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At least 19 records

Isotopic evidence of enhanced carbonate dissolution at a coal mine drainage site in Allegheny County, Pennsylvania, USA

Stable isotopes were used to determine the sources and fate of dissolved inorganic C (DIC) in the circumneutral pH drainage from an abandoned bituminous coal mine in western Pennsylvania. The C isotope signatures of DIC (δ{sup 13}C{sub DIC}) were intermediate between local carbonate and organic C sources, but were higher than those of contemporaneous Pennsylvanian age groundwaters in the region. This suggests a significant contribution of C enriched in {sup 13}C due to enhanced carbonate dissolution associated with the release of H{sub 2}SO{sub 4} from pyrite oxidation. The Sr isotopic signature of the drainage was similar to other regional mine waters associated with the same coal seam and reflected contributions from limestone dissolution and cation exchange with clay minerals. The relatively high δ{sup 34}S{sub SO4} and δ{sup 18}O{sub SO4} isotopic signatures of the mine drainage and the presence of presumptive SO{sub 4}-reducing bacteria suggest that SO{sub 4} reduction activity also contributes C depleted in {sup 13}C isotope to the total DIC pool. With distance downstream from the mine portal, C isotope signatures in the drainage increased, accompanied by decreased total DIC concentrations and increased pH. These data are consistent with H{sub 2}SO{sub 4} dissolution of carbonate rocks, enhanced by cation exchange, and C release to the atmosphere via CO{sub 2} outgassing.

01 COAL, LIGNITE, AND PEAT↗

Stratigraphic control of landscape response to base-level fall, Young Womans Creek, Pennsylvania, USA [Caprock controls on landscape response to baselevel fall constrained by nested detrital in situ 10Be, Young Womans Creek, Pennsylvania, USA]

Landscapes are thought to respond to changes in relative base level through the upstream propagation of a boundary that delineates relict from adjusting topography. However, spatially-variable rock strength can influence the topographic expression of such transient landscapes, especially in layered rocks, where strength variations can mask topographic signals expected due to changes in climate or tectonics. Here, we analyze the landscape response to base-level fall in Young Womans Creek, a 220 km 2 catchment on the Appalachian Plateau, USA underlain by gently folded Paleozoic sedimentary rocks. We measured in situ 10 Be concentrations in stream sands from 17 nested watersheds, and used a spatially-distributed model of sediment and 10 Be production to constrain a threefold increase in the rate of base-level fall propagating upstream from the catchment outlet. Using lidar topography and a nearby detailed stratigraphic section, we map the extent of continuous, blocky, resistant sandstone strata that act as a caprock overlying more easily erodible sandstones and siltstones. The caprock influences landscape response in two ways. First, it serves as a boundary between slowly eroding (11.5 m Myr –1 ), low-sloping (3–5°) areas of relict topography and lower, steeper portions of the landscape adjusting to base-level fall. Second, hillslopes supported by the overlying caprock are armored with coarse sediment and are significantly steeper (20–30°) than hillslopes where the caprock has been eroded (10°), despite having similar erosion rates (36 m Myr –1 ) and bedrock substrate. Lastly, our results illustrate how gently dipping, layered rocks engender complicated relationships between lithology, topography and erosion rate, highlighting the importance of understanding how rock material properties influence surface processes and landscape evolution.

58 GEOSCIENCES↗

Results from an Aeromagnetic Survey to Detect Steel-Cased Wells at a Marcellus Shale Well Site in Washington County, Pennsylvania

