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The Spacelab Lyman alpha and white light coronagraphs program

The Harvard-Smithsonian Center for Astrophysics and the High Altitude Observatory have defined a joint coronagraphs experiment for a future Spacelab mission. The instrumentation package would include an ultraviolet light coronagraph to measure the intensity and profiles of spectral lines formed between 1.2 and 8 solar radii from sun center and a white light coronagraph to measure the intensity and polarization of visible light. The overall goals of the joint program are to use new coronal plasma diagnostic techniques to understand the physical processes and mechanisms operating in the solar corona, to understand the acceleration of high-speed and low-speed solar wind streams and to extrapolate this knowledge to other stars in order to help understand the physics of stellar coronae and stellar mass loss.

Kohl, J. L.

Intact capture of hypervelocity particles on Shuttle

The capability for capturing micrometeoroid analogs intact through laboratory simulations in passive underdense media offers a valuable tool for cosmic dust research. However, no amount of laboratory simulations can replace actual space experiments due to the technical inability to launch high fidelity analogs of micrometeoroids in ground laboratories and then reliably simulating high hypervelocities (greater than 7 km/s). Fluffy composite micrometeoroid analogs tend to break up and have not survived laboratory launches at beyond 4 km/s, however, a new technique of launching cluster analogs was developed for the two-stage light-gas gun at NASA Ames Vertical Gun Range. Plasma drag or electrostatic accelerators may be able to achieve higher speeds than two-stage light-gas guns but only with very limited projectile compositions and may result in severe projectile deformation. Consequently, a space demonstration of intact capture was sought since 1983. Initial results from our STS-47 flight, which carried the first Shuttle Sample Return Experiment (SRE) with silica aerogel capture media, are reported.

Tsou, P.

Advanced Propulsion Concepts at the Jet Propulsion Laboratory

Current interest in advanced propulsion within NASA and research activities in advanced propulsion concepts at the Jet Propulsion Laboratory are reviewed. The concepts, which include high power plasma thrusters such as lithuim-fueled Lorentz-Force-Accelerators, MEMS-scale propulsion systems, in-situ propellant utilization techniques, fusion propulsion systems and methods of using antimatter, offer the potential for either significantly enhancing space transportation capability as compared with that of traditional chemical propulsion, or enabling ambitious new missions.

advanced propulsion plasma thrusters

A Summary of the NASA Fusion Propulsion Workshop 2000

A NASA Fusion Propulsion Workshop was held on Nov. 8 and 9, 2000 at Marshall Space Flight Center (MSFC) in Huntsville, Alabama. A total of 43 papers were presented at the Workshop orally or by posters, covering a broad spectrum of issues related to applying fusion to propulsion. The status of fusion research was reported at the Workshop showing the outstanding scientific research that has been accomplished worldwide in the fusion energy research program. The international fusion research community has demonstrated the scientific principles of fusion creating plasmas with conditions for fusion burn with a gain of order unity: 0.25 in Princeton TFTR, 0.65 in the Joint European Torus, and a Q-equivalent of 1.25 in Japan's JT-60. This research has developed an impressive range of physics and technological capabilities that may be applied effectively to the research of possibly new propulsion-oriented fusion schemes. The pertinent physics capabilities include the plasma computational tools, the experimental plasma facilities, the diagnostics techniques, and the theoretical understanding. The enabling technologies include the various plasma heating, acceleration, and the pulsed power technologies.

Thio, Y. C. Francis

The average magnetic field draping and consistent plasma properties of the Venus magnetotail

The detailed average draping pattern of the magnetic field in the deep Venus magnetotail is examined. The variability of the data ordered by spatial location is studied, and the groundwork is laid for developing a coordinate system which measured locations with respect to the tail structures. The reconstruction of the tail in the presence of flapping using a new technique is shown, and the average variations in the field components are examined, including the average field vectors, cross-tail current density distribution, and J x B forces as functions of location across the tail. The average downtail velocity is derived as a function of distance, and a simple model based on the field variations is defined from which the average plasma acceleration is obtained as a function of distance, density, and temperature.

