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DOE OSTI2020

Materials Data on PdCl2 by Materials Project

PdCl2 is Tungsten structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three PdCl2 clusters. Pd2+ is bonded in a rectangular see-saw-like geometry to four Cl1- atoms. All Pd–Cl bond lengths are 2.34 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pd2+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pd2+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on PdCl2 by Materials Project

PdCl2 crystallizes in the orthorhombic Pnnm space group. The structure is one-dimensional and consists of two PdCl2 ribbons oriented in the (1, 0, 0) direction. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Pd2+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on PdCl2 by Materials Project

PdCl2 crystallizes in the monoclinic P2/m space group. The structure is one-dimensional and consists of two PdCl2 ribbons oriented in the (0, 1, 0) direction. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Pd2+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on PdCl2 by Materials Project

PdCl2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one PdCl2 sheet oriented in the (1, 0, 0) direction. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.34 Å. Cl1- is bonded in a bent 120 degrees geometry to two equivalent Pd2+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on Pd(SCl3)2 by Materials Project

PdCl2(SCl2)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one palladium(ii) chloride molecule and two sulfur dichloride molecules.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on Pd(SeCl3)2 by Materials Project

PdCl2(SeCl2)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four palladium(ii) chloride molecules and eight selenium dichloride molecules.

36 MATERIALS SCIENCE↗