Materials Data on TlPt3O4 by Materials Project
TlTl(Pt3O4)2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four thallium molecules and one Tl(Pt3O4)2 framework. In the Tl(Pt3O4)2 framework, Pt+2.33+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Pt–O bond lengths are 2.05 Å. Tl1+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Tl–O bond lengths are 2.42 Å. O2- is bonded to three equivalent Pt+2.33+ and one Tl1+ atom to form a mixture of distorted edge and corner-sharing OTlPt3 tetrahedra.
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