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At least 19 records

Ozone concentration in the cabin of a Gates Learjet measured simultaneously with atmospheric ozone concentrations

A Gates Learjet Model 23 was instrumented with monitors to measure simultaneously the atmospheric and the cabin concentrations of ozone at altitudes up to 13 kilometers. Six data flights were made in February 1978. Results indicated that only a small amount of the atmospheric ozone is destroyed in the cabin pressurization system. Ozone concentrations measured in the cabin near the conditioned-air outlets were only slightly lower than the atmospheric ozone concentration. For the two cabin configurations tested, the ozone retention in the cabin was 63 and 41 percent of the atmospheric ozone concentration. Maximum cabin ozone concentration measured during these flights was 410 parts per billion by volume.

Briehl, D.

NASA satellite helps airliners avoid ozone concentrations

Results from a test to determine the effectiveness of satellite data for helping airlines avoid heavy concentrations of ozone are reported. Information from the Total Ozone Mapping Spectrometer, aboard the Nimbus-7 was transmitted, for use in meteorological forecast activities. The results show: (1) Total Ozone Mapping Spectrometer profile of total ozone in the atmosphere accurately represents upper air patterns and can be used to locate meteorological activity; (2) route forecasting of highly concentrated ozone is feasible; (3) five research aircraft flights were flown in jet stream regions located by the Total Ozone Mapping Spectrometer to determine winds, temperatures, and air composition. It is shown that the jet stream is coincides with the area of highest total ozone gradient, and low total ozone amounts are found where tropospheric air has been carried along above the tropopause on the anticyclonic side of the subtropical jet stream.

Source record

Decrease of summer tropospheric ozone concentrations in Antarctica

It is shown here that surface ozone concentrations at the South Pole in the austral summer decreased by 17 percent over the period 1976-90. Over the same period, solar irradiance at the South Pole in January and February decreased by 7 percent as a result of a 25 percent increase in cloudiness. It is suggested that the trend in the summer ozone concentrations is caused by enhanced photochemical destruction of ozone in the lower troposphere caused by the increased penetration of UV radiation associated with stratospheric ozone depletion, coupled with enhanced transport of ozone-poor marine air from lower latitudes to the South Pole.

Schnell, R. C.

Comparison of seasonal variations of upper stratospheric ozone concentrations revealed by Umkehr and Nimbus 4 BUV observations

This paper reports the results of a comparison between upper stratospheric ozone concentration profiles in the region between 22 and 1.4 mbar, as determined from surface-based Umkehr observations and satellite Nimbus 4 BUV observations. The Umkehr data, consisting of monthly averages of observations extending over several years or longer, were obtained at three stations located in the Northern Hemisphere and two in the Southern Hemisphere. The BUV data were obtained during the period from May 1970 to March 1971. Aside from some bias in the magnitudes of the Umkehr and BUV data, marked annual cycles of ozone concentration in the upper stratosphere are clearly revealed. Above 4 mbar the profiles show a summer minimum and a winter maximum, while below 4 mbar the annual variation is reversed from this pattern. In the Northern Hemisphere the winter maximum is accompanied by a secondary minimum of 1- to 2-month duration near 3 mbar. This short-term minimum is much less obvious in the Southern Hemisphere data. Some of the problem of attempting to monitor long-term changes in the upper stratosphere are discussed briefly.

Deluisi, J. J.

Comparison of ozone concentrations obtained from Skylab eclipse and ozonesonde measurements

The satellite eclipse technique of ozone measurement is evaluated to determine its accuracy and resolution. The method of obtaining ozone concentrations from ground-based observations of eclipsing satellites is described, the theory of this method is outlined, and the data reduction procedure is summarized. It is shown that the satellite eclipse technique successfully measures the vertical distribution of ozone from 15 to 40 km with precisions ranging from + or - 12% between 20 and 35 km and + or - 25% at both 15 and 40 km. The ozone profile is found to be in good agreement with in situ measurements obtained from an ozonesonde launched near the eclipse tangent point at local sunset, the percent differences being less than 14% from 20 to 40 km.

