Results for “Pt(S3N)2”

Materials Data on Pt(S3N)2 by Materials Project

PtS6N2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four ammonia molecules and two PtS6 clusters. In each PtS6 cluster, Pt2+ is bonded in a square co-planar geometry to four equivalent S2- atoms. All Pt–S bond lengths are 2.30 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in an L-shaped geometry to two equivalent S2- atoms. Both S–S bond lengths are 2.03 Å. In the second S2- site, S2- is bonded in an L-shaped geometry to one Pt2+ and one S2- atom.