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NASA NTRSDate not supplied

Latest Results from NASA Ames’ COSmIC and Optical Constants Facility (OCF): Determining Optical Constants for Titan, Pluto and Protoplanetary Disks Applications

The NASA Ames COsmic SImulation Chamber (COSmIC) is a unique experimental facility that can be used, among many applications, to produce solid particles from gas phase molecular precursors at low temperature (150 K) using a plasma discharge to induce the chemistry in the stream of a free jet expansion. The choice of the initial gas mixture used to produce the solid sample allows the simulation of either cold planetary atmospheres like Titan or Pluto (with N2/CH4-based initial mixtures), or circumstellar environments (with Ar/CxHy-based initial mixtures). The Ames Optical Constants Facility (OCF) allows the determination of optical constants covering a broad wavelength range with high spectral resolution for solid materials, analogs of organic refractory materials formed in planetary and astrophysical environments. The core of the OCF is a Fourier transform infrared (FTIR) spectrometer that allows the continuous characterization of solid samples in the visible to far-infrared (FIR) range (0.59–200 μm, 16,950–50 cm−1). Modeling of the laboratory measurements conducted with the OCF allows the determination of accurate optical constants, n and k, over the full vis-FIR range. Here we present the latest results of two studies that combined (1) experiments performed with COSmIC to produce analogs of aerosols forming in Titan’s atmosphere and analogs of cosmic grains forming in circumstellar envelops, and (2) the characterization of these analogs with the OCF to provide the real and imaginary parts of their refractive indices, n + ik, to the community, from the visible to the FIR. These optical constants can be used as critical input parameters in radiative transfer, atmospheric and reflectance models to interpret observational data of, e.g., Titan’s atmosphere and protoplanetary disks. Providing optical constants for various materials of different compositions allows to explore a broad range of composition by simulating mixtures of materials. We also present a new project to produce analogs of Pluto’s atmospheric aerosols with COSmIC and determine their optical constants with OCF, to be used in reflectance spectra models for the interpretation of New Horizons observations of Lowell Regio, Sputnik Planitia and Cthulhu.

COsmic SImulation Chamber (COSmIC)↗
NASA NTRSDate not supplied

On the New Optical Constants Database (OCdb) and its Importance for the Interpretation of Observational Data

The Optical Constants database(ocdb.smce.nasa.gov) came online in February 2023 and provides complex refractive indices of laboratory-generated organic refractory materials and ices relevant to (exo) planetary and astrophysical environments.The goal of the OCdb is to centralize published optical constants data to facilitate both their access by the scientific community and their use to analyze observational data returned by space missions and ground-based observatories. Computational tools are also under development to facilitate scientific use of the available OCdb optical constants data sets. Investigators generating laboratory optical constants are therefore encouraged to contribute their data to OCdb in order to increase the availability of their data and to enhance the scientific effectiveness of the database. Optical constants are critical input parameters in models (e.g.,radiative transfer, atmospheric, and reflectance spectral models)that are used to simulate the absorption, reflection, and scattering of light due to solid materials present in planetary and astrophysical environments (planets, their satellites, exoplanets, asteroids, comets, protoplanetary disks, etc.), and are key to the compositional interpretation of observations. We will first present the infrastructure of the OCdb and show how to use and contribute to it. We will introduce the two large NASA projects, namely, the Laboratory Astrophysics Directed Work Package and the NASA Center for Optical Constants, that have been instrumental in (i) developing the OCdb, (ii) generating planetary-and astrophysics-relevant ices and organic refractory materials from gas and ice irradiation in the laboratory, and (iii) determining their optical constants for inclusion in OCdb. We will also present two studies that are making use of these optical constants to interpret observations of Titan’s atmosphere and Pluto’s surface. These studies show the importance of measuring optical constants of laboratory-generated materials, and their impact on the models used to analyze and interpret astronomical observations. These studies also demonstrate the essential importance of such a database and the need for optical constants of a broad range of materials and wavelengths to enable the scientific community and to maximize the scientific return from space missions (e.g., Cassini, New Horizons, SOFIA, JWST).

The Optical Constants database↗
NASA NTRS1980

Effective optical constants of anisotropic materials

The applicability of a technique for determining the optical constants of soil or aerosol components on the basis of measurements of the reflectance or transmittance of inhomogeneous samples of component material is investigated. Optical constants for a sample of very pure quartzite were obtained by a specular reflection technique and line parameters were calculated by classical dispersion theory. Predictions of the reflectance of powdered quartz were then derived from optical constants measured for the anisotropic quartz and for pure quartz crystals, and compared with experimental measurements. The calculated spectra are found to resemble each other moderately well in shape, however the reflectance level calculated from the psuedo-optical constants (quartzite) is consistently below that calculated from quartz values. The spectrum calculated from the quartz optical constants is also shown to represent the experimental nonrestrahlen features more accurately. It is thus concluded that although optical constants derived from inhomogeneous materials may represent the spectral features of a powdered sample qualitatively a quantitative fit to observed data is not likely.