Pennsylvania has a 150-year history of oil and gas production—the longest of any state—and this enduring activity has resulted in the drilling of more than 300,000 recorded wells. However, unknown wells likely exist because innumerable wells were drilled during Pennsylvania’s intense early oil and gas history when incomplete records were kept of well locations. There is concern that early wells are likely to be ineffectively sealed because there were no laws that required plugging when the wells were abandoned. Today, many undocumented and unplugged wells are thought to be in areas of emerging shale gas and shale oil development where open wellbores can provide a pathway for undesired upward migration of fluids and gas from hydraulically fractured reservoirs. Due to this concern, Pennsylvania regulators have asked operators to locate orphaned and abandoned wells within a 1,000-ft buffer of proposed new wells. The objective of this report is to demonstrate that high-resolution aeromagnetic surveys, historic air photos, and Light Detection and Ranging (LiDAR) imagery can be rapid and effective methods to reconnoiter large, forested areas of moderate terrain for the presence of abandoned wells. These well-finding methods were evaluated at a proposed Marcellus Shale gas drilling site in Washington County, Pennsylvania, where the methods collectively located 18 confirmed wells: 15 wells were identified from aeromagnetic surveys, two wells were identified from inspection of historical air photos, and one well was identified by evaluation of state-wide LiDAR imagery. Only six wells were previously known, and their locations, as recorded in Pennsylvania’s statewide oil and gas wells database (PA/IRIS/WIS), were often too inaccurate for the wells to be found in the dense underbrush. Twelve wells identified in this study were abandoned, unmarked, and undocumented. Aeromagnetic surveys locate wells by detecting the unique magnetic signature of vertical, steel well casing, which is depicted on magnetic maps as a “bull’s eye” type anomaly that is centered directly over the well. However, when wells were drilled and found to be sub-economic, their casing was sometimes pulled and salvaged for reuse. Such wellbores provide no magnetic response and go undetected if all casing was removed. Oftentimes attempts to retrieve well casing were not 100% successful. For example, historical records for one well in the study area indicate that the well was completed in 1902 as a dry hole and that, to the extent possible, the casing was pulled for reuse. However, a section of 10-in. diameter steel casing was not recovered and remains at an unknown depth in the wellbore. This well was easily detected by the aeromagnetic survey although only deep casing remained in the well. To mitigate for the likelihood that wellbores exist where most or all casing has been removed, this study augmented aeromagnetic data with historic air photos and digital terrain models generated from LiDAR datasets—both databases are publicly available at no cost for areas within Pennsylvania. These complementary methods located three wells where the aeromagnetic anomaly, although present, was subtle and overlooked. Together, these methods determined accurate locations for six known wells within the study area and located 12 previously unknown wells. Although it is not certain that these methods successfully located all wells in the study area, the application of these methods does represent a significant improvement over relying on existing databases for well locations. For the Appendix to the report, see: https://www.netl.doe.gov/energy-analysis/details?id=b46c417a-7c9e-4d25-b810-e6248b0217f4</p>

04 OIL SHALES AND TAR SANDS↗

Finding Pennsylvania's Solar Future (Final Technical Report)

Finding Pennsylvania’s Solar Future (Project) was a project of the Pennsylvania Department of Environmental Protection (DEP) Energy Program’s Office (EPO) with funding from the U.S. Department of Energy Solar Energy Technologies Office. DEP brought together a project team that included Citizens for Pennsylvania’s Future (PennFuture), the Vermont Energy Investment Corporation (VEIC), and Pennsylvania-based solar subject matter experts (“Facilitators”) Sharon Pillar, Dr. Jeffrey Brownson, Ron Celentano, and Maureen Mulligan. The goals of the project were to explore whether Pennsylvania has sufficient technical and economic potential to increase in-state solar generation to provide 10 percent of its electricity consumption by 2030 and to identify potential pathways to achieve this target, as well as to explore the associated economic, environmental, and health impacts of achieving the goal. The project had four essential activities: stakeholder engagement, scenario modeling and analysis, strategy development, and dissemination and outreach.

14 SOLAR ENERGY↗

Quantifying methane emissions from natural gas production in north-eastern Pennsylvania

