Materials Data on Pd2Cl2O by Materials Project
Pd2OCl2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Pd–O bond lengths are 2.05 Å. Both Pd–Cl bond lengths are 2.35 Å. O2- is bonded to four equivalent Pd2+ atoms to form corner-sharing OPd4 tetrahedra. Cl1- is bonded in an L-shaped geometry to two equivalent Pd2+ atoms.
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