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All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Complex Volcanism at Oppenheimer U Floor-Fractured Crater

Recent remote sensing studies have identified complex volcanism in the floor-fractured crater (FFC) Oppenheimer U, located in the northwest floor of Oppenheimer crater (35.2degS, 166.3degW, 208 km dia., Figure 1) within the "South Pole - Aitken basin" (SPA) region of the lunar far side. Up to 15 sites of pyroclastic volcanism have been identified in the floor of Oppenheimer crater. Studies of Moon Mineralogy Mapper data (M3, 0.4-3 microns, 86 bands, [5]) indicated that the pyroclastic deposits are comprised of mixtures of clinopyroxene and iron-rich glass, with the Oppenheimer U deposit showing variable composition within the FFC and having the most iron-rich volcanic glass thus far identified on the Moon. Here we examine the floor of Oppenheimer U in more detail and show evidence for possible multiple eruptive vents.

Gaddis, L. R.↗
NASA NTRS2013

Joint M3 and Diviner Analysis of the Mineralogy, Glass Composition, and Country Rock Content of Pyroclastic Deposits in Oppenheimer Crater

Here we present our analysis of the near- and mid-infrared spectral properties of pyroclastic deposits within the floor fractured Oppenheimer Crater that are hypothesized to be Vulcanian in origin. These are the first results of our global study of lunar pyroclastic deposits aimed at constraining the range of eruption processes on the Moon. In the near-infrared, we have employed a new method of spectral analysis developed in Horgan et al. (2013) of the 1 m iron absorption band in Chandrayaan-1 Moon Mineralogy Mapper (M3) spectra. By analyzing both the position and shape of the 1 m band we can detect and map the distribution of minerals, glasses, and mixtures of these phases in pyroclastic deposits. We are also using mid-infrared spectra from the Lunar Reconnaissance Orbiter Diviner Lunar Radiometer Experiment to develop ~200 m/pixel Christiansen Feature (CF) maps, which correlate with silica abundance. One of the benefits of using CF maps for analysis of pyroclastic deposits is that they can be used to detect silicic country rock that may have been emplaced by Vulcanian-style eruptions, and are sensitive to iron abundance in glasses, neither of which is possible in the near-infrared. M3 analysis reveals that the primary spectral endmembers are low-calcium pyroxene and iron-bearing glass, with only minor high-calcium pyroxene, and no detectable olivine. The large deposit in the south shows higher and more extensive glass concentrations than the surrounding deposits. We interpret the M3 spectra of the pyroclastic deposits as indicating a mixture of low-calcium pyroxene country rock and juvenile glass, and no significant olivine. Analysis of Diviner CF maps of the Oppenheimer crater floor indicates an average CF value of 8.16, consistent with a mixture of primarily plagioclase and some pyroxene. The average CF values of the pyroclastic deposits range from 8.31 in the SW to 8.24 in the SE. Since CF values within the deposits are as high as 8.49, the lower average CF values of the deposits suggest that each deposit is a mixture of crater floor material and highly mafic juvenile material consistent with either olivine or Fe-bearing pyroclastic glass. Synthesizing our M3 and Diviner results indicates that the crater floor consists of plagioclase with some pyroxene, and the pyroclastic deposits are a mix of this substrate and a glass-rich juvenile material. While we cannot determine the iron content of the glass from M3 spectra alone, the high Diviner CF values suggest that the glass is relatively iron-rich. Indeed, FeO abundances inferred from CF values using the method of Allen et al. (2012) imply that the large southern deposit exhibits a significant enhancement in iron content. This supports our hypothesis that the glass in this deposit is relatively iron-rich.

Bennett, Kristen A.↗
NASA NTRS2014

Inferred Variable FeO Content in Medium-sized Lunar Pyroclastic Deposits from LRO Diviner Data