Aronson, J. R.↗
NASA NTRS1986

Methods for estimating the optical constants of atmospheric hazes based on complex optical measurements

The methods of multifrequency laser sounding (MLS) are the most effective remote methods for investigating the atmospheric aerosols, since it is possible to obtain complete information on aerosol microstructure and the effective methods for estimating the aerosol optical constants can be developed. The MLS data interpretation consists in the solution of the set of equations containing those of laser sounding and equations for polydispersed optical characteristics. As a rule, the laser sounding equation is written in the approximation of single scattering and the equations for optical characteristics are written assuming that the atmospheric aerosol is formed by spherical and homogeneous particles. To remove the indeterminacy of equations, the method of optical sounding of atmospheric aerosol, consisting in a joint use of a mutifrequency lidar and a spectral photometer in common geometrical scheme of the optical experiment was suggested. The method is used for investigating aerosols in the cases when absorption by particles is small and indicates the minimum necessary for interpretation of a series of measurements.

Zuev, V. E.↗
NASA NTRS1976

The optical constants of several atmospheric aerosol species - Ammonium sulfate, aluminum oxide, and sodium chloride

An investigation is conducted of problems which are related to a use of measured optical constants in the simulation of the optical constants of real atmospheric aerosols. The techniques of measuring optical constants are discussed, taking into account transmission measurements through homogeneous and inhomogeneous materials, the immersion of a material in a liquid of a known refractive index, the consideration of the minimum deviation angle of prism measurement, the interference of multiply reflected light, reflectivity measurements, and aspects of mathematical analysis. Graphs show the real and the imaginary part of the refractive index as a function of wavelength for aluminum oxide, NaCl, and ammonium sulfate. Tables are provided for the dispersion parameters and the optical constants.

Toon, O. B.↗
NASA NTRS1994

Infrared optical constants of H2O ice, amorphous nitric acid solutions, and nitric acid hydrates

We determined the infrared optical constants of nitric acid trihydrate, nitric acid dihydrate, nitric acid monohydrate, and solid amorphous nitric acid solutions which crystallize to form these hydrates. We have also found the infrared optical constants of H2O ice. We measured the transmission of infrared light throught thin films of varying thickness over the frequency range from about 7000 to 500/cm at temperatures below 200 K. We developed a theory for the transmission of light through a substrate that has thin films on both sides. We used an iterative Kramers-Kronig technique to determine the optical constants which gave the best match between measured transmission spectra and those calculated for a variety of films of different thickness. These optical constants should be useful for calculations of the infrared spectrum of polar stratospheric clouds.

Toon, Owen B.↗
NASA NTRS2010

Infrared Spectra, Index of Refraction, and Optical Constants of Nitrile Ices Relevant to Titan's Atmosphere

Spectra and optical constants of nitrite ices known or suspected to be in Titan's atmosphere are presented from 2.5 to 200 microns (4000 to 50 per cm ). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan's winter pole. Ices studied include: HCN, hydrogen cyanide; C2N2, cyanogen; CH3CN, acetonitrile; C 2H5CN, propionitrile; and HC3N, cyanoacetylene. For each of these molecules we report new measurements of the index of refraction, n, determined in both the amorphous- and crystallinephase at 670 nm. Spectra were measured and optical constants were calculated for each nitrite at a variety of temperatures including 20, 35, 50, 75, 95, and 110 K, in the amorphous- and crystalline-phase. This laboratory effort uses a dedicated FTIR spectrometer to record transmission spectra of thin-film ice samples. Laser interference is used to measure film thickness during condensation onto a transparent cold window attached to the tail section of a closed-cycle helium cryostat. Optical constants, real (n) and imaginary (k) refractive indices, are determined using Kramers-Kronig (K-K) analysis. Our calculation reproduces the complete spectrum, including all interference effects. Index of refraction measurements are made in a separate dedicated FTIR spectrometer where interference deposit fringes are measured using two 670 nm lasers at different angles to the ice substrate. A survey of these new measurements will be presented along with a discussion of their validation, errors, and application to Titan data.