Mccomas, D. J.

Solar wind Acceleration from the Upper Chromosphere to the Corona in Coronal Hole Regions

The dynamic behavior of the plasma in the chromosphere/transition region /inner corona is vital for the acceleration of the solar wind. With new theoretical descriptions of the solar atmosphere and corona, and the increased observational possibilities provided by the SOHO spacecraft, it is possible to conduct an integrated study of the solar atmosphere and corona using observational and theoretical approaches. Over the past few years a series of observational techniques have been used to estimate the solar wind densities, temperatures and flow speed in the inner corona. These estimates suggest that the solar wind has higher outflow speeds in the inner corona and lower densities than previously assumed. A comparison with densities derived from atmospheric models support these lower densities.

Esser, Ruth

Experimental investigation of nozzle/plume aerodynamics at hypersonic speeds

Much of the work involved the Ames 16-Inch Shock Tunnel facility. The facility was reactivated and upgraded, a data acquisition system was configured and upgraded several times, several facility calibrations were performed and test entries with a wedge model with hydrogen injection and a full scramjet combustor model, with hydrogen injection, were performed. Extensive CFD modeling of the flow in the facility was done. This includes modeling of the unsteady flow in the driver and driven tubes and steady flow modeling of the nozzle flow. Other modeling efforts include simulations of non-equilibrium flows and turbulence, plasmas, light gas guns and the use of non-ideal gas equations of state. New experimental techniques to improve the performance of gas guns, shock tubes and tunnels and scramjet combustors were conceived and studied computationally. Ways to improve scramjet engine performance using steady and pulsed detonation waves were also studied computationally. A number of studies were performed on the operation of the ram accelerator, including investigations of in-tube gasdynamic heating and the use of high explosives to raise the velocity capability of the device.

Bogdanoff, David W.

Remote Sensing of Coronal Forces During a Solar Prominence Eruption

We present a new methodology—the Keplerian Optical Dynamics Analysis (KODA)—for quantifying the dynamics of erupting magnetic structures in the solar corona. The technique involves adaptive spatiotemporal tracking of propagating intensity gradients and their characterization in terms of time-evolving Keplerian areas swept out by the position vectors of moving plasma blobs. Whereas gravity induces purely ballistic motions consistent with Kepler's second law, noncentral forces such as the Lorentz force introduce nonzero torques resulting in more complex motions. KODA algorithms enable direct evaluation of the line-of-sight component of the net torque density from the image-plane projection of the areal acceleration. The method is applied to the prominence eruption of 2011 June 7, observed by the Solar Dynamics Observatory's Atmospheric Imaging Assembly. Results obtained include quantitative estimates of the magnetic forces, field intensities, and blob masses and energies across a vast region impacted by the postreconnection redistribution of the prominence material. The magnetic pressure and energy are strongly dominant during the early, rising phase of the eruption, while the dynamic pressure and kinetic energy become significant contributors during the subsequent falling phases. Measured intensive properties of the prominence blobs are consistent with those of typical active-region prominences; measured extensive properties are compared with those of the whole pre-eruption prominence and the post-eruption coronal mass ejection of 2011 June 7, all derived by other investigators and techniques. We show that KODA provides valuable information on spatially and temporally dependent characteristics of coronal eruptions that is not readily available via alternative means, thereby shedding new light on the environment and evolution of these solar events.

V M Uritskiy

Enabling a Larger Deep Space Mission Suite: A Deep Space Network Queuing Antenna for Demand Access

