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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Meson Spectroscopy at CLAS and CLAS12: the Present and the Future

Mesons are the simplest quark bound system, being made by a quark and an anti-quark pair. Studying their structure and properties is a fundamental step to reach a deep understanding of QCD. For this purpose both a precise determination of the meson spectrum for conventional states and the search for states beyond the simple qq-bar configurations, as hybrids (qqg) or glueballs, are needed. Finding evidence for these unconventional states would help in understanding some of the open issues in hadronic physics, as how the quarks are confined within hadrons and what is the role of gluons. These topics are presently studied with the CLAS detector at Jefferson Lab and will be studied with the novel CLAS12 experiment after the 12 GeV upgrade of the facility. In my talk I will present the physics program that is presently in progress and the future perspectives.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Carbon-Based Metal-Free ORR Electrocatalysts for Fuel Cells: Past, Present, and Future

Replacing precious platinum with earth-abundant materials in fuel cells for oxygen reduction reaction (ORR) has been the objective worldwide for several decades. In last ten years, the carbon-based metal-free ORR electrocatalysts is the fastest-growing branch in this area. Great progresses have been made in promoting the performance and understanding the underlying ORR process. This article presents a comprehensive review of this filed by emphasizing on the emerging issues such as the design and controllable construction of porous structures and doping configurations, mechanistic understanding from the model catalysts and the combined experimental and theoretical studies, and more importantly, the performance evaluation in a full cell. Centering these topics, the most up-to-date results are presented, along with the remarks and perspectives for the future development of carbon-based metal-free ORR electrocatalysts.

Yang, Lijun↗

Searches for New Physics: Les Houches Recommendations for the Presentation of LHC Results

We present a set of recommendations for the presentation of LHC results on searches for new physics, which are aimed at providing a more efficient flow of scientific information between the experimental collaborations and the rest of the high energy physics community, and at facilitating the interpretation of the results in a wide class of models. Implementing these recommendations would aid the full exploitation of the physics potential of the LHC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Zero-Valent Iron: Impact of Anions Present during Synthesis on Subsequent Nanoparticle Reactivity

Zero-valent iron particles are an effective remediation technology for ground water contaminated with halogenated organic compounds. In particular, nanoscale zero-valent iron is a promising material for remediation because of its high specific surface area, which results in faster rate constants and more effective use of the iron. An aspect of iron nanoparticle reactivity that has not been explored is the impact of anions present during iron metal nanoparticle synthesis. Solutions containing chloride, phosphate, sulfate, and nitrate anions and ferric ions were used to generate iron oxide nanoparticles. The resulting materials were dialyzed to remove dissolved by-products and then dried and reduced by hydrogen gas at high temperature. The reactivity of the resulting zero-valent iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform yield were observed. The reactivity of nanoparticles prepared in the presence of sulfate and phosphate demonstrated the highest reactivity and chloroform yield. Furthermore, substantial variations in the solid-state products of oxidation (magnetite, iron sulfide, goethite, etc.) were also observed.

42 ENGINEERING↗

The present and future status of heavy neutral leptons

Abstract The existence of nonzero neutrino masses points to the likely existence of multiple Standard Model neutral fermions. When such states are heavy enough that they cannot be produced in oscillations, they are referred to as heavy neutral leptons (HNLs). In this white paper, we discuss the present experimental status of HNLs including colliders, beta decay, accelerators, as well as astrophysical and cosmological impacts. We discuss the importance of continuing to search for HNLs, and its potential impact on our understanding of key fundamental questions, and additionally we outline the future prospects for next-generation future experiments or upcoming accelerator run scenarios.

Abdullahi, Asli M.↗

This report provides data, analysis, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic University of America (VSL) to determine the melter processing rates that are achievable with RPP-WTP HLW simulants. The principal findings were presented earlier in a summary report (VSL-00R2S90-l) but the present report provides additional details.

This report provides data, analysis, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic University of America (VSL) to determine the melter processing rates that are achievable with RPP-WTP HLW simulants. The principal findings were presented earlier in a summary report (VSL-00R2S90-l) but the present report provides additional details.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Dirac plasmons and beyond: the past, present, and future of plasmonics in 3D topological insulators

Here, we review progress studying unique plasmonics in topological insulators (TIs). First, we describe exfoliation and deposition synthesis approaches. TI materials have substantially improved: it is now possible to grow samples with few trivial electrons and controllable doping. We then describe the theory behind the unique behavior of the coupled, 2D Dirac plasmons. While reviewing experimental efforts, we note that Dirac plasmons have been conclusively demonstrated in TIs and they show remarkable properties including long lifetimes, large mode indices, and huge modulation depths. Finally, we describe the opportunities that are present now that high-quality materials can be obtained, including spin and nanoparticle plasmons.

36 MATERIALS SCIENCE↗

2014 Water Power Program Peer Review: Hydropower Technologies, Compiled Presentations (Presentation)

This document represents a collection of all presentations given during the EERE Wind and Water Power Program's 2014 Hydropower Peer Review. The purpose of the meeting was to evaluate DOE-funded hydropower and marine and hydrokinetic R&D projects for their contribution to the mission and goals of the Water Power Program and to assess progress made against stated objectives.

