Materials Data on Rb(PRh)2 by Materials Project
Rb(RhP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rb is bonded in a body-centered cubic geometry to eight equivalent P atoms. All Rb–P bond lengths are 3.55 Å. Rh is bonded to four equivalent P atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. All Rh–P bond lengths are 2.35 Å. P is bonded in a 8-coordinate geometry to four equivalent Rb and four equivalent Rh atoms.
36 MATERIALS SCIENCE↗