The advent of deep space small spacecraft, as exemplified by the Mars Cubesat One (MarCO), Lunar Trailblazer, Janus, the Escape and Plasma Acceleration and Dynamics Explorers (EscaPADE), and the thirteen Artemis 1 missions, opens the possibility that a much larger number of deep space spacecraft may be launched over the next 10 years and beyond. While scientifically exciting, the prospect of a (much) larger mission suite raises significant challenges for the current approach to ground stations and mission operations. We have been investigating an integrated approach for ground stations and missions operations to enable new modes of operation while maintaining the capabilities of the current operational techniques. This integrated approach is built around three core capabilities: (1) A queuing antenna that enables monitoring the status of a much larger number of spacecraft, and allows spacecraft to transmit requests for telemetry with NASA’s Deep Space Network (DSN); (2) a flexible scheduling system that expands the current DSN scheduling services to enable allocating time on DSN antennas in near real-time; and (3) a cloud-based ground data system that can be spun up and down according to how tracks are assigned by the flexible scheduling system. We shall show that an 18 meter DSN queuing antenna equipped with cyrogenic receivers would enable use of the DSN Demand Access Service for small spacecraft throughout the inner Solar System, thus providing service to a large mission suite. We first discuss the architecture of the queuing antenna and its supporting systems, including, for instance, the service required to generate the schedule for the queueing antenna (which dictates how it slews to monitor multiple spacecraft in a day of operations). Next, we describe the signaling scheme used to encode a request, which is inherited from the already operational DSN Beacon Tone Service, and describe two alternative ways to detect the incoming tone at the ground station, one based on maximum likelihood estimation (MLE), and another one based on Fast-Fourier Transfer (FFT) processing. We then use these results to estimate the maximum range at which a request can be reliably detected as a function of the spacecraft and ground station communication capabilities. Finally, the last part of this part of this paper briefly describes the prototyping effort undertaken at Morehead State University (MSU) and JPL to demonstrate the viability of this new DSN demand access. In particular, we describe the suite of tests conducted using MSU’s 21 meter ground station to validate its use a queuing antenna.

Mattle, Emily

Advanced space propulsion thruster research

Experiments showed that stray magnetic fields can adversely affect the capacity of a hollow cathode neutralizer to couple to an ion beam. Magnetic field strength at the neutralizer cathode orifice is a crucial factor influencing the coupling voltage. The effects of electrostatic accelerator grid aperture diameters on the ion current extraction capabilities were examined experimentally to describe the divergence, deflection, and current extraction capabilities of grids with the screen and accelerator apertures displaced relative to one another. Experiments performed in orificed, mercury hollow cathodes support the model of field enhanced thermionic electron mission from cathode inserts. Tests supported the validity of a thermal model of the cathode insert. A theoretical justification of a Saha equation model relating cathode plasma properties is presented. Experiments suggest that ion loss rates to discharge chamber walls can be controlled. A series of new discharge chamber magnetic field configurations were generated in the flexible magnetic field thruster and their effect on performance was examined. A technique used in the thruster to measure ion currents to discharge chamber walls is described. Using these ion currents the fraction of ions produced that are extracted from the discharge chamber and the energy cost of plasma ions are computed.

Wilbur, P. J.

