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Powder River Basin CORE-CM: Advancing Strategies for Carbon Ore, Rare Earth Element, and Critical Mineral Resource Development in the Nation's Largest Coal Producing Basin
Since its introduction in the late 1800s, Elaeagnus augustifolia (Russian olive) has become a widespread invasive shrub that poses a threat to native riparian species in the United States by competing with native riparian plants for space and resources. To date, limited information on the distribution of Russian olive in the Powder River Basin of Montana and Wyoming have hampered management efforts and decision making. Here, we detect and model the distribution of Russian Olive using field surveys, ocular sampling, and variables from Landsat 8 Operational Land Imager (OLI), Sentinel-2 MultiSpectral Instrument (MSI), and Shuttle Radar Topography Mission (SRTM) using the Random Forest algorithm. We derived topographic, spectral, and hydrological variables from Landsat 8 OLI, Sentinel-2 MSI, and SRTM to utilize as model inputs. The team was able to successfully create a spectral Russian olive detection map for the Powder River Basin (RMSE =15.44%, R2 = 0.6482). The team also examined change in stream channel geomorphology from 1984-2020 in a time-series analysis using Landsat visible imagery and the RivMap MATLAB package and found little change. Our results will help our partners at the Powder River County Weed Board, Gay Ranch, United States Geological Survey, and University of Northern Colorado to locate and prioritize areas for riparian habitat restoration and to understand the region’s hydrology and geomorphology.
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The Powder River Basin (PRB) Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) project is part of the Department of Energy sponsored CORE-CM initiative focused on domestic production of critical minerals and promoting economic development in traditionally fossil fuel producing basins. An important part of this project is regional assessment of waste streams and development of basinal strategies for waste stream reuse within the critical minerals (CM) supply chain. The availability of water for all parts of the CM supply chain is of particular concern in the arid mountain west. In the Wyoming PRB, average annual production of produced water (PW) by the oil and gas industry is more than 16 billion gallons (2015-2022). Through published data and engagement with industry partners, we conducted a preliminary investigation of PW in the PRB to understand volumes, quality, and the potential for use in the CM supply chain. PW was assessed for potential as a direct feedstock and for use in CM processing of a variety of conventional and unconventional feedstocks, including ore from the Bear Lodge Alkaline Complex, coal, and coal byproducts. Preliminary findings suggest that PRB PW contains significantly lower concentrations of rare earth elements (REE) and lithium than would be considered economic at this time. For example, concentrations of REE+Sc measured in PRB PW are <1 ppb (DE-EE0007603), and only seven PRB PW samples reported in the USGS PW database had lithium concentrations ≥50 ppm. However, enrichment of CM in residual brine and sludge from PW evaporation and solidification treatment ponds may yield concentrations of interest over a pond lifetime and should be considered in future studies. Coal bed methane (CBM) PW accounted for 42% of all PW in the Wyoming PRB in 2022. Compared to non-CBM PW, PRB CBM water quality generally meets standards allowing surface discharge and reuse in local industries such as livestock. CBM PW may help to fill water needs within the CM supply chain. Understanding the distribution of CBM PW that is discharged versus reused will help develop basinal reuse strategies.