13 HYDRO ENERGY↗

2014 Water Power Program Peer Review: Marine and Hydrokinetic Technologies, Compiled Presentations (Presentation)

This document represents a collection of all presentations given during the EERE Wind and Water Power Program's 2014 Marine and Hydrokinetic Peer Review. The purpose of the meeting was to evaluate DOE-funded hydropower and marine and hydrokinetic R&D projects for their contribution to the mission and goals of the Water Power Program and to assess progress made against stated objectives.

13 HYDRO ENERGY↗

Nuclear Data Uncertainty Quantification: Past, Present and Future

An historical overview is provided of the mathematical foundations of uncertainty quantification and the roles played in the more recent past by nuclear data uncertainties in nuclear data evaluations and nuclear applications. Significant advances that have established the mathematical framework for contemporary nuclear data evaluation methods, as well as the use of uncertainty information in nuclear data evaluation and nuclear applications, are described. This is followed by a brief examination of the current status concerning nuclear data evaluation methodology, covariance data generation, and the application of evaluated nuclear data uncertainties in contemporary nuclear technology. A few possible areas for future investigation of this subject are also suggested.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Most theoretical approaches used in nuclear astrophysics to model the nucleosynthesis of heavy elements incorporate the so-called statistical model in order to describe the excitation and decay properties of atomic nuclei. One of the basic assumptions of this model is the validity of the Brink–Axel hypothesis and the related concept of so-called photon strength functions to describe γ-ray transition probabilities. We present a novel experimental approach that allows for the first time to experimentally determine the photon strength function simultaneously in two independent ways by a unique combination of quasi-monochromatic photon beams and a newly implemented γ–γ coincidence setup. This technique does not assume a priori the validity of the Brink–Axel hypothesis and sets a benchmark in terms of the detection sensitivity for measuring decay properties of photo-excited states below the neutron separation energy. The data for the spherical off-shell nucleus 128 Te were obtained for γ-ray beam-energy settings between 3 MeV and 9 MeV in steps of 130 keV for the lower beam energies and in steps of up to 280 keV for the highest beam settings. We present a quantitative analysis on the consistency of the derived photon strength function with the Brink–Axel hypothesis. The data clearly demonstrate a discrepancy of up to a factor of two between the photon strength functions extracted from the photoabsorption and photon emission process, respectively. In addition, we observe that the photon strength functions are not independent of the excitation energy, as usually assumed. Thus, we conclude, that the Brink–Axel hypothesis is not strictly fulfilled in the excitation-energy region below the neutron separation threshold (S n = 8.78 MeV) for the studied case of 128 Te.

Not Available

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Chemical Challenges that the Peroxide Dianion Presents to Rechargeable Lithium–Air Batteries

Understanding the fundamental redox reactions and processes that occur in lithium–air and, more generally, metal–air batteries is important to the progress of this promising energy-storage technology. Knowledge of the chemistry of the peroxide dianion, O 2 2– , is especially crucial, as the dianion is at the nexus of the charge/discharge cycle of lithium–air batteries. The intrinsic electron transfer properties and redox chemistry of peroxide dianion are poorly defined because it is difficult to isolate the dianion free of protons and metal ions. We review the results of (i) the electron transfer kinetics and (ii) the redox reaction chemistry of isolated peroxide dianion encapsulated within the cavity of a hexacarboxamide cryptand. With regard to the former, electron transfer kinetics measurements provide fundamental Marcus parameters that will be useful for models that seek to disentangle the precise contributions of Li + ion-coupled electron transfer, electron transfer across the Li 2 O 2 solid particle interface, and charge hopping among Li 2 O 2 particles. With regard to the latter, an underappreciated chemistry of peroxide dianion with CO 2 produces peroxymonocarbonate (OOCO 2 2– ) and peroxydicarbonate (O 2 COOCO 2 2– ). An autocatalytic cycle will lead to oxidative degradation of traditional organic electrolytes and other vulnerable cell components employed in lithium–air batteries. Furthermore, this peroxycarbonate-derived chemistry, in addition to more commonly recognized solution-based oxidation chemistry, will need to be mitigated to realize the long-term cyclability of rechargeable lithium–air batteries.

25 ENERGY STORAGE↗

Global energetics and local physics as drivers of past, present and future monsoons

Global constraints on momentum and energy govern the variability of the rainfall belt in the intertropical convergence zone and the structure of the zonal mean tropical circulation. The continental-scale monsoon systems are also facets of a momentum- and energy-constrained global circulation, but their modern and palaeo variability deviates substantially from that of the intertropical convergence zone. The mechanisms underlying deviations from expectations based on the longitudinal mean budgets are neither fully understood nor simulated accurately. We argue that a framework grounded in global constraints on energy and momentum yet encompassing the complexities of monsoon dynamics is needed to identify the causes of the mismatch between theory, models and observations, and ultimately to improve regional climate projections. In a first step towards this goal, disparate regional processes must be distilled into gross measures of energy flow in and out of continents and between the surface and the tropopause, so that monsoon dynamics may be coherently diagnosed across modern and palaeo observations and across idealized and comprehensive simulations. Accounting for zonal asymmetries in the circulation, land/ocean differences in surface fluxes, and the character of convective systems, such a monsoon framework would integrate our understanding at all relevant scales: from the fine details of how moisture and energy are lifted in the updrafts of thunderclouds, up to the global circulations.

54 ENVIRONMENTAL SCIENCES↗