Mcdougal, D. S.

Transportable Lidar for the Measurement of Ozone Concentration and Flux Profiles in the Lower Troposphere

In many areas of the United States, as well as in other industrial areas (such as Europe), elevated and potentially harmful levels of ozone are being measured during summer. Most of this ozone is photochemically produced. The relatively long lifetime of ozone allows industrially produced ozone to be transported on a hemispheric scale. Since the trends of tropospheric ozone are very likely dependent on the source strengths and distributions of the pollutants and the chemical/ transport process involved, a predictive understanding of tropospheric ozone climatology requires a focus on the chemical and transport processes that link regional emissions to hemispheric ozone trends and distributions. Of critical importance to these studies is a satisfactory data base of tropospheric ozone distribution from which global and regional tropospheric ozone climatology can be derived, and the processes controlling tropospheric ozone can be better understood. A transportable lidar for measuring ozone concentration and flux profiles in the lower troposphere is needed. One such system is being developed at the National Oceanic and Atmospheric Administration/Earth Resources Laboratory (NOAA/ERL) Wave Propagation Laboratory (WPL).

Zhao, Yanzeng

Development of the Double Etalon Fabry-Perot Interferometer for Determining Total and Tropospheric Ozone Concentrations

Measuring and understanding the distribution of ozone through the lower levels of Earth's atmosphere are high priorities in global change and climate research. Of particular interest now is the global distribution of ozone in the upper troposphere and lower stratosphere. Global coverage of the stratospheric ozone is feasible only via remote sensing instruments on a space-based platform. And though extensive monitoring tropospheric ozone is possible using instruments flown aboard conventional aircraft, a space-based system would be significantly less costly and provide information over a much broader area and produce more uniform coverage. Here we describe the prototype of an instrument being developed to monitor, from an orbiting spacecraft, the ozone found in Earth's upper troposphere and lower stratosphere. Our new spectrometer is an infrared Fabry-Perot interferometer which uses two synchrounously tuned etalons: a high resolution narrow band device and a lower resolution broader band filtering etalon. The prototype is a scanning device making use of nearly collimated input radiation and a single element detector. As presently configured, it is capable of providing a resolution better than 0.07/cm with a spectral band width approximately 5/cm wide and centered at 1054.7/cm. For the future space-based emission device a modification of the the prototype was to be made to employ innovative circle-to-line detector optics, those developed or in development at UM/SPRL, and a focal plane array detector. These enhancements would enable a simultaneous recording of the entire spectral range of interest, but with simple detection electronics and a significant gain in signal-to-noise over that of the scanning version.

Cook, William

The global consequences of increasing tropospheric ozone concentrations

Recent analyses of long term records of tropospheric ozone measurements in the Northern Hemisphere suggest that it is increasing at a rate of 1 to 2 percent per year. Because of this, it is argued that the amount of atmospheric warming due to increasing tropospheric ozone is comparable to, or possibly even greater than, the amount of warming due to the increase of carbon dioxide. Unlike all other climatically important trace gases, ozone is toxic, and increases in its concentration will result in serious environmental damage, as well as impairment of human health.

Fishman, Jack

The global consequences of increasing tropospheric ozone concentrations

Recent analyses of long-term records of tropospheric ozone measurements in the Northern Hemisphere suggest that it is increasing at a rate of 1 to 2 percent per year. Because of this, it is argued that the amount of atmospheric warming due to increasing tropospheric ozone is comparable to, or possibly even greater than, the amount of warming due to the increase of carbon dioxide. Unlike all other climatically important trace gases, ozone is toxic, and increases in its concentration will result in serious environmental damage, as well as impairment of human health.