Electric propulsion system technology

The work performed in fiscal year (FY) 1991 under the Propulsion Technology Program RTOP (Research and Technology Objectives and Plans) No. (55) 506-42-31 for Low-Thrust Primary and Auxiliary Propulsion technology development is described. The objectives of this work fall under two broad categories. The first of these deals with the development of ion engines for primary propulsion in support of solar system exploration. The second with the advancement of steady-state magnetoplasmadynamic (MPD) thruster technology at 100 kW to multimegawatt input power levels. The major technology issues for ion propulsion are demonstration of adequate engine life at the 5 to 10 kW power level and scaling ion engines to power levels of tens to hundreds of kilowatts. Tests of a new technique in which the decelerator grid of a three-grid ion accelerator system is biased negative of neutralizer common potential in order to collect facility induced charge-exchange ions are described. These tests indicate that this SAND (Screen, Accelerator, Negative Decelerator) configuration may enable long duration ion engine endurance tests to be performed at vacuum chamber pressures an order of magnitude higher than previously possible. The corresponding reduction in pumping speed requirements enables endurance tests of 10 kW class ion engines to be performed within the resources of existing technology programs. The results of a successful 5,000-hr endurance of a xenon hollow cathode operating at an emission current of 25 A are described, as well as the initial tests of hollow cathodes operating on a mixture of argon and 3 percent nitrogen. Work performed on the development of carbon/carbon grids, a multi-orifice hollow cathode, and discharge chamber erosion reduction through the addition of nitrogen are also described. Critical applied-field MPD thruster technical issues remain to be resolved, including demonstration of reliable steady-state operation at input powers of hundreds to thousands of kilowatts, achievement of thruster efficiency and specific impulse levels required for missions of interest, and demonstration of adequate engine life at these input power, efficiency, and specific impulse levels. To address these issues we have designed, built, and tested a 100 kW class, radiation-cooled applied-field MPD thruster and a unique dual-beam thrust stand that enables separate measurements of the applied- and self-field thrust components. We have also initiated the development of cathode thermal and plasma sheath models that will eventually be used to guide the experimental program. In conjunction with the cathode modeling, a new cathode test facility is being constructed. This facility will support the study of cathode thermal behavior and erosion mechanisms, the diagnosis of the near-cathode plasma and the development and endurance testing of new, high-current cathode designs. To facilitate understanding of electrode surface phenomenon, we have implemented a telephoto technique to obtain photographs of the electrodes during engine operation. In order to reduce the background vacuum tank pressure during steady-state engine operation in order to obtain high fidelity anode thermal data, we have developed and are evaluating a gas-dynamic diffuser. A review of experience with alkali metal propellants for MPD thrusters led to the conclusion that alkali metals, particularly lithium, offer the potential for significant engine performance and lifetime improvements. These propellants are also condensible at room temperature, substantially reducing test facility pumping requirements. The most significant systems-level issue is the potential for spacecraft contamination. Subsequent experimental and theoretical efforts should be directed toward verifying the performance and lifetime gains and characterizing the thruster flow field to assess its impact on spacecraft surfaces. Consequently, we have begun the design and development of a new facility to study engine operation with alkali metal propellants.

Brophy, John R.

Laboratory Plasma Source as an MHD Model for Astrophysical Jets

The significance of the work described herein lies in the demonstration of Magnetized Coaxial Plasma Gun (MCG) devices like CPS-1 to produce energetic laboratory magneto-flows with embedded magnetic fields that can be used as a simulation tool to study flow interaction dynamic of jet flows, to demonstrate the magnetic acceleration and collimation of flows with primarily toroidal fields, and study cross field transport in turbulent accreting flows. Since plasma produced in MCG devices have magnetic topology and MHD flow regime similarity to stellar and extragalactic jets, we expect that careful investigation of these flows in the laboratory will reveal fundamental physical mechanisms influencing astrophysical flows. Discussion in the next section (sec.2) focuses on recent results describing collimation, leading flow surface interaction layers, and turbulent accretion. The primary objectives for a new three year effort would involve the development and deployment of novel electrostatic, magnetic, and visible plasma diagnostic techniques to measure plasma and flow parameters of the CPS-1 device in the flow chamber downstream of the plasma source to study, (1) mass ejection, morphology, and collimation and stability of energetic outflows, (2) the effects of external magnetization on collimation and stability, (3) the interaction of such flows with background neutral gas, the generation of visible emission in such interaction, and effect of neutral clouds on jet flow dynamics, and (4) the cross magnetic field transport of turbulent accreting flows. The applicability of existing laboratory plasma facilities to the study of stellar and extragalactic plasma should be exploited to elucidate underlying physical mechanisms that cannot be ascertained though astrophysical observation, and provide baseline to a wide variety of proposed models, MHD and otherwise. The work proposed herin represents a continued effort on a novel approach in relating laboratory experiments to astrophysical jet observation. There exists overwhelming similarity among these flows that has already produced some fascinating results and is expected to continue a high pay off in future flow similarity studies.

Mayo, Robert M.