Project update presentation for Powder River Basin CORE-CM project
The objective of this paper is to assess how well completion practices and well performance have evolved over time (“time slices”) in the tight sands and shales of the Powder River Basin (PRB). This information can provide a foundation for helping operators define more effective well completion practices and thus optimize well performance in an emerging “tight oil” basin. To start, the authors assembled a “database” containing well completion practices, production data, and geologic information for more than 800 horizontal (Hz) wells targeting three “tight oil” formations -- Turner, Frontier, and Mowry--placed on production in the past dozen years. To control for the impact of geologic and reservoir properties on well performance, the authors defined 12 geologically distinct areas (“partitions”) for the Turner, Frontier, and Mowry Shale in the Powder River Basin (4 partitions in each formation). This paper discusses the methodology for establishing “time slices” for each partition within each of the three “tight oil” formations, including (1) taking out, to the extent practical, the effects of geology by partitioning the three “tight oil” formations based on their geologic parameters; (2) using type curves and estimated ultimate recoveries (EURs) to establish a reliable measure of well performance; and (3) rigorously inspecting the production and well completion data to assure a quality dataset. Partition #2, a high thermal maturity area of the Frontier Sandstone in the western Powder River Basin, helps illustrate the results of the study. Using a dataset of 55 Hz wells, the study found that well performance has steadily improved, with oil EURs increasing from 180 MBbl in 2012-13 to 290 MBbl in 2018-19. Much of this improvement was due to the use of longer Hz laterals, increasing notably from 3,765 ft in 2012-13 to 10,260 ft in 2018-19. More intensive completion practices contributed, as well. For example, the number of frac stages more than doubled, from 17 to 35, and proppant concentrations increased from 1,060 lbs/ft to 1,320 lbs/ft. Finally, the data show diminishing returns to longer laterals and more intensive completion practices. For example, the key performance measure of oil EUR per 1,000 ft of lateral is decreasing. For 2012-13, Hz wells recovered 50 MBbl of oil per 1,000 ft of lateral while the more recent 2018-19 Hz wells only provide 30 MBbl of oil per 1,000 ft of lateral. Considerable insight can be gained by using “time slices” and geologic partitioning to better understand the relationship between changes in well drilling and completion practices and changes in well performance in emerging “tight oil” plays. The results from this study can also serve as a foundation for subsequent, more intense efforts involving data analytics for defining more optimum well completion practices targeting specified geologic settings and formations.
Project update presentation for the Powder River Basin CORE-CM project
The Enhanced Oil Recovery Institute (EORI) has completed a map of thermal maturity of the Mowry Shale in the Powder River Basin (PRB). Thermal maturity, the degree to which the total organic carbon in a formation has been transformed from kerogen to producible hydrocarbons due to heat and pressure, is an important measure for not just the quality of a source rock, but also helps for delineating areas more favorable for unconventional drilling. There is a dearth of published Mowry maturity maps available for the PRB and this publication endeavors to provide a detailed map based on a large, public data set covering the Wyoming portion of the PRB. Additional data, currently held confidential by operators in the basin, would be of benefit to future iterations of this map.
The Enhanced Oil Recovery Institute (EORI) has completed a map of thermal maturity of the Mowry Shale in the Powder River Basin (PRB). Thermal maturity, the degree to which the total organic carbon in a formation has been transformed from kerogen to producible hydrocarbons due to heat and pressure, is an important measure for not just the quality of a source rock, but also helps for delineating areas more favorable for unconventional drilling. There is a dearth of published Mowry maturity maps available for the PRB and this publication endeavors to provide a detailed map based on a large, public data set covering the Wyoming portion of the PRB. Additional data, currently held confidential by operators in the basin, would be of benefit to future iterations of this map.
The project established a Tight Oil Field Laboratory to address technical challenges in developing stacked unconventional reservoirs in the Powder River Basin. Key activities included data compilation, subsurface mapping, drilling, logging, coring, deployment of fiber optics and microseismic, completion and stimulation optimization, and well performance evaluation.
Recent demand for coal as a thermal energy source has decreased significantly and will likely continue to decrease as renewable sources of energy become more available and environmental concern and cost from burning coal makes it more costly than renewables. Given that Powder River Basin (PRB) coal in Wyoming has relatively low thermal energy, it is critical for Wyoming to employ coal in other capacities at the current energy transition period in history. Among many potential non-thermal applications, PRB coal can be utilized for membrane and electrode applications through the formation of carbon fibers. Coal-derived membranes can become low-cost, conductive membranes for use in electrodialysis separation processes. Carbon fiber derived electrodes have been shown be a cost-effective alternative to typical electrode materials that can meet or exceed the performance of current carbon electrode materials. In this talk, we demonstrate the manufacture of supercapacitor electrodes from Powder River Basin (PRB) coal-derived precursors. Specifically, PRB coal was treated in cheap solvents, partitioned into liquid extract and solid residue. An electropinning process has been developed that can convert either the liquid extract or the solid residue into carbon fiber mats. The electrospinning process is versatile with many tunable process parameters to achieve desirable physiochemical properties. For example, the coal residue can be manipulated by additional heat treatment, or by adding binders, salts, or surfactants to create a solution that can be electrospun into advanced carbon electrodes with desirable structural and surface properties. Similarly, some of the liquid extract (tar fraction) can be subsequently reacted with toluene diisocyanate to create resinous coal-derived polyurethane (PUs) as a spinnable ink. Carbon nanofiber mats made from our proprietary electrospinning process were further carbonized at temperature ranging from 700°C to 900°C before they are used as electrodes in supercapacitors. Galvanostatic charge-discharge (GCD) results show that the best performing PU fiber mats can deliver a specific capacitance of 604 F g -1 at the current density of 1 A g -1 . A carbon fiber mat from a different solvent extraction residue also delivered the specific capacitance of 508 F g -1 . These specific capacitance values are comparable to or better than commercial activated carbons, demonstrating the viability of manufacturing carbon nanofiber electrodes from coal without the use of a commercial polymer as binder in the spinning ink.
