velocity tested. However, the optimum of harnessing efficiency is located at the beginning of the VIV upper branch. The gap between VIV and galloping is bridged when large PTC is used, eliminating the drop in power and efficiency even at higher damping, which would be a weakness of regular-PTC cylinder for energy harvesting. Finally, the mechanism behind the variation of harnessing efficiency with inflow velocity and damping ratio is revealed, and the optimality criterion for the converter design is discussed.

16 TIDAL AND WAVE POWER↗

Effects of the U.S. inflation reduction act on SMR economics

The U.S. Inflation Reduction Act (IRA) of 2022 provides a wide array of tax credits and other incentives for low-carbon energy. The technology-neutral clean generation production tax credit (PTC) (Section 45Y of the U.S. Internal Revenue Code) and the technology-neutral investment tax credit (ITC) (Section 48E) lower the net cost of new electricity generation projects with zero or negative greenhouse gas emission rates. We evaluate the impact of the IRA legislation—specifically the PTC and ITC—on the cost-competitiveness of small modular reactors (SMRs). We use the Argonne Low-carbon Energy Analysis Framework (A-LEAF) model to calculate the capacity factor of an SMR with a range of hypothetical variable operating and maintenance (O&M) costs in the Electric Reliability Council of Texas (ERCOT) electricity market. We selected ERCOT for market modeling because of its competitive structure, available data, and extensive use in prior literature. We use a discounted cash flow model to calculate the SMR’s net present value based on the market prices and capacity factors from A-LEAF, hypothetical ranges of capital and variable O&M costs, and other input parameters, with or without the IRA tax credits. We determine the SMR owner’s optimal choice of PTC or ITC for the hypothetical ranges of capital and variable O&M costs. We also evaluate potential shifts in the SMR owner’s optimal choice of PTC or ITC based on historical patterns of nuclear capital cost overruns in the United States. We also assess the sensitivity of our results to longer PTC period and electricity prices from the New England market, which tend to be higher than electricity prices in ERCOT. We find that even with the IRA tax credits, only SMRs with low capital and variable O&M costs would be economically feasible in the low-price ERCOT market scenario modeled. A longer PTC period and higher-price market such as New England, however, would significantly expand the economic feasibility of SMRs in the United States.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quantifying Heavy Precipitation throughout the Entire Tropical Cyclone Life Cycle

Abstract Tropical cyclones (TCs) and their associated precipitation can have devastating impacts on the areas affected, with outcomes ranging from mudslides to inland flash flooding. Previous studies have used a fixed radius around the TC to isolate storm-related precipitation. One previous study instead used a dynamic radius of 8 m s −1 winds, but the wind field of the TC can deteriorate or shift quickly after landfall or the onset of extratropical transition (ET). This study uses a dynamical radius derived from the 500-hPa geopotential height in and around the TC to define TC- and post-tropical cyclone (PTC)-related heavy precipitation, allowing for the analysis of precipitation with tropical origins after the official demise of the original TC. Climatologies are constructed, indicating a maximum in TC- and PTC-related heavy precipitation in the west North Pacific and a secondary maximum in the east North Pacific. PTC-related heavy precipitation accounts for as much as 40% of the annual heavy precipitation in the northwest portion of the west North Pacific basin and 3.13% of heavy precipitation globally. We observe that the major hurricane stage contributes on average 2.6% of the global TC- and PTC-related precipitation, while the less intense but more common tropical storm stages of the TC life cycle contribute 85.7% of this observed precipitation. This analysis framework can be further extended to assess model biases and climate projections of TC and PTC precipitation.

Meteorology & Atmospheric Sciences↗

RTN-056: Study of the Photon Transfer Curve in the CCD detectors of the Vera C. Rubin Observatory

The RECA internship program provides Colombian students with an opportunity to enhance their research skills in Astronomy, Astrophysics, and Cosmology. During this three-month program, our main objective was to study the Photon Transfer Curves (PTC) of the Vera C. Rubin Observatory, specifically the gain, and to compare it with the gain obtained through pairs of flats. Overall, the study of PTCs is crucial in understanding the performance of detectors and instruments used in Astronomy. The Vera C. Rubin Observatory is an important facility that will enable researchers to carry out a wide range of studies in this field, making it essential to investigate its gain performance. We used run 13144 to construct the PTCs and 13186 to analyze the crosstalk. We employed the LSST Science Pipelines (also known as the DM stack), a software under development for this observatory, which performs all the necessary reductions for the construction of the PTCs. We also used simulations to replicate the observed effects. Initially, we found a 5% difference between the gain calculated by PTC and pairs of flats for a flow range between 5000 and 10000 ADU. Simulations showed that this difference was due to the handling of statistics and the assumption that the distribution following the Lupton equation is Gaussian. We found an error interval for this flow region based on the vendor, with (1.8 ± 0.7, 4.1 ± 0.9) % for E2V and (0.85 ± 0.7, 2.2 ± 0.9) % for ITL. From the PTC, we also obtained the average Full Well Capacity of LSSTCam as 130000 ± 10000$ electrons. We identified a list of segments where we found differences with the results obtained by SLAC National Acceleration Laboratory in PTC parameters, low saturation level, or other defects. We detected and corrected the effect of statistics in the gain calculation using pairs of flats and proposed a code change, which was implemented in the pipeline software. We do not recommend correcting for crosstalk as it does not significantly affect the parameters and does not change the shape of the PTC. However, the opposite is true for the nonlinearity correction.