Natural gas infrastructure releases methane (CH 4 ), a potent greenhouse gas, into the atmosphere. The estimated emission rate associated with the production and transportation of natural gas is uncertain, hindering our understanding of its greenhouse footprint. This study presents a new application of inverse methodology for estimating regional emission rates from natural gas production and gathering facilities in north-eastern Pennsylvania. An inventory of CH 4 emissions was compiled for major sources in Pennsylvania. This inventory served as input emission data for the Weather Research and Forecasting model with chemistry enabled (WRF-Chem), and atmospheric CH 4 mole fraction fields were generated at 3 km resolution. Simulated atmospheric CH 4 enhancements from WRF-Chem were compared to observations obtained from a 3-week flight campaign in May 2015. Modelled enhancements from sources not associated with upstream natural gas processes were assumed constant and known and therefore removed from the optimization procedure, creating a set of observed enhancements from natural gas only. Simulated emission rates from unconventional production were then adjusted to minimize the mismatch between aircraft observations and model-simulated mole fractions for 10 flights. To evaluate the method, an aircraft mass balance calculation was performed for four flights where conditions permitted its use. Using the model optimization approach, the weighted mean emission rate from unconventional natural gas production and gathering facilities in north-eastern Pennsylvania approach is found to be 0.36 % of total gas production, with a 2 σ confidence interval between 0.27 and 0.45 % of production. Similarly, the mean emission estimates using the aircraft mass balance approach are calculated to be 0.40 % of regional natural gas production, with a 2 σ confidence interval between 0.08 and 0.72 % of production. Furthermore these emission rates as a percent of production are lower than rates found in any other basin using a top-down methodology, and may be indicative of some characteristics of the basin that make sources from the north-eastern Marcellus region unique.

03 NATURAL GAS↗

Pennsylvania Energy and Cost Savings for New Single- and Multifamily Homes: 2012 IECC as Compared to the 2009 IRC

The 2012 International Energy Conservation Code (IECC) yields positive benefits for Pennsylvania homeowners. Moving to the 2012 IECC from Chapter 11 of the 2009 International Residential Code (IRC) is cost-effective over a 30-year life cycle. On average, Pennsylvania homeowners will save $\$$8,632 with the 2012 IECC. Each year, the reduction to energy bills will significantly exceed increased mortgage costs. After accounting for up-front costs and additional costs financed in the mortgage, homeowners should see net positive cash flows (i.e., cumulative savings exceeding cumulative cash outlays) in 1 year for the 2012 IECC. Average annual energy savings are $\$$515 for the 2012 IECC.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Pennsylvania and Delaware Energy Code Field Studies (Final Technical Report (FTR)

Led by Northeast Energy Efficiency Partnerships (NEEP) in partnership with Performance Systems Development (PSD), the project aimed to conduct energy code compliance field studies for single-family residential buildings in Pennsylvania and Delaware, as well as multifamily and commercial buildings in Pennsylvania. Using U.S. Department of Energy (DOE) approved methodologies, trained field teams conducted on-site observations and testing to document compliance with key energy efficiency measures, including building envelope insulation, air sealing, duct leakage, windows, and mechanical systems. Data from these studies would then be analyzed to identify construction trends and compliance gaps. The goals included published baseline data for each study, and a training roadmap tailored to each state’s needs. This roadmap would have guided outreach and training for builders, code officials, and other stakeholders on the specific code requirements that offered the greatest opportunity for improvement.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Nuclear Security Education Program at the Pennsylvania State University

The availability of trained and qualified nuclear and radiation security experts worldwide has decreased as those with hands-on experience have retired while the demand for these experts and skills have increased. The U.S. Department of Energy's National Nuclear Security Administration's (NNSA) Global Threat Reduction Initiative (GTRI) has responded to the continued loss of technical and policy expertise amongst personnel and students in the security field by initiating the establishment of a Nuclear Security Education Initiative, in partnership with Pennsylvania State University (PSU), Texas A and M (TAMU), and Massachusetts Institute of Technology (MIT). This collaborative, multi-year initiative forms the basis of specific education programs designed to educate the next generation of personnel who plan on careers in the nonproliferation and security fields with both domestic and international focus. The three universities worked collaboratively to develop five core courses consistent with the GTRI mission, policies, and practices. These courses are the following: Global Nuclear Security Policies, Detectors and Source Technologies, Applications of Detectors/Sensors/Sources for Radiation Detection and Measurements Nuclear Security Laboratory, Threat Analysis and Assessment, and Design and Analysis of Security Systems for Nuclear and Radiological Facilities. The Pennsylvania State University (PSU) Nuclear Engineering Program is a leader in undergraduate and graduate-level nuclear engineering education in the USA. The PSU offers undergraduate and graduate programs in nuclear engineering. The PSU undergraduate program in nuclear engineering is the largest nuclear engineering programs in the USA. The PSU Radiation Science and Engineering Center (RSEC) facilities are being used for most of the nuclear security education program activities. Laboratory space and equipment was made available for this purpose. The RSEC facilities include the Penn State Breazeale Reactor (PSBR), gamma irradiation facilities (in-pool irradiator, dry irradiator, and hot cells), neutron beam laboratory, radiochemistry laboratories, and various radiation detection and measurement laboratories. A new nuclear security education laboratory was created with DOE NNSA- GTRI funds at RSEC. The nuclear security graduate level curriculum enables the PSU to educate and train future nuclear security experts, both within the United States as well as worldwide. The nuclear security education program at Penn State will grant a Master's degree in nuclear security starting fall 2015. The PSU developed two courses: Nuclear Security- Detector And Source Technologies and Nuclear Security- Applications of Detectors/Sensors/Sources for Radiation Detection and Measurements (Laboratory). Course descriptions and course topics of these courses are described briefly: - Nuclear Security - Detector and Source Technologies; - Nuclear Security - Applications of Detectors/Sensors/Sources for Radiation Detection and Measurements Laboratory.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Canonsburg, Pennsylvania, UMTRCA Title I Disposal Site 35 Years Postclosure (1985-2020) - 20288