Radiometric and meteorological data acquired at three ground stations located approximately 150 km apart in the Powder River Basin, Wyoming, are summarized. The data were collected between July 10 and July 29, 1978, to support the HCMM thermal satellite data acquired during this time period. The parameters measured are direct solar radiance, total solar radiance, sky radiance, air temperature, relative humidity, wind speed, and wind direction. A tabulation of the measurement accuracies is presented.
Examination of a fly ash derived from the combustion of a low-S, subbituminous Powder River Basin coal by Scanning Electron Microscopy (SEM) and High-resolution Transmission Electron Microscopy (HRTEM), both supplemented by Energy-dispersive X-ray spectroscopy (EDS), showed that the fly ashes were dominated by amorphous phases, Ca-rich plagioclase feldspars, Mg-rich phases, complex Ca-Mg-Al-Si-Ti-Fe grains, and trace amounts of REE-rich particles. Many of the particles were rimmed by a Ca-S, possibly a sulfate. HRTEM-EDS examination of a REE-rich particle proved it to be a mix of light- and heavy-rare earth minerals mixed with amorphous phases.
Increasing demand for a more robust domestic supply of rare earth elements (REE) and critical minerals (CM) has led to significant investigation into unconventional sources. Coal and coal byproducts from the Powder River Basin (PRB) of Wyoming are potential sources of REE but lack complete characterization of mineral hosts including ion-adsorption clays (IACs). IACs, which provide a substantial portion of the global REE supply, form when hydrated REE complexes are physiosorbed to negatively charged sites on clay surfaces. Typical IAC minerals include kaolinite, illite, and smectite. REE complexes are easily leached from IACs via ion exchange, making them economically attractive. However, research regarding the partitioning behaviors of strategic metals into PRB coal-hosted clays is limited. This project aims to quantify the modes of occurrence and distribution of REE and CM in clay minerals derived from PRB coals. Strategic metals investigated in this project have historic production or promising deposits within the PRB and/or high anticipated supply risk, and include: REE (lanthanides and Y), V, Ti, platinum group elements (PGE; Pt, Pd, Rh, Ru, Ir, Os), Al, Co, Ga, Zr, and W. Semi-quantitative compositional data from portable x-ray fluorescence spectroscopy (pXRF) on coal core from the PRB is consistent with the known correlation between REE and Al content, suggesting increased REE abundance will be found in clay-rich units. pXRF data also identifies elevated V, Ti, Co, and Zr correlated with Al. Preliminary x-ray diffraction (XRD) data indicates kaolinite, illite, and dickite are abundant minerals in overburden and clay-rich partings. Quantitative analysis via inductively coupled plasma mass spectrometry (ICP-MS) provides insights into REE and CM fractionation in coals as we compare trace metal occurrence to variations in mineralogy. Additionally, we apply scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS) data to correlate clay size and morphology to trace metal occurrence. Our findings supplement a broader effort to couple REE and CM extraction with existing domestic coal production and contribute to the fundamental understanding of adsorption processes that occur in low-temperature basin environments.