SOHO Ultraviolet Coronagraph Spectrometer (UVCS) Mission Operations and Data Analysis

The scientific goal of UVCS is to obtain detailed empirical descriptions of the extended solar corona as it evolves over the solar cycle and to use these descriptions to identify and understand the physical processes responsible for coronal heating, solar wind acceleration, coronal mass ejections (CMEs), and the phenomena that establish the plasma properties of the solar wind as measured by "in situ" solar wind instruments. This report covers the period from 15 November 1998 to 14 March 2001. During that time, UVCS observations have consisted of three types: 1) standard synoptic observations comprising, primarily, the H I Lycc line profile and the O VI 103.2 and 103.7 nm intensity over a range of heights from 1.5 to about 3.0 solar radii and covering 360 degrees about the sun, 2) sit and stare watches for CMEs, and 3) special observations designed by the UVCS Lead Observer of the Week for a specific scientific purpose. The special observations are often coordinated with those of other space-based and ground based instruments and they often are part of SOHO joint observation programs and campaigns. Lead observers have included UVCS Co-Investigators, Guest Investigators, scientists from the solar physics community and several graduate and undergraduate level students. UVCS has continued to successfully meet its goal of using powerful spectroscopic diagnostic techniques to obtain a much more detailed description of coronal structures than existed before the SOHO mission. The new descriptions of coronal structures from UVCS have inspired a large number of theoretical studies aimed at identifying the physical processes responsible for solar wind acceleration in coronal holes and streamers. UVCS has proven to be a very stable instrument. Stellar observations have demonstrated its stability and the analysis of coordinated observations with Spartan 201 have verified the accuracy of the absolute calibration and spectral resolution at H I Ly (alpha) line profile. UVCS has required no flight software modifications and all mechanisms are operational. The UVCS O VI Channel with its redundant optical path for wavelengths near H I Ly (alpha) is capable of observing the entire UVCS wavelength range. Since December 1998, the O VI Channel has been used for all UVCS observations. Although the H I Ly (alpha) Channel and detector are still operational, increases in the dark count up to about 5x 10(exp-4) counts/sec/pixel and an increase in high voltage current to within a factor of two of the maximum used in the laboratory before flight led to the decision to not use that detector at the present time. There is no significant science impact since the O VI Channel can observe nearly the same wavelength range.

Kohl, John L.

SOHO Ultraviolet Coronagraph Spectrometer (UVCS) Mission Operations and Data Analysis

The scientific goal of UVCS is to obtain detailed empirical descriptions of the extended solar corona as it evolves over the solar cycle and to use these descriptions to identify and understand the physical processes responsible for coronal heating, solar wind acceleration, coronal mass ejections (CMEs), and the phenomena that establish the plasma properties of the solar wind as measured by 'in situ' solar wind instruments. This report covers the period from 01 February 2002 to 15 February 2003. During that time, UVCS observations have consisted of three types: 1) standard synoptic observations comprising, primarily, the H I Ly alpha line profile and the O VI 103.2 and 103.7 nm intensity over a range of heights from 1.5 to about 3.0 solar radii and covering 360 degrees about the sun, 2) sit and stare watches for CMEs, and 3) special observations designed by the UVCS Lead Observer of the Week for a specific scientific purpose. The special observations are often coordinated with those of other space-based and ground-based instruments and they often are part of SOHO joint observation programs and campaigns. Lead observers have included UVCS Co-Investigators, scientists from the solar physics community and several graduate and undergraduate level students. UVCS has continued to achieve its purpose of using powerful spectroscopic diagnostic techniques to obtain a much more detailed description of coronal structures and dynamic phenomena than existed before the SOHO mission. The new descriptions of coronal mass ejections (CMEs) and coronal structures from UVCS have inspired a large number of theoretical studies aimed at identifying the physical processes responsible for CMEs and solar wind acceleration in coronal holes and streamers. UVCS has proven to be a very stable instrument. Stellar observations have demonstrated its stability. UVCS has required no flight software modifications and all mechanisms are operational. The UVCS O VI Channel with its redundant optical path for wavelengths near H I Ly alpha is capable of observing the entire UVCS wavelength range. Since December 1998, the O VI Channel has been used for all UVCS observations. Although the H I Ly alpha Channel and detector are still operational, increases in the dark count up to about 5 x 10(exp -4) counts/sec/pixel and an increase in high voltage current to within a factor of two of the maximum used in the laboratory before flight led to the decision to not use that detector at the present time. There is no significant decrease in the scientific capability of UVCS owing to the O VI channel redundant optical path. UVCS data, data analysis software, calibration files and the mission log are available from the SOHO archive and SAO. All UVCS data is now available to scientists and the general public via the SOHO Data Archive and SAO within three months of the observations. UVCS has resulted in 46 scientific papers in 2002. There were numerous presentations at scientific meetings. All requests for observation time by qualified outside users have been granted.