Moore, Marla↗
NASA NTRS1974

Investigation of the Kramers-Kronig analysis - Revised optical constants of AgCl

White and Straley (1968) have reported room-temperature optical constants for AgCl that exhibit negative, unphysical dips at the band edge. Because Morrison (1961) also obtained such behavior for InAs, InSb, and GaAs, a study is made of the possible sources of this anomaly. An artifact of the experimental reflectance data near this energy is found to be responsible. No defect in the Kramers-Kronig transform or its use is implied, contrary to some suggestions. The corrected optical constants of AgCl were modified by about 10% up to 5 eV, whereas at higher energies they were barely affected. Thus Kramers-Kronig-deduced optical constants that exhibit unusual structure are not affected by this structure at other energies. The new AgCl results are presented, and assignments are briefly discussed.

Bauer, R. S.↗
NASA NTRS2019

Introducing NASA Ames' New Infrared Optical Constant Facility. Determinations of Complex Refractive Indices for Titan Aerosol Analogs and Other Applications

A new optical constant facility has been developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of (exo)planetary hazes and cloud particles. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR to Far-IR range (from 0.74 to 200 μm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of non-homogeneous samples (laboratory (exo)planetary aerosol analogs, films, slabs of material, crystals, powders, etc.) over a wide incidence and emittance angle range (0-90 degrees). This new experimental setup allows the characterization of angular light distribution in both transmission and reflection measurements, and enables the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory measurements. The resulting refractive indices are critical input parameters in radiative transfer models, microphysical models, cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. Here we present a description of the facility along with the first determination of optical constants for Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental setup developed at NASA Ames that allows the simulation of Titan’s complex atmospheric chemistry at Titan-like temperature (200 K). We also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

Sciamma-O'Brien, Ella M.↗
NASA NTRS1991

Derivation of Midinfrared (5-25 micrometers) Optical Constants of Some Silicates and Palagonite

The midinfrared 2000-400/ cm (5-25 microns) optical constants (real (n) and imaginary (k) indices of refraction) are presented for: (1) pyrophyllite; (2) kaolinite; (3) serpentine; (4) montmorillonite; (5) saponite; (6) palagonite; and (7) orthopyroxene. Comparison of the values derived here with those previously presented for serpentine, montmorillonite, and palagonite is generally quite good and discrepancies between values are probably due to either chemical differences between the actual samples or different techniques used to derive the values. For montmorillonite, saponite, and palagonite we were able to derive optical constants in the region of the H2O-bending fundamental near 6 microns. We find that if a pellet of pure material can be produced with a mirror-like surface then the optical constants of clays and other noncohesive materials can be readily derived.

Roush, T.↗
NASA NTRS1989

Optical constants of solid methane

Methane is the most abundant simple organic molecule in the outer solar system bodies. In addition to being a gaseous constituent of the atmospheres of the Jovian planets and Titan, it is present in the solid form as a constituent of icy surfaces such as those of Triton and Pluto, and as cloud condensate in the atmospheres of Titan, Uranus, and Neptune. It is expected in the liquid form as a constituent of the ocean of Titan. Cometary ices also contain solid methane. The optical constants for both solid and liquid phases of CH4 for a wide temperature range are needed for radiative transfer calculations, for studies of reflection from surfaces, and for modeling of emission in the far infrared and microwave regions. The astronomically important visual to near infrared measurements of solid methane optical constants are conspicuously absent from the literature. Preliminary results are presented of the optical constants of solid methane for the 0.4 to 2.6 micron region. K is reported for both the amorphous and the crystalline (annealed) states. Using the previously measured values of the real part of the refractive index, n, of liquid methane at 110 K n is computed for solid methane using the Lorentz-Lorentz relationship. Work is in progress to extend the measurements of optical constants n and k for liquid and solid to both shorter and longer wavelengths, eventually providing a complete optical constants database for condensed CH4.

Khare, Bishun N.↗
NASA NTRS1990

Optical constants of solid methane

Methane is the most abundant simple organic molecule in the outer solar system bodies. In addition to being a gaseous constituent of the atmospheres of the Jovian planets and Titan, it is present in the solid form as a constituent of icy surfaces such as those of Triton and Pluto, and as cloud condensate in the atmospheres of Titan, Uranus, and Neptune. It is expected in the liquid form as a constituent of the ocean of Titan. Cometary ices also contain solid methane. The optical constants for both solid and liquid phases of CH4 for a wide temperature range are needed for radiative transfer calculations, for studies of reflection from surfaces, and for modeling of emission in the far infrared and microwave regions. The astronomically important visual to near infrared measurements of solid methane optical constants are conspicuously absent from the literature. Preliminary results are presented on the optical constants of solid methane for the 0.4 to 2.6 micrometer region. Deposition onto a substrate at 10 K produces glassy (semi-amorphous) material. Annealing this material at approximately 33 K for approximately 1 hour results in a crystalline material as seen by sharper, more structured bands and negligible background extinction due to scattering. The constant k is reported for both the amorphous and the crystalline (annealed) states. Typical values (at absorption maxima) are in the .001 to .0001 range. Below lambda = 1.1 micrometers the bands are too weak to be detected by transmission through the films less than or equal to 215 micrometers in thickness, employed in the studies to date. Using previously measured values of the real part of the refractive index, n, of liquid methane at 110 K, n is computed for solid methane using the Lorentz-Lorenz relationship. Work is in progress to extend the measurements of optical constants n and k for liquid and solid to both shorter and longer wavelengths, eventually providing a complete optical constants database for condensed CH4.