The DOE Office of Legacy Management (LM) Canonsburg, Pennsylvania, Disposal Site is a former uranium ore-processing site located in the borough of Canonsburg and an important part of US history. For 46 years (1911-1957), the site processed ore, for vanadium, radium and then uranium. Soils and groundwater beneath the site were contaminated by the milling operations. The 15-hectare (37-acre) site is owned by the US government and managed by LM, which serves as the federal land manager and steward of cultural, historical, and natural resources at Cold War legacy sites that have been successfully cleaned up to remedial standards. In 1978 Congress directed DOE to remediate 22 inactive uranium-ore processing sites under the Uranium Mill Tailings Radiation Control Act (UMTRCA), in accordance with standards promulgated by the US Environmental Protection Agency in Title 40 CFR Part 192 (40 (CFR 192). Subpart B of 40 CFR 192 regulates the cleanup of contaminated groundwater at the processing sites. The radioactive materials were encapsulated in US Nuclear Regulatory Commission (NRC)-approved disposal cells, and the NRC general license for UMTRCA Title I sites is established in 10 CFR 40.27. Canonsburg was the first site to be remediated under UMTRCA. From 1983 to 1985, the Canonsburg site underwent cleanup under this US law that provides for the safe and environmentally sound disposal, long-term stabilization, and control of uranium mill tailings in a manner that minimizes or eliminates radiation health hazards to the public. The site is unique in that it is one of only two UMTRCA Title I sites in the eastern half of the United States, the other site being the Burrell, Pennsylvania, Title I Disposal Site, a vicinity property to the Canonsburg site. It has been 35 years since the disposal cell at the Canonsburg site was completed. This paper discusses the many efforts that have been taken to maintain the site and presents some of the lessons learned concerning the long-term care of the site. The discussion includes but is not limited to the following: (1) Preserving site history so the community can better appreciate and understand the site. (2) Community outreach efforts, and the importance of maintaining transparency of environmental monitoring results with the community. (3) Pursuing reuse opportunities that offer the potential for improving the community. (4) Remaining engaged with the local community. (5) Remaining proactive in the long-term care of the site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Chemical Characterization of Natural Gas Leaking from Abandoned Oil and Gas Wells in Western Pennsylvania

The U.S. Environmental Protection Agency estimates that there are over 3.2 million abandoned wells in the United States. Studies conducted on gas emissions from abandoned wells have been limited to methane, a powerful greenhouse gas, due to concerns regarding climate change. However, volatile organic compounds (VOCs), including benzene, a known human carcinogen, are known to be associated with upstream oil and gas development and hence could also be released when methane is emitted to the atmosphere. In this investigation, we analyze gas from 48 abandoned wells in western Pennsylvania for fixed gases, light hydrocarbons, and VOCs and estimate associated emission rates. We demonstrate that (1) gas from abandoned wells contains VOCs, including benzene; (2) VOCs are emitted from abandoned wells, the magnitude of which depends on the flow rate and concentration of VOCs in the gas stream; and (3) nearly one-quarter of abandoned wells are located within 100 m of buildings, including residences, in Pennsylvania. Together, these observations indicate that further investigation is necessary to determine whether emissions from abandoned wells pose an inhalation risk to people living, working, or congregating near abandoned wells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Response of Aquatic Bacterial Communities to Hydraulic Fracturing in Northwestern Pennsylvania: A Five-Year Study

