Materials Data on Os3Cl by Materials Project
OsOs2Cl is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional and consists of two osmium molecules and one Os2Cl framework. In the Os2Cl framework, Os+0.33+ is bonded to four equivalent Cl1- atoms to form a mixture of edge and corner-sharing OsCl4 tetrahedra. All Os–Cl bond lengths are 2.69 Å. Cl1- is bonded in a body-centered cubic geometry to eight equivalent Os+0.33+ atoms.
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