Kohl, John L.

SOHO Ultraviolet Coronagraph Spectrometer (UVCS) Mission Operations and Data Analysis

The scientific goal of UVCS is to obtain detailed empirical descriptions of the extended solar corona as it evolves over the solar cycle and to use these descriptions to identify and understand the physical processes responsible for coronal heating, solar wind acceleration, coronal mass ejections (CMEs), and the phenomena that establish the plasma properties of the solar wind as measured by "in situ" solar wind instruments. This report covers the period from 15 February 2003 to 14 April 2004. During that time, UVCS observations have consisted of three types: 1) standard synoptic observations comprising, primarily, the H I Lyalpha line profile and the 0 VI 103.2 and 103.7 nm intensity over a range of heights from 1.5 to about 3.0 solar radii and covering 360 degrees about the Sun, 2) sit and stare observations for major flare watches, and 3) special observations designed by the UVCS Lead Observer of the Week for a specific scientific purpose. The special observations are often coordinated with those of other space-based and ground-based instruments and they often are part of SOHO joint observation programs and campaigns. Lead observers have included UVCS Co-Investigators, scientists from the solar physics community and several graduate and undergraduate level students. UVCS has continued to achieve its purpose of using powerful spectroscopic diagnostic techniques to obtain a much more detailed description of coronal structures and dynamic phenomena than existed before the SOHO mission. The new descriptions of coronal mass ejections (CMEs) and coronal structures from UVCS have inspired a large number of theoretical studies aimed at identifying the physical processes responsible for CMEs and solar wind acceleration in coronal holes and streamers. UVCS has proven to be a very stable instrument. Stellar observations have demonstrated its radiometric stability. UVCS has not required any flight software modifications and all mechanisms are operational. The UVCS 0 VI Channel with its redundant optical path for wavelengths near H I Lyalpha is capable of observing the entire UVCS wavelength range. The regions of the detector currently being used require different grating angles for direct OVI observations and redundant path H I Lyalpha observations, and so those can no longer be observed simultaneously. Since December 1998, the 0 VI Channel has been used for all UVCS observations. Although the H I Lyalpha Channel and detector are still operational, increases in the dark count up to about 5x10(exp 4) counts/sec/pixel and an increase in high voltage current to within a factor of two of the maximum used in the laboratory before flight led to the decision to not use that detector after 1998. The visible light channel functioned nominally during the reporting period. UVCS data, data analysis software, calibration files and the mission log are available from the SOHO archive and SAO. All UVCS data are now available within three months of the observations to scientists and the general public via the SOHO Data Archive and SAO. UVCS has resulted in 33 scientific papers in 2003. There were numerous presentations at scientific meetings. UVCS Education and Public Outreach activities involved nine members of the UVCS team. During the reporting period, there were over a dozen events directed at students and teachers, museum audiences, and public audiences via the mass media, internet and educational literature.

