Materials Data on PdS3 by Materials Project
PdS(S)2 crystallizes in the tetragonal I4/mmm space group. The structure is two-dimensional and consists of two PdS sheets oriented in the (0, 0, 1) direction and two S sheets oriented in the (0, 0, 1) direction. In each PdS sheet, Pd2+ is bonded in a square co-planar geometry to four equivalent S+0.67- atoms. All Pd–S bond lengths are 2.37 Å. S+0.67- is bonded in a square co-planar geometry to four equivalent Pd2+ atoms. In each S sheet, S+0.67- is bonded in a square co-planar geometry to four equivalent S+0.67- atoms. All S–S bond lengths are 2.37 Å.
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