79 ASTRONOMY AND ASTROPHYSICS↗

Wind-induced torsion of parabolic trough collectors in operation

Parabolic trough collector (PTC) systems, a type of concentrating solar power (CSP), use parabolic mirrors to reflect the sun's rays toward an absorber tube to heat the fluid inside. PTCs track the sun throughout the day and are sensitive to angular misalignment, which reduces optical performance. Torsion of the PTC, exacerbated by wind loading, contributes to angular misalignment, which has been quantified by previous studies using numerical simulations and experimental tests. However, angular misalignment due to torsion and wind loading has not yet been studied in an operational plant, which can experience more extreme and variable conditions. This study characterizes the angular misalignment due to torsion at three rows of the Nevada Solar One CSP plant and investigates the influence of wind loading. These findings reveal substantial torsion along the PTC support structure that depends on wind conditions and orientation. Strong winds perpendicular to the PTCs increase the median angular displacement of the outermost row by up to 18 mrad and increase the standard deviation by up to 8 mrad when compared to weak wind conditions. These findings can inform enhanced PTC design, controls and modeling that will improve the performance, reliability and bankability of future CSP plants.

14 SOLAR ENERGY↗

The Poisson tensor completion non-parametric differential entropy estimator

We introduce the Poisson tensor completion (PTC) estimator, a non-parametric differential entropy estimator. The PTC estimator leverages inter-sample relationships to compute a low-rank Poisson tensor decomposition of the frequency histogram. Our crucial observation is that the histogram bins are an instance of a space partitioning of counts and thus can be identified with a spatial Poisson process. The Poisson tensor decomposition leads to a completion of the intensity measure over all bins—including those containing few to no samples—and leads to our proposed PTC differential entropy estimator. A Poisson tensor decomposition models the underlying distribution of the count data and guarantees non-negative estimated values and so can be safely used directly in entropy estimation. Our estimator is the first tensor-based estimator that exploits the underlying spatial Poisson process related to the histogram explicitly when estimating the probability density with low-rank tensor decompositions for the purpose of tensor completion. Furthermore, we demonstrate that our PTC estimator is a substantial improvement over standard histogram-based estimators for sub-Gaussian probability distributions because of the concentration of norm phenomenon.

42 ENGINEERING↗

JGI Plant Transformation Workshop, May 20-21, 2025

Domestic biomass crops such as sorghum, switchgrass, Miscanthus, and poplar can provide United States industries with renewable feedstocks while also supporting low-input farming systems and strengthening supply chains for biofuels, biochemicals and biomaterials. The U.S. leads globally in biomass crop genomics, yet progress in engineering traits is constrained by slow, genotype-dependent transformation methods and lengthy Design-Build-Test-Learn (DBTL) cycles. At a May 2025 workshop, a panel of experts recommended establishing a DOE Plant Transformation Capability (PTC) to overcome these barriers. The PTC would unite two missions: advancing research to achieve genotype-independent, automated methods, and delivering scalable transformation services through a user-facility model. With expected gains of 10–100x in efficiency, including transformation and cost reduction, the PTC would accelerate the path from discovery to engineered plants, expand community access and training, and support downstream applications and workflows including field trials and regulatory navigation. By enabling rapid and predictable crop engineering, the PTC would strengthen U.S. supply chains, enhance industrial competitiveness, and ensure that DOE’s genomic investments deliver national impact.

09 BIOMASS FUELS↗

Comparative analysis of thermal management systems in electric vehicles at extreme weather conditions: Case study on Nissan Leaf 2019 Plus, Chevrolet Bolt 2020 and Tesla Model 3 2020

With the surge in electric vehicle (EV) adoption and the need for extended driving ranges, optimizing energy efficiency, particularly through thermal management, is critical, especially in extreme weather. Managing the substantial energy needed for cabin climate control and battery temperature regulation can increase energy demands by over 50 %, severely limiting range. This study conducts a comparative analysis of thermal management systems (TMS) in three popular EV vehicles, 2020 Chevrolet Bolt, 2019 Nissan Leaf Plus, and 2020 Tesla Model 3, evaluating their distinct TMS configurations and performance under varied weather conditions. Using both numerical simulations and experimental data collected on a controlled test bench at Argonne National Laboratory, we assess how TMS architecture and operational modes influence energy consumption and range. A comprehensive TMS model was developed, integrating cabin and battery thermal sub-models in the Autonomie software platform, to simulate temperature fluctuations and range impacts. Cabin climate was modeled using a mono-zonal approach, while battery cell temperature distribution was estimated through a 2D nodal structure. Each vehicle's distinct TMS setup was evaluated: the Chevrolet Bolt and Tesla Model 3 use a dual evaporator vapor compression cycle with a PTC heater for the cabin and a coolant loop for battery thermal management; the Nissan Leaf Plus employs a heat pump with a PTC heater for the cabin and air-cooling for the battery. Tests conducted at ambient temperatures of 35°C, 22°C, -7°C, and -18°C reveal significant differences in energy use and range reduction across both configurations and conditions. At 35°C, the Tesla Model 3, Chevrolet Bolt, and Nissan Leaf Plus have a range reduction of 8%, 9%, and 13%, respectively, due to air conditioning. In winter, heating technology is paramount; at -7°C, the Nissan Leaf's heat pump configuration achieves a lower range reduction (19.3%) compared to the Tesla and Chevrolet Bolt PTC heaters, which reduce range by 28.3% and 31%, respectively. Further, this study provides valuable insights for automotive engineers, EV technology researchers, and thermal management system designers aiming to enhance electric vehicle performance by understanding how different weather conditions and TMS architectures impact energy consumption and driving range.

33 ADVANCED PROPULSION SYSTEMS↗