THE USE OF A PROTON-PROTON SPIN DECOUPLING METHOD FOR THE DETERMINATION OF NUCLEAR MAGNETIC RESONANCE CHEMICAL SHIFTS
Proton-proton spin decoupling method for the determination of nuclear magnetic chemical shifts
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Proton-proton spin decoupling method for the determination of nuclear magnetic chemical shifts
Description of an experimental method for the determination of the longitudinal relaxation time for spin-decoupled protons by a modified version of the saturation recovery technique reported by Van Geet and Hume (1965). The described method should facilitate relaxation studies of chemically shifted protons (or fluorines) and can be applied to more complicated spin systems with the aid of triple resonance and noise-decoupling techniques.
Electron spin resonance transitions involving simultaneous changes in spin states of two neighboring protons
The proton spin lattice relaxation times and Knight shifts were measured in f.c.c. (delta-phase) and f.c.t. (epsilon-phase) ZrH/sub x/ for 1.5 or = to x or = to 2.0. Both parameters indicate that N(E/sub F/) is very dependent upon hydrogen content with a maximum occurring at ZrH1 83. This behavior is ascribed to modifications in N(E/sub F/) through a fcc/fct distortion in ZrH/sub x/ associated with a Jahn-Teller effect.
Results of experiments to confirm a theory that links classical electromagnetism with the geometry of spacetime are described. The theory, based on the introduction of a Torsion tensor into Einstein s equations and following the approach of Schroedinger, predicts effects on clocks attached to charged particles, subject to intense electric fields, analogous to the effects on clocks in a gravitational field. We show that in order to interpret this theory, one must re-interpret all clock changes, both gravitational and electromagnetic, as arising from changes in potential energy and not merely potential. The clock is provided naturally by proton spins in hydrogen atoms subject to Nuclear Magnetic Resonance trials. No frequency change of clocks was observed to a resolution of 6310(exp -9). A new "Clock Principle" was postulated to explain the null result. There are two possible implications of the experiments: (a) The Clock Principle is invalid and, in fact, no metric theory incorporating electromagnetism is possible; (b) The Clock Principle is valid and it follows that a negative rest mass cannot exist.
The absence of experimental data in the literature concerning a viscosity difference for normal and equilibrium liquid hydrogen may be attributed to the limited reproducibility of "oscillating disk" measurements in a liquid-hydrogen environment. Indeed, there is disagreement over the viscosity values for equilibrium liquid hydrogen even without proton spin considerations. Measurements presented here represent the first application of the piezoelectric alpha quartz torsional oscillator technique to liquid-hydrogen viscosity measurements.
Nuclear magnetic resonance spectra of vinyl protons of cyclopentadiene and cyclohexadiene from spin decoupling
Nuclear magnetic resonance (NMR) and relaxation studies of the proton spin-lattice relaxation time (PSLRT) and proton second moment (PSM) are reported. Tetramethylammonium cadmium chloride (TMCC) was selected as a diamagnetic member of the isomorphic series, and hence proton data relate directly to the motion of the tetramethylammonium ion in the absence of paramagnetic ions. In the model adopted, the correlation time for hindered motion of one of the methyl groups differs from that of the other three groups in the low-temperature phase below 104 K. PSLRT and PSM values agree closely with experimental data with this model. Crystallographic phase transitions in TMCC occur at 104 K and 119 K according to the PSLRT measurements. Dipolar interactions between adjacent protons account for the PSLR rates below 104 K.
Proton spin-lattice relaxation time in dilute liquid and gas solutions of orthohydrogen in parahydrogen, noting dependence on temperature, density and composition
Long lived radicals produced in crystalline ribonuclease and lysozyme by 120-Mev protons studied by ESR spectroscopy
Geminal and vicinal proton-proton couplings - nuclear magnetic resonance spin-spin coupling
Atomic resonance and scattering - magnetic moment of proton and spin-exchange scattering
Both proton and fluorine nuclear spin-lattice relaxations have been studied by the 180- to 90-deg pulse method in magnesium fluosilicate hexahydrate at 25 and 13 MHz over the temperature range from 170 to 350 K. Observed nonexponential behavior of the nuclear magnetic relaxation is explained by internal rotations of the doubly charged negative fluosilicate ions and doubly charged positive magnesium hexahydrate ions.
Discussion of proton flux data recorded for 32 samples per spin period by two solid state proton detectors and a three-axis fluxgate magnetometer aboard Explorer 45 which was launched from Kenia into a 220-km-to-5.24 earth radius orbit. The occurrence of an amplifier saturation effect in the presence of high energy protons is noted. Diagrams are included for proton intensities, proton differential flux vs altitude in six energy bands, evolution of proton differential energy spectra through a steep gradient region, omnidirectional fluxes vs altitude, and plasma densities.
NMR spin-spin coupling constants between vinyl protons in cyclopentadiene, 1,3-cyclohexadiene and 1-3-cyclooctadiene from spectrum analysis
General covariance and maximum four-dimensional Yang-Mills gauge symmetry lead to these results: (1) gravity is characterized by a dimensionless constant F of the order of 10 to the -19th; (2) the Newtonian force is always attractive; (3) space-time has a torsion; and (4) gravitational spin-force between two protons is about 10 to the 19th times stronger than the corresponding Newtonian force. A possible experimental test is discussed.
The far-infrared laser magnetic resonance spectrum of the SiH radical in the v = O level of its X2Pi state has been recorded. The signals are rather weak. The molecules were generated in the reaction between fluorine atoms and SiH4. Rotational transitions have been detected in both 2Pi1/2 and 2Pi3/2 spin components but no fine structure transitions between the spin components were observed. Proton hyperfine splittings were resolved on some lines. The measurements have been analyzed, subjected to a least-squares fit using an effective Hamiltonian, and the appropriate molecular parameters determined. The weakness of the spectrum and the failure of attempts to power saturate favorable lines are both consistent with a small value for the electric dipole moment for SiH.
Polarization difference in elastic scattering of proton from Ar 40 and Ca 40 due to spin-orbit force difference