Lunar pyroclastic deposits (LPDs) are low albedo features that mantle underlying terrain (Gaddis et al. 1985). They are high priority targets for science and exploration as they are believed to originate from and therefore reflect the composition of the deep lunar interior (NRC, 2011). They are also the best potential resource of oxygen out of any Apollo samples (Allen et al. 1996). Historically, LPDs have been divided into regional versus local categories (Gaddis et al. 2003). The large (>1000 km2 area) regional deposits are deeply sourced (>400 km deep) and result from fire fountaining. Small (<1000 km2) local deposits are thought to result from Vulcanian eruptions in which magma is slowly emplaced beneath the surface until enough volatiles exsolve and the high pressure causes an explosion. Bennett et al. (2013) identified a local deposit (674 km2 area) that may have resulted from both Vulcanian activity and fire fountaining. This deposit potentially represents a new intermediate class of LPDs that straddles the interface between the two formation mechanisms. The deposit also exhibits the highest inferred FeO wt.% of any known lunar glass. In this work we investigate the inferred FeO abundances of other medium-sized deposits to characterize this potential new class of deposits and understand the magnitude of variations in inferred FeO among pyroclastic deposits. We use the method of Greenhagen et al. (2010) to calculate the wavelength of the Christiansen Feature (CF) from Lunar Reconnaissance Orbiter Diviner Lunar Radiometer instrument thermal-infrared observations for four medium-sized deposits. From the CF values, we estimate each deposit's FeO abundance using the method of Allen et al. (2012). The four LPDs that we examined (Oppenheimer South, Beer, Cleomedes, and J. Herschel) all have average CF values from 8.22-8.28 microns, corresponding to FeO abundances of approx. 10-15 wt.%. All of these values are within the range and uncertainties of FeO abundances measured in Apollo samples. As previously identified, the Oppenheimer South deposit exhibits an area of enhanced CF values (8.49 microns) that, if the methods of Allen et al. (2012) can be extrapolated, correspond to a highest observed approx. 30 wt.% FeO. Moon Mineralogy Mapper near-infrared spectra indicate that this area is glass-rich as opposed to olivine-rich. While we are still investigating the nature of the high CF wavelength in Oppenheimer South, spatially-resolved observations there and (to a smaller degree) in our other study sites, shows that FeO wt.% can vary within LPDs. Thus, obtaining only the average FeO abundance over a large area may not be adequate to understand global variation. The magnitude of Oppenheimer South's CF variability, if due to actual surface variations rather than calibration artifacts or spectral mixing, could indicate that it is a unique deposit and not part of a new mid-sized class of deposits. The higher value could be a result of its location within the South Pole Aitken Basin and exsolution of more deeply sourced magma due to the thin crust there.

Bennett, K. A.↗
NASA NTRS2002

First Principle Predictions of Isotopic Shifts in H2O

We compute isotope independent first and second order corrections to the Born-Oppenheimer approximation for water and use them to predict isotopic shifts. For the diagonal correction, we use icMRCI wavefunctions and derivatives with respect to mass dependent, internal coordinates to generate the mass independent correction functions. For the non-adiabatic correction, we use scaled SCF/CIS wave functions and a generalization of the Handy method to obtain mass independent correction functions. We find that including the non-adiabatic correction gives significantly improved results compared to just including the diagonal correction when the Born-Oppenheimer potential energy surface is optimized for H2O-16. The agreement with experimental results for deuterium and tritium containing isotopes is nearly as good as our best empirical correction, however, the present correction is expected to be more reliable for higher, uncharacterized levels.

Schwenke, David W.↗
NASA NTRS1972

Collision matrix elements near a pseudocrossing of potential energy curves.

The cross sections of certain inelastic atomic collision processes can be determined from the matrix elements of the collision operator, d/dR, where R is the separation of the colliding atoms. At one extreme, the matrix element may pass through zero near a pseudocrossing of potential energy curves, while at the other extreme, it may pass through a maximum. The resulting cross sections are entirely different in magnitude and in energy dependence. An attempt is made to predict the qualitative behavior of the collision matrix elements with variations in R from an analysis of the Born-Oppenheimer adiabatic Hamiltonian. The modifications caused by a second pseudocrossing with a third adiabatic state are studied.

Oppenheimer, M.↗
NASA NTRS1986

Predicting Two-Dimensional, Unsteady Turbulent Combustion

MIMOC calculates flow field and flame propagation in turbulent combustion tunnel. Program employs algorithm for turbulent combustion modeling described by Ghoniem, Chorin, and Oppenheim. Program used to study flow field in model combustor, formed by rearward-facing step in channel, in terms of vorticity field, velocity field, turbulent shear stresses, flame contours, and concentration field.

Marek, C. J.↗
NASA NTRS1967

The nature of intermolecular forces.

