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Materials Data on PrSn3 by Materials Project

PrSn3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pr is bonded to twelve equivalent Sn atoms to form a mixture of corner and face-sharing PrSn12 cuboctahedra. All Pr–Sn bond lengths are 3.39 Å. Sn is bonded in a distorted square co-planar geometry to four equivalent Pr atoms.

36 MATERIALS SCIENCE↗

Materials Data on Pr3Sn by Materials Project

Pr3Sn is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pr is bonded in a distorted square co-planar geometry to four equivalent Sn atoms. All Pr–Sn bond lengths are 3.54 Å. Sn is bonded to twelve equivalent Pr atoms to form a mixture of face and corner-sharing SnPr12 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on PrSn2 by Materials Project

PrSn2 is Zirconium Disilicide-like structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. Pr is bonded in a 10-coordinate geometry to ten Sn atoms. There are a spread of Pr–Sn bond distances ranging from 3.26–3.62 Å. There are three inequivalent Sn sites. In the first Sn site, Sn is bonded in a 4-coordinate geometry to six equivalent Pr and two equivalent Sn atoms. Both Sn–Sn bond lengths are 3.15 Å. In the second Sn site, Sn is bonded in a distorted square co-planar geometry to four equivalent Pr and four equivalent Sn atoms. All Sn–Sn bond lengths are 3.27 Å. In the third Sn site, Sn is bonded in a distorted square co-planar geometry to four equivalent Pr and four equivalent Sn atoms.

36 MATERIALS SCIENCE↗

Materials Data on Pr5Sn3 by Materials Project

Pr5Sn3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. there are two inequivalent Pr sites. In the first Pr site, Pr is bonded in a 6-coordinate geometry to six equivalent Sn atoms. All Pr–Sn bond lengths are 3.37 Å. In the second Pr site, Pr is bonded in a 5-coordinate geometry to five equivalent Sn atoms. There are a spread of Pr–Sn bond distances ranging from 3.22–3.68 Å. Sn is bonded in a 9-coordinate geometry to nine Pr atoms.

36 MATERIALS SCIENCE↗

Materials Data on Pr3Sn5 by Materials Project

Pr3Sn5 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Pr sites. In the first Pr site, Pr is bonded in a 9-coordinate geometry to nine Sn atoms. There are a spread of Pr–Sn bond distances ranging from 3.20–3.59 Å. In the second Pr site, Pr is bonded in a 10-coordinate geometry to ten Sn atoms. There are a spread of Pr–Sn bond distances ranging from 3.32–3.61 Å. There are three inequivalent Sn sites. In the first Sn site, Sn is bonded in a 5-coordinate geometry to five Pr and four Sn atoms. There are two shorter (3.09 Å) and two longer (3.28 Å) Sn–Sn bond lengths. In the second Sn site, Sn is bonded in a 6-coordinate geometry to six Pr and four Sn atoms. There are two shorter (3.09 Å) and one longer (3.12 Å) Sn–Sn bond lengths. In the third Sn site, Sn is bonded in a 9-coordinate geometry to six Pr and three Sn atoms.

36 MATERIALS SCIENCE↗