Horizontal drilling and hydraulic fracturing extraction procedures have become increasingly present in Pennsylvania where the Marcellus Shale play is largely located. The potential for long-term environmental impacts to nearby headwater stream ecosystems and aquatic bacterial assemblages is still incompletely understood. Here, we perform high-throughput sequencing of the 16 S rRNA gene to characterize the bacterial community structure of water, sediment, and other environmental samples (n = 189) from 31 headwater stream sites exhibiting different histories of fracking activity in northwestern Pennsylvania over five years (2012–2016). Stream pH was identified as a main driver of bacterial changes within the streams and fracking activity acted as an environmental selector for certain members at lower taxonomic levels within stream sediment. Methanotrophic and methanogenic bacteria (i.e. Methylocystaceae, Beijerinckiaceae, and Methanobacterium ) were significantly enriched in sites exhibiting Marcellus shale activity (MSA+) compared to MSA- streams. This study highlighted potential sentinel taxa associated with nascent Marcellus shale activity and some of these taxa remained as stable biomarkers across this five-year study. Identifying the presence and functionality of specific microbial consortia within fracking-impacted streams will provide a clearer understanding of the natural microbial community’s response to fracking and inform in situ remediation strategies.

58 GEOSCIENCES↗

Final Report for Research in High Energy Physics at the University of Pennsylvania for the period ending April 30, 2012

The University of Pennsylvania elementary particle physics/particle cosmology group, funded by the Department of Energy Office of Science, participates in research in high energy physics and particle cosmology that addresses some of the most important unanswered questions in science. The research is divided into five areas. Energy Frontier - We participate in the study of proton-proton collisions at the Large Hadron Collider in Geneva, Switzerland using the ATLAS detector. The University of Pennsylvania group was responsible for the design, installation, and commissioning of the front-end electronics for the Transition Radiation Tracker (TRT) and plays the primary role in its maintenance and operation. We play an important role in the triggering of ATLAS, and we have made large contributions to the TRT performance and to the study and identification of electrons, photons, and taus. We have been actively involved in searches for the Higgs boson and for SUSY and other exotic particles. We have made significant contributions to measurement of Standard Model processes such as inclusive photon production and WW pair production. We also have participated significantly in R&D for upgrades to the ATLAS detector. Cosmic Frontier - The Dark Energy Survey (DES) telescope will be used to elucidate the nature of dark energy and the distribution of dark matter. Penn has played a leading role both in the use of weak gravitational lensing of distant galaxies and the discovery of large numbers of distant supernovae. The techniques and forecasts developed at Penn are also guiding the development of the proposed Large Synoptic Survey Telescope (LSST).We are also developing a new detector, MiniClean, to search for direct detection of dark matter particles. Intensity Frontier - We are participating in the design and R&D of detectors for the Long Baseline Neutrino Experiment (now DUNE), a new experiment to study the properties of neutrinos. Advanced Techology R&D - We have an extensive involvement in electronics required for sophisticated new detectors at the LHC and are developing electronics for the LSST camera. Theoretical Physics - We are carrying out a broad program studying the fundamental forces of nature and early universe cosmology and mathematical physics. Our activities span the range from model building, formal field theory, and string theory to new paradigms for cosmology and the interface of string theory with mathematics. Our effort combines extensive development of the formal aspects of string theory with a focus on real phenomena in particle physics, cosmology and gravity.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Pennsylvania Residential Energy Code Field Study: Baseline Report

A research project in the Commonwealth of Pennsylvania identified opportunities to reduce homeowner utility bills in residential single-family new construction by increasing compliance with the state energy code. The study was initiated in October 2014 and continued through July 2015. During this period, research teams visited 171 homes during various stages of construction, resulting in a substantial data set based on observations made directly in the field. Analysis of the data has led to a better understanding of the energy features present in homes, and indicates over $2.7 million in potential annual savings to Pennsylvania homeowners that could result from increased compliance with the 2009 International Energy Conservation Code (and equivalent compliance options). Public and private entities within the state can use this information to justify and catalyze future investments in energy code training and related energy-efficiency programs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Assessing impacts of unconventional natural gas extraction on microbial communities in headwater stream ecosystems in Northwestern Pennsylvania

