Use of a time-sharing computer in nuclear chemistry.
Computer-analyzer system for nuclear chemistry, noting advantage of on-line data acquisition and analysis coupled with time sharing economy
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Computer-analyzer system for nuclear chemistry, noting advantage of on-line data acquisition and analysis coupled with time sharing economy
Radioactive age determination and isotopic composition analyses on rocks, meteorites, and lunar samples
Concentrations of primordial radioelements and of cosmogenic radionuclides in crystalline rocks, breccias, and soils from the Ocean of Storms were determined. Concentrations of K, Th, U, Al-26, and Na-22 were determined for seven clastic or brecciated rocks, three sieved samples of fines, and one composite sample of sawdust from the cutting of a fragmental rock, all from samples obtained on the Apollo 14 mission. The K, Th, and U concentrations and cogmogenic radionuclide abundances in rocks and soils from Apollo 15 are also discussed.
Primordial and cosmogenic radionuclide concentrations are determined nondestructively by gamma-ray spectrometry in soil and rock samples from the returned Apollo 17 sample collection from Taurus-Littrow and Descartes. Geochemical evidence in support of field geology speculation concerning layering of the subfloor basalt flows is demonstrated along with a possible correlation of magmatic fractionation of K/U as a function of depth. The pattern of radionuclide concentrations observed in these samples is distinct due to proton bombardment by the intense solar flares of August 4-9, 1972. Such radionuclide determinations are used in determining lunar sample orientation and characterizing solar flare activity.
Nondestructive medical and biologic nuclear activation analysis by computer-coupled automatic system, noting feasibility of operation
Nucleosynthesis of D, Li, Be and B by high- energy solar particles during early history of solar system in nuclear spallation model
Preliminary proton nuclear magnetic resonance (NMR) studies were made to determine the applicability of this technique for the study of interactions between monomeric and polymeric amino acids with monomeric nucleic acid bases and nucleotides. Proton NMR results for aqueous solutions (D2O) demonstrated interactions between the bases cytosine and adenine and acidic and aromatic amino acids. Solutions of 5'-AMP admixed with amino acids exhibited more complex behavior but stacking between aromatic rings and destacking at high amino acids concentration was evident. The multisite nature of 5'-AMP was pointed out. Chemical shift changes for adenine and 5'-AMP with three water soluble polypeptides demonstrated that significant interactions exist. It was found that the linewidth-pH profile of each amino acid is unique. It is concluded that NMR techniques can give significant and quantitative data on the association of amino acid and nucleic acid constituents.
Both NASA and Google have explored and funded Low Energy Nuclear Reaction (LENR) aka Solid-State Fusion or Lattice Confinement Fusion (LCF) research. NASA has funded efforts since 1989, and Google Research began in 2014. Google, and researchers initially-funded by Google, published significant scientific papers in Nature, Nature Communications and the Journal of Applied Physics. NASA began a significant set of LENR-triggering programs in 2012 resulting in papers in Physical Review C, the Journal of Electroanalytical Chemistry and the Journal of Condensed Matter Nuclear Science. Both NASA and Google engaged researchers across fields of nuclear physics, chemistry, electrochemistry, material science and more. NASA built upon early novel gas pumping experiments then followed the patented work of the US Navy SPAWAR (US8,419,919, “System and Method to Generate Particles”) and experiments with the Naval Surface Warfare Centers. Google supported researchers at Lawrence Berkeley National Laboratory (LBNL), the University of British Columbia (UBC), MIT and others. This resulted in patent applications and two granted patents (US10264661B2, “Target structure for enhanced electron screening” and US10566094B2 “Enhanced electron screening through plasmon oscillations”). These separate efforts, unknown to the researchers at the time, provided the impetus for the DoE ARPA-E LENR program followed by the DARPA DSO “Mechanisms for Amplification of Fusion Reaction Rates in Solids” (MARRS) program. This document briefly describes the overlapping NASA and Google Research efforts in plasma loading and electron screening emphasizing the results of the latest paper in Nature Communications. The papers and patents cited are listed.