Increasing demand for a more robust domestic supply of rare earth elements (REE) and critical minerals (CM) has led to significant investigation into unconventional sources. Coal and coal byproducts from the Powder River Basin (PRB) of Wyoming are potential sources of REE and CM. The association between strategic metals and their mineral hosts has important implications for extractability. Samples of overburden, underclays, and clay-rich partings were selected for analysis from core and bucket samples from three PRB coal mines. Quartz, illite, and kaolinite-group minerals are abundant in clay-rich portions of the PRB coal strata. We performed a five-step sequential extraction to constrain critical metal partitioning in samples of overburden and underclays (n=10). Unlike the occurrences of REE in other clay deposits, insignificant amounts of total REE + Y (TREY) were recovered in the ion-exchangeable fraction (< 0.5 ppm). A significant amount of TREY was leached from the acid-soluble fraction by 0.1M HCl, suggesting REE may be tied up within crystal lattices rather than sorbed to clay surfaces. The acid-soluble fraction contained between 3 and 250 ppm TREY, with an average TREY concentration of 60 ppm. Relative standard deviations for each extraction step were generally < ±10%. Whole-rock samples (n=72) contained greater TREY enrichment in overburden than in underclays and partings, however, the opposite is true for other CM, such as Ti and V. Other locations in the PRB show different enrichment trends. Our findings supplement a broader effort to couple REE and CM extraction with existing domestic coal production and contribute to the fundamental understanding of how these metals concentrate in low-temperature basin environments.
Coal and associated sediments are potential sources of Rare Earth Elements (REE) and other critical minerals necessary for many consumer and defense-related products and development of energy technologies. For this study, 15 samples were sourced from Dry Fork Mine within the Powder River Basin near Gillette, Wyoming, to determine REE content along with select transition metals (t-metals) of interest in non-combusted coals and associated sediments. An excavator collected samples along a mine highwall, within benched intervals representing a foot to a few feet of coal strata. Homogenized sample subsets were crushed in an aluminum-ceramic vial, then passed through a 106-micron sieve. Sieved samples were pyrolyzed by a LECO TGA-108, which concurrently measured sample moisture, volatile, and ash content. Residual ash was then fused into a glass bead with lithium metaborate at a 6:1 Li-metaborate to sample ratio and then dissolved in 20% nitric acid. The nitric acid solutions containing digested beads were then diluted and passed through a 0.45 micron syringe filter. Filtered samples were analyzed by ICP-MS for REE and select t-metals. Reagent blanks were analyzed to assess for any potential contamination. Total REE plus Y (REE+Y) concentrations across the 15 samples range from 52 ppm to 1015 ppm with an average of 477 ppm on a dry ash basis. When normalized to upper continental crust (UCC; Taylor and McLennan, 1985) values, 13 of the 15 samples show average enrichment factors (EF) for REE+Y greater than 1. EF values indicate M-type enrichment (Sm through Er), as opposed to distinct preferential enrichment of light or heavy REE. T-metals with the highest average concentrations are V, Cu, Ni, and Zr at 215, 243, 123, and 118 ppm, respectively. Multiple t-metals had EF>1; however, Cu, Ge, and Sb have the highest average EF relative to UCC for t-metals, at 9.7, 8.0, and 17.0, respectively.