Gurman, Joseph

Plasma Pressure in the Topside Ionosphere

A previous three year NASA-funded project resulted in the first 2-D maps of magnetotail pressure, density and temperature. A proposal to continue the work was declined, but modest funding was provided for one year to ramp down of the work. During the phase-out year, we used a time when 5 DMSP satellites were simultaneously active to produce the first instantaneous partial image of the magnetotail. The results have been submitted to the proceedings of the 1998 Huntsville Meeting on "The New Millennium Magnetosphere: Integrating Imaging, Discrete Observations and Global Simulations". A method of inferring central plasma sheet (CPS) temperature, density, and pressure from ionospheric observations was developed under a previous 3-year grant. These particles properties are calculated from data taken by particle instruments on DMSP satellites. Ion spectra occurring in conjunction with electron acceleration events are excluded. Because of the variability of magnetotail stretching, mapping to the plasma sheet was done using a modified Tsyganenko 1989 magnetic field model adjusted to agree with the actual magnetotail stretch. On May 25, 1997, five DMSP satellites (F10-F14) passed through the southern hemisphere nightside oval within a 19 minute period. Attached is the first magnetotail image, which results from applying our technique to that data set.

Newell, Patrick T.

Radiation from Relativistic Jets in Turbulent Magnetic Fields

Using our new 3-D relativistic electromagnetic particle (REMP) code parallelized with MPI, we have investigated long-term particle acceleration associated with an relativistic electron-positron jet propagating in an unmagnetized ambient electron-positron plasma. The simulations have been performed using a much longer simulation system than our previous simulations in order to investigate the full nonlinear stage of the Weibel instability and its particle acceleration mechanism. Cold jet electrons are thermalized and ambient electrons are accelerated in the resulting shocks. The acceleration of ambient electrons leads to a maximum ambient electron density three times larger than the original value. Behind the bow shock in the jet shock strong electromagnetic fields are generated. These fields may lead to the afterglow emission. We have calculated the time evolution of the spectrum from two electrons propagating in a uniform parallel magnetic field to verify the technique.

Nishikawa, K.-I.

New Method Developed To Purify Single Wall Carbon Nanotubes for Aerospace Applications

Single wall carbon nanotubes have attracted considerable attention because of their remarkable mechanical properties and electrical and thermal conductivities. Use of these materials as primary or secondary reinforcements in polymers or ceramics could lead to new materials with significantly enhanced mechanical strength and electrical and thermal conductivity. Use of carbon-nanotube-reinforced materials in aerospace components will enable substantial reductions in component weight and improvements in durability and safety. Potential applications for single wall carbon nanotubes include lightweight components for vehicle structures and propulsion systems, fuel cell components (bipolar plates and electrodes) and battery electrodes, and ultra-lightweight materials for use in solar sails. A major barrier to the successful use of carbon nanotubes in these components is the need for methods to economically produce pure carbon nanotubes in large enough quantities to not only evaluate their suitability for certain applications but also produce actual components. Most carbon nanotube synthesis methods, including the HiPCO (high pressure carbon monoxide) method developed by Smalley and others, employ metal catalysts that remain trapped in the final product. These catalyst impurities can affect nanotube properties and accelerate their decomposition. The development of techniques to remove most, if not all, of these impurities is essential to their successful use in practical applications. A new method has been developed at the NASA Glenn Research Center to purify gram-scale quantities of single wall carbon nanotubes. This method, a modification of a gas phase purification technique previously reported by Smalley and others, uses a combination of high-temperature oxidations and repeated extractions with nitric and hydrochloric acid. This improved procedure significantly reduces the amount of impurities (catalyst and nonnanotube forms of carbon) within the nanotubes, increasing their stability significantly. The onset of decomposition of the purified nanotubes (determined by thermal gravimetric analysis in air) is more than 300 C higher than that of the crude nanotubes. Transmission electron microscopy analysis of nanotubes purified by this method reveals near complete removal of iron catalyst particles. Analysis of the nanotubes using inductively coupled plasma spectroscopy revealed that the iron content of the nanotubes was reduced from 22.7 wt% in the crude nanotubes to less than 0.02 wt%. X-ray photoelectron spectroscopy revealed a decrease in iron content after purification as well as an increase in oxygen content due to the formation of carboxylic acid groups on the surface of the nanotubes. Nanotubes purified by this improved method can be readily dispersed in common organic solvents, in particular N,N-dimethylformamide, using prolonged ultrasonic treatment. These dispersions can then be used to incorporate single wall carbon nanotubes into polymer films.

Lebron, Marisabel