Intermolecular forces theory, considering hydrogen atom interaction through Born- Oppenheimer approximation and variational calculations

ATOMIC COLLISION↗
NASA NTRS1974

Possible H2/+/ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H2(+) 2p pi u - /s sigma g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H2(+) to its 2p pi u state appears to be photoexcitation, principally through absorption of the solar Lyman-alpha line. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H2(+) probe is discussed.

Wu, F.-M.↗
NASA NTRS1974

Rotational-vibrational coupling in the theory of electron-molecule scattering

The adiabatic-nuclei approximation of vibrational-rotational excitation of homonuclear diatomic molecules can be simply augmented to describe the vibrational-rotational coupling by including the dependence of the vibrational wave function on j. Appropriate formulas are given, and the theory, is applied to e-H2 excitation, whereby it is shown that deviations from the simple Born-Oppenheimer approximation measured by Wong and Schultz can be explained. More important, it can be seen that the inclusion of the j-dependent centrifugal term is essential for transitions involving high-rotational quantum numbers.

Temkin, A.↗
NASA NTRS1975

Asymptotic form of the charge-exchange cross section in three-body rearrangement collisions

A three-body general-type rearrangement collision is considered in which the initial and final bound states are described by hydrogen-like wave functions. It is shown that the charge-exchange amplitude in the first Born approximation can be expanded at all incident energies in terms of the inverse powers of the principal quantum number (n). By expanding the exchange amplitude in this way, it is demonstrated conclusively that the cross section for capture into the s, p, and d states as well as for the sum over all the angular-momentum states is proportional to 1/n-cubed plus terms proportional to higher inverse odd powers of n. It is found that the low-lying levels cannot be scaled to the 1/n-cubed law irrespective of the value of the incident energy except in the case of capture into the s states in accordance with the Oppenheimer-Brinkman-Kramers approximation. Zeros and minima in the differential cross sections are given in the limit of high principal quantum number for electron capture by protons from atomic hydrogen and for positronium formation by proton-atomic hydrogen collisions.

Omidvar, K.↗
NASA NTRS1976

Single-electron Born approximations for charge transfer from multielectron atoms to protons

The Born approximation, including the internuclear interaction, is used to compute cross sections for the transfer of one electron from a multielectron atom to an incident proton. When the full internuclear interaction is included, the results lie far above high-energy experimental K-shell data for protons and argon. However, when only enough internuclear interaction is included so that the total projectile-target interaction goes to zero asymptotically in accordance with plane-wave functions actually used, fair agreement at high energies is obtained. The latter form of the Born approximation is compared with data on K-shell capture from helium as well as argon and with the simpler approximation of Oppenheimer and of Brinkman and Kramers (OBK), where no internuclear interaction is included. The OBK results typically lie a factor of 2 to 8 above the data, while the present Born results are within a factor of 2 of most of the existing high-velocity K-shell data.

Omidvar, K.↗
NASA NTRS1975

Molecular spectroscopy and collisional excitation

The paper examines the basic principles underlying the molecular transitions responsible for interstellar molecular spectra. The energy levels of molecules are discussed in detail with special attention given to the Born-Oppenheimer approximation, the electronic Hamiltonian, and the parameters of vibrational and rotational energy. The probabilities for radiative and collisional transitions are calculated. A brief review of techniques for molecular spectroscopy is presented along with methods used to determine collision cross sections on both an experimental and a theoretical basis.

Green, S.↗
NASA NTRS1977

Charge-equilibrium and radiation of low-energy cosmic rays passing through interstellar medium

The charge equilibrium and radiation of an oxygen and an iron beam in the MeV per nucleon energy range, representing a typical beam of low-energy cosmic rays passing through the interstellar medium, is considered. Electron loss of the beam has been taken into account by means of the First Born approximation allowing for the target atom to remain unexcited, or to be excited to all possible states. Electron capture cross sections have been calculated by means of the scaled Oppenheimer-Brinkman-Kramers approximation, taking into account all atomic shells of the target atoms. Radiation of the beam due to electron capture into the excited states of the ion, collisional excitation and collisional inner-shell ionization of the ions has been considered. Effective X-ray production cross sections and multiplicities for the most energetic X-ray lines emitted by the Fe and O beams have been calculated.

Rule, D. W.↗