The demand for Rare Earth Elements (REE) and other critical minerals (CM) required for consumer products, defense-related applications, and low-carbon energy technology is increasing rapidly. Unconventional sources of REE/CM, such as coal and associated sediments, could prove very important in building resilient and ethical energy supply chains. Utilization of existing infrastructure and the highly trained energy workforce in traditionally coal-producing regions in emerging REE/CM industries could provide an economic boost to coal communities. The Powder River Basin (PRB) of Wyoming and Montana, USA, is a prime candidate to investigate the feasibility of extracting REE/CM from coal and associated sediments. The PRB hosts thick (>50 ft) coal seams that are mined at the surface and more than 40% of the coal produced in the US comes from the PRB. Geochemical data from multiple locations in PRB coal systems show REE enrichments at the top and bottom margins and at internal partings in coal seams. This trend is exhibited in two cores drilled at Peabody’s North Antelope Rochelle mine in the east central PRB, the largest coal mine in the world. The two cores include the Wyodak Anderson coal zone as well as the over- and underlying shale units. The Wyodak Anderson coal zone is part of the Paleocene Tongue River Member of the Fort Union Formation in which most of the coal resources in the PRB reside. To understand REE/CM enrichment, a total of 188 samples were analyzed for their major and trace element chemistry from both cores, sampled at one foot or smaller intervals. The two cores show distinct REE enrichments in the uppermost and lowermost 3 to 12 feet of the Wyodak Anderson coal zone, as well as enrichments in bounding carbonaceous shale units. Total REE+Y (REY) concentrations as high as 2510 ppm (all concentrations reported on an ash basis), or 15 times average upper continental crust values (Taylor and McLennan, 1995), were identified in the coal. Partings within the coal zone also show relative REE enrichment, with concentrations up to 485 ppm REY. The remaining interior portions of the coal zone contain lower concentrations of REE, resulting in an average REY for all samples from both cores of 288 ppm. The proportion of high-value critical REE (Nd, Eu, Tb, Dy, Er, Y) compared to REY averages 36%, which is higher than the critical REE proportion in average upper continental crust of 33%. This finding highlights the relative enrichment of middle REE compared to light REE, in contrast to many conventional REE deposits. Other critical trace elements that show enrichments above average upper continental crust include Ga, Nb, and V. Within this sample suite, Ga concentrations range from 2.8 to 213 ppm, with an average of 29 ppm; Nb from 2.9 to 166 ppm with an average of 26 ppm; and V from 27 to 1695 ppm with an average of 188 ppm. None of these trace elements exhibit the same distinct pattern of enrichment as REE in the upper and lower bounding layers and internal partings of the coal zone. Major element chemistry indicates CaO concentrations averaging ~25% in the coal samples from both cores, which has important implications for the extractability of REE from coal. Calcium-rich PRB coal has been shown to be more amenable to REE extraction than lower calcium coals by some methods (Stuckman et al., 2019; Taggart et al., 2016), highlighting the importance of REE extractability in addition to REE concentration in assessing the value of potential feedstocks. The original coal resource in the PRB is estimated at 1.16 trillion short tons (Luppens et al., 2015). Thus, the PRB represents an important potential unconventional source for REE and other CM. Ongoing research to fully characterize the REE/CM resource, identify enrichment mechanisms, and further develop and scale extraction technologies is necessary to understand the full potential of this resource.
Background/Objectives. Critical minerals (CM) are essential for numerous industrial and defense applications, including green technologies that will help to meet carbon emission reduction goals. Many CM are currently mined and processed in countries that lack stringent environmental and labor regulations. Unconventional sources such as existing industrial waste streams could play a part in building an ethical CM supply chain. Additionally, waste streams created in the extraction and processing of CM could be used for other industrial or commercial purposes, thereby reducing waste and advancing a circular economy. Approach/Activities. The Department of Energy funded Powder River Basin (PRB) CORE-CM project is exploring all aspects of the carbon ore, rare earth element (REE), and CM value chain, including the potential for extraction of CM from industrial waste streams in the basin. Waste streams that have potential as CM feedstocks are being inventoried to assess the concentration of CM in each waste stream and to estimate volume and accessibility. Although basin-specific technologies for extraction of CM are still in development, waste streams that may be produced during these processes are being cataloged and mapped to potential secondary uses. Results/Lessons Learned. Initial studies of the CM potential of PRB coal ash show that this waste stream contains concentrations of greater than 300 ppm total REE (Bagdonas et al., 2022, Renewable and Sustainable Energy Reviews). Moreover, calcium-rich PRB coal ash is amenable to REE extraction (Taggart et al., 2016, Environmental Science and Technology). Wyoming coal is shipped to 28 states, meaning that coal ash produced at power stations across the US represents a potential widespread resource for the extraction of REE. In addition to coal mining and coal fired electricity generation, the PRB is home to other energy industries including oil and gas production, in-situ uranium mining, and bentonite mining. Historically, precious and base metal mining has taken place on the perimeter of the PRB. Waste streams from these industries are currently being evaluated for their CM potential. Assessing the CM resource potential of waste streams could contribute to the development of an ethical CM supply chain. Results from these studies can be replicated for other waste streams, increasing the likelihood of successful creation of circular economies.