Fishman, Jack

Higher Surface Ozone Concentrations Over the Chesapeake Bay than Over the Adjacent Land: Observations and Models from the DISCOVER-AQ and CBODAQ Campaigns

Air quality models, such as the Community Multiscale Air Quality (CMAQ) model, indicate decidedly higher ozone near the surface of large interior water bodies, such as the Great Lakes and Chesapeake Bay. In order to test the validity of the model output, we performed surface measurements of ozone (O3) and total reactive nitrogen (NOy) on the 26-m Delaware II NOAA Small Research Vessel experimental (SRVx), deployed in the Chesapeake Bay for 10 daytime cruises in July 2011 as part of NASA's GEO-CAPE CBODAQ oceanographic field campaign in conjunction with NASA's DISCOVER-AQ air quality field campaign. During this 10-day period, the EPA O3 regulatory standard of 75 ppbv averaged over an 8-h period was exceeded four times over water while ground stations in the area only exceeded the standard at most twice. This suggests that on days when the Baltimore/Washington region is in compliance with the EPA standard, air quality over the Chesapeake Bay might exceed the EPA standard. Ozone observations over the bay during the afternoon were consistently 10-20% higher than the closest upwind ground sites during the 10-day campaign; this pattern persisted during good and poor air quality days. A lower boundary layer, reduced cloud cover, slower dry deposition rates, and other lesser mechanisms, contribute to the local maximum of ozone over the Chesapeake Bay. Observations from this campaign were compared to a CMAQ simulation at 1.33 km resolution. The model is able to predict the regional maximum of ozone over the Chesapeake Bay accurately, but NOy concentrations are significantly overestimated. Explanations for the overestimation of NOy in the model simulations are also explored

boundary layer

Observations of reduced ozone concentrations in the tropical stratosphere after the eruption of Mt. Pinatubo

Two independent sets of data, one of aerosols from an airborne lidar system, and one of ozone from ozonesonde measurements indicate that significant ozone decreases may have happened as a result of the injection of debris by the Mt. Pinatubo volcano in June 1991. The amount of this reduction maximizes at 24-25 km, near the peak of the aerosol distribution, though a deficit is seen throughout the lower stratosphere between 19 and 28 km. The greatest differences observed prior and subsequent to the eruptions at these altitudes is 18-20 percent.

Grant, W. B.

Measuring Concentration Of Ozone Automatically

Airborne photometer measures absorption of ultraviolet. Automatically measures ozone concentrations in atmosphere to accuracy within 10 parts per billion. Air collected outside airplane enters photometer by way of transfer valve. Pressure and temperature of air measured simultaneously with transmissivity of air to ultraviolet light from lamp. Instrument has mass of 20.5 kg and fits in aluminum box measuring 78 by 58 by 25 cm. Compact, lightweight, low-power instrument developed for use on high-altitude research airplane.

Lavelle, Joseph R.

Quantifying Uncertainty in Projections of Stratospheric Ozone Over the 21st Century

Future stratospheric ozone concentrations will be determined both by changes in the concentration of ozone depleting substances (ODSs) and by changes in stratospheric and tropospheric climate, including those caused by changes in anthropogenic greenhouse gases (GHGs). Since future economic development pathways and resultant emissions of GHGs are uncertain, anthropogenic climate change could be a significant source of uncertainty for future projections of stratospheric ozone. In this pilot study, using an ensemble of opportunity of chemistry-climate model (CCM) simulations, the contribution of scenario uncertainty from different plausible emissions pathways for 10 ODSs and GHGs to future ozone projections is quantified relative to the contribution from model uncertainty and internal variability of the chemistry-climate system. For both the global, annual mean ozone concentration and for ozone in specific geographical regions, differences between CCMs are the dominant source of uncertainty for the first two-thirds of the 21 st century, up-to and after the time when ozone concentrations 15 return to 1980 values. In the last third of the 21st century, dependent upon the set of greenhouse gas scenarios used, scenario uncertainty can be the dominant contributor. This result suggests that investment in chemistry-climate modelling is likely to continue to refine projections of stratospheric ozone and estimates of the return of stratospheric ozone concentrations to pre-1980 levels.

Charlton-Perez, A. J.

