Materials Data on Pr(PPd)2 by Materials Project
PrPd2P2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Pr is bonded in a 8-coordinate geometry to eight equivalent Pd and eight equivalent P atoms. All Pr–Pd bond lengths are 3.27 Å. All Pr–P bond lengths are 3.17 Å. Pd is bonded to four equivalent Pr and four equivalent P atoms to form a mixture of distorted corner, edge, and face-sharing PdPr4P4 cuboctahedra. All Pd–P bond lengths are 2.50 Å. P is bonded in a 9-coordinate geometry to four equivalent Pr, four equivalent Pd, and one P atom. The P–P bond length is 2.27 Å.