Hydraulic fracturing and horizontal drilling have increased dramatically in Pennsylvania Marcellus shale formations, however the potential for major environmental impacts are still incompletely understood. High-throughput sequencing of the 16S rRNA gene was performed to characterize the microbial community structure of water, sediment, bryophyte, and biofilm samples from 26 headwater stream sites in northwestern Pennsylvania with different histories of fracking activity within Marcellus shale formations. Further, we describe the relationship between microbial community structure and environmental parameters measured. Approximately 3.2 million 16S rRNA gene sequences were retrieved from a total of 58 samples. Microbial community analyses showed significant reductions in species richness as well as evenness in sites with Marcellus shale activity. Beta diversity analyses revealed distinct microbial community structure between sites with and without Marcellus shale activity. For example, operational taxonomic units (OTUs) within the Acetobacteracea, Methylocystaceae, Acidobacteriaceae, and Phenylobacterium were greater than three log-fold more abundant in MSA+ sites as compared to MSA- sites. Further, several of these OTUs were strongly negatively correlated with pH and positively correlated with the number of well-pads in a watershed. It should be noted that many of the OTUs enriched in MSA+ sites are putative acidophilic and/or methanotrophic populations. This study revealed apparent shifts in the autochthonous microbial communities and highlighted potential members that could be responding to changing stream conditions as a result of nascent industrial activity in these aquatic ecosystems.

beta diversity↗

Aspects of rare earth element enrichment in Allegheny Plateau coals, Pennsylvania, USA

The Allegheny Plateau in western Pennsylvania, western Maryland, and northern West Virginia has relatively flat-lying strata with southwest-northeast-trending anticlines cored by splay faults originating from the thrust faults and southeast-northwest-trending lineaments. The lineaments define both the structural relief of the anticlines and the coal rank. Coal rank in the Pennsylvanian Allegheny Group coals is medium volatile bituminous in the region of less-prominent structural relief and low volatile bituminous in the region with more pronounced anticlines. Zinc and Cl exhibit high values in coals in the vicinity of the lineaments. Although coal rank was not a parameter in the Principal components analysis, the highest rank coals clustered together in a quadrant defined, in part, by the Zn concentration. Zinc was selected as a parameter due to its possible link with hydrothermal mineralization and Zr and TiO 2 /Al 2 O 3 were selected based on their presumed association with detrital mineral influences. The highest rare earths + Y values in benches of the Lower Kittanning coal were found at sites close to the lineaments. Negative or negligible Ce anomalies (δCe) and strongly positive Gd anomalies (δGd) suggest marine or hydrothermal influences and negative Eu anomalies (δEu) along with high TiO 2 /Al 2 O 3 values suggest a terrestrial input. In conclusion, the plots of δCe vs. δGd and δCe vs. δEu show that the low volatile bituminous coals are segregated from the other coals, suggesting that the factors that influenced coal rank also influenced the distribution of the rare earth elements.

58 GEOSCIENCES↗

Pennsylvania Department of Environmental Protection (PA DEP) 26r Detailed Produced Water Compositions (version 2.0)

A database of geochemical compositions of aqueous species in produced water reported to the PA Department of Environmental Protection (PA DEP). Samples were collected between late-2010 to late-2024. Data from publicly available PA DEP 26r reports were scraped from pdf files and cumulated into tabular spreadsheet format for >3,000 produced water streams from Marcellus Shale wells in Pennsylvania. In addition to providing the original values, the NETL NEWTS team has reformatted the dataset to allow sample streams to be easily copied into OLI Studio and Geochemist WorkBench (GWB) software for modeling the geochemistry and the recovery of critical minerals, such as lithium, from these produced water streams. ***This dataset is an updated version of the PA DEP 26r Detailed Produced Water Compositions (version 1.0) dataset, providing expanded spatial and temporal coverage.***

Aqueous Chemistry↗