Turbulent transport and production/destruction of ozone in a boundary layer over complex terrain

The first Intensive Observation Period (IOP) of the Swiss air pollution experiment POLLUMET took place in 1990 in the Aare River Valley between Bern and Zurich. During the IOP, fast response measurements of meteorological variables and ozone concentration were made within the boundary layer aboard a motorglider. In addition, mean values of meteorological variables and the concentrations of ozone and other trace species were measured using other aircraft, pilot balloons, tethersondes, and ground stations. Turbulent flux profiles of latent and sensible heat and ozone are calculated from the fast response data. Terms in the ozone mean concentration budget (time rate of change of mean concentration, horizontal advection, and flux divergence) are calculated for stationary time periods both before and after the passage of a cold front. The source/sink term is calculated as a residual in the budget, and its sign and magnitude are related to the measured concentrations of reactive trace species within the boundary layer. Relationships between concentration ratios of trace species and ozone concentration are determined in order to understand the influence of complex terrain on the processes that produce and destroy ozone.

Greenhut, Gary K.

The roles of dynamical and chemical processes in determining the stratospheric concentration of ozone in one-dimensional and two-dimensional models

The two-dimensional model of Ko et al. (1985) was used to calculate the stratospheric concentrations of ozone, to determine the principal modes of balance for different stratospheric regions. The results of this analysis show that the local concentration of ozone in different regions of stratosphere is determined by balances between different mechanisms. In the upper stratosphere, the ozone concentration is dominated by photochemical processes, whereas in the mid-lower stratosphere, the bulk of ozone appears to be controlled by an interaction between the transport and the photochemical processes. The results point to the limitations of one-dimensional models, which fail to properly account for the effect of transport in the lower stratosphere.

Ko, Malcolm K. W.

Aircraft cabin ozone measurements on B747-100 and B747-SP aircraft: Correlations with atmospheric ozone and ozone encounter statistics

Simultaneous measurements of atmospheric (outside) ozone concentration and ozone levels in the cabin of the B747-100 and B747-SP airliners were made by NASA to evaluate the aircraft cabin ozone contamination problem. Instrumentation on these aircraft measured ozone from an outside probe and at one point in the cabin. Average ozone in the cabin of the B747-100 was 39 percent of the outside. Ozone in the cabin of the B747-SP measured 82 percent of the outside, before corrective measures. Procedures to reduce the ozone in this aircraft included changes in the cabin air circulation system, use of the high-temperature 15th stage compressor bleed, and charcoal filters in the inlet cabin air ducting, which as separate actions reduced the ozone to 58, 19 and 5 percent, respectively. The potential for the NASA instrumented B747 aircraft to encounter high levels of cabin ozone was derived from atmospheric oxone measurements on these aircraft. Encounter frequencies for two B747-100's were comparable even though the route structures were different. The B747-SP encountered high ozone than did the B747-100's.

Perkins, P. J.

BOREAS AFM-03-NCAR Electra 1994 Aircraft Sounding Data

The Boreal Ecosystem-Atmosphere Study (BOREAS) Airborne Fluxes and Meteorology (AFM)-3 team used the National Center for Atmospheric Research's (NCAR) Electra aircraft to make sounding measurements to study the planetary boundary layer using in situ and remote-sensing measurements. Measurements were made of wind speed and direction, air pressure and temperature, potential temperature, dewpoint, mixing ratio of H, O, CO, concentration, and ozone concentration. Twenty-five research missions were flown over the Northern Study Area (NSA), Southern Study Area (SSA), and the transect during BOREAS Intensive Field Campaigns (IFCs) 1, 2, and 3 during 1994. All missions had from four to ten soundings through the top of the planetary boundary layer. This sounding data set contains all of the in situ vertical profiles through the boundary layer top that were made (with the exception of 'porpoise' maneuvers). Data were recorded in one-second time intervals. These data are stored in tabular ASCII files. The NCAR Electra 1994 aircraft sounding data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

Lenschow, Donald H.