Khare, Bishun N.↗
NASA NTRS2011

Infrared Spectra and Optical Constants of Nitrile Ices Relevant to Titan's Atmosphere

Spectra and optical constants of nitrile ices known or suspected to be in Titan?s atmosphere have been determined from 2.0 to 333.3 microns (approx.5000 to 30/cm). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan?s winter pole. Ices studied were: HCN, hydrogen cyanide; C2N2, cyanogen; CH3CN, acetonitrile; C2H5CN, propionitrile; and HC3N, cyanoacetylene. Optical constants were calculated, using Kramers-Kronig analysis, for each nitrile ice?s spectrum measured at a variety of temperatures, in both the amorphous- and crystalline phases. Spectra were also measured for many of the nitriles after quenching at the annealing temperature and compared with those of annealed ices. For each of these molecules we also measured the real component, n, of the refractive index for amorphous and crystalline phases at 670 nm. Several examples of the information contained in these new data sets and their usefulness in modeling Titan?s observed features will be presented (e.g., the broad emission feature at 160/cm; Anderson and Samuelson, 2011).

Anderson, Carrie↗
NASA NTRS1982

Optical constants in the extreme ultraviolet and soft X-ray region

The nature of optical constants and their measurement by reflection or absorption techniques in the extreme ultraviolet and soft X-ray spectral region from 30 to 3000 eV is discussed with emphasis on mirror design. Sources of optical constant data are mentioned and reflectance measurements for SiC and Kanigen between 40 and 200 eV are reported.

Rife, J. C.↗
NASA NTRS1994

Optical constants of liquid and solid methane

The optical constants n(sub r) + in(sub i) of liquid methane and phase 1 solid methane were determined over the entire spectral range by the use of various data sources published in the literature. Kramers-Kronig analyses were performed on the absorption spectra of liquid methane at the boiling point (111 K) and the melting point (90 K) and on the absorption spectra of phase 1 solid methane at the melting point and at 30 K. Measurements of the static dielectric constant at these temperatures and refractive indices determined over limited spectral ranges were used as constraints in the analyses. Applications of methane optical properties to studies of outer solar system bodies are described.

Martonchik, John V.↗
NASA NTRS2023

First Optical Constants of Laboratory-Generated Organic Refractory Materials (Tholins) Produced in the NASA Ames COSmIC Facility from the Visible to the Near Infrared (0.4–1.6 μm): Application to Titan’s Aerosols

We have measured the complex refractive indices, from 0.4 to 1.6μm, of five laboratory-generated organic refractory materials (tholins) produced at low temperature(150 K)using plasma chemistry in the stream of a supersonic expansion in NASA Ames’ COsmic SImulation Chamber(COSmIC)facility. Three samples were produced from N2:CH4gas precursors(with different voltages inducing different degrees of ionization in the plasma), one sample was produced from N2:CH4:C2H2, and one sample was produced from Ar:CH4in order to produce a purely carbonaceous sample. The optical constants, n and k, of the samples were determined using spectral reflectance measurements. We observe that both n and k appear to be correlated with the nitrogen content in the solid sample, with samples containing more nitrogen having higher n and k. Comparisons to previous laboratory studies and Titan aerosol optical constants derived from observations show that the COSmIC tholins with a higher nitrogen content (higher n and k)are closer analogs of Titan aerosols. We also present a new analysis of Cassini Visible Infrared Mapping Spectrometer observations of Titan’s atmosphere in the visible to near infrared using the COSmIC tholin optical constants in a radiative transfer model. The COSmIC tholin sample produced from N2:CH4with the lowest energy level has a spectral behavior that appears well suited to reproduce the observed Titan aerosol properties. This study has therefore demonstrated that this COSmIC tholin sample has valuable and promising optical properties for the analysis of Cassini’s Titan atmospheric observations.

Optical Constants↗