Hydrogen solubility in eutectic sodium-potassium mixture, noting usefulness as nuclear reactor coolants, and dependence on pressure and temperature variations
Future gravitational wave antennas will be approximately 100 kilogram cylinders, whose end-to-end vibrations must be measured so accurately (10 to the -19th power centimeters) that they behave quantum mechanically. Moreover, the vibration amplitude must be measured over and over again without perturbing it (quantum nondemolition measurement). This contrasts with quantum chemistry, quantum optics, or atomic, nuclear, and elementary particle physics where measurements are usually made on an ensemble of identical objects, and care is not given to whether any single object is perturbed or destroyed by the measurement. Electronic techniques required for quantum nondemolition measurements are described as well as the theory underlying them.
Book and document information list - astrophysics, atmospherics, biology, nuclear physics, missile technology, navigation, electronics, chemistry, materials, mathematics, and other topics
Polymer molecular structure, discussing concentration of primary and secondary hydroxyl groups, use of NMR to establish stereo and positional isomeric configuration, etc
The significance of gas phase reactions in determining the nuclear structure of comets is discussed. The sublimation of parent molecules such as H2O, CH4, CO2, and NH3 from the surface of the nucleus and their subsequent photodissociation and ionization in forming observed cometary molecular species are elaborated.
The paper discusses physical processes in comets which involve solar and nuclear radial forces that affect the motions of gases and icy grains, gas-phase chemistry very close to the nuclei of large comets near the sun, sublimation of icy grains, dissociation of parent molecules into radicals and of radicals into atoms, and ionization by sunlight and collisions. The composition and dimensions of nuclei are examined along with variations in intrinsic brightness, the nature of volatiles, gas production rates in the coma, characteristics of icy grains in the coma, and the structure of streamers, ion tails, and dust tails. The structure of the coma is described in detail on the basis of spectroscopic observations of several comets. The origin of comets is briefly reviewed together with the relation of comets to earth, the interplanetary complex, and the interstellar medium. Desirable future observations are noted, especially by space missions to comets.
Numerous investigations have been undertaken on samples from the Apollo 16 deep drill core. These studies are diverse in character and range from grain size analyses, through chemical and mineralogical studies to investigations of nuclear particle tracks, rare gases, and isotopic abundances. In order to comprehend the significance of the studies of the mineral chemistry of the clasts below 1 mm in size in several samples with respect to other studies, it became obvious that a review of all previous works was desireable. After reviewing the available literature it can be concluded that only four major stratigraphic divisions exist in the core section. Whether these represent four single events or multi-stage events within one unit is uncertain; however, it appears that accumulation of the material in the core has taken place during a period of 1 billion years, and that the material is predominantly of locally derived Highlands origin.
Measurements of ozone and nitric oxide in a nuclear cloud 7 days after the explosion are reported. No measurable increase above ambient density of either ozone or nitric oxide was found. Results from a chemistry model of the cloud do not agree with the measurement unless 'nonstandard' assumptions are made with regard to the operating chemical processes. A number of possible explanations of the results are discussed.
Two different topics which only relate in that they are pertinent to lithium thionyl chloride battery safety are discussed. The first topic is a hazards analysis of a system (risk assessment), a formal approach that is used in nuclear engineering, predicting oil spills, etc. It is a formalized approach for obtaining assessment of the degree of risk associated with the use of any particular system. The second topic is a small piece of chemistry related to the explosions that can occur with lithium thionyl chloride systems. After the two topics are presented, a discussion is generated among the Workshop participants.
Simulated nuclear fuel element specimens, consisting of uranium mononitride (UN) fuel cylinders clad with tungsten-lined T-111, were exposed for up to 7500 hr at 1040 C (1900 F) in a pumped-lithium loop. The lithium flow velocity was 1.5 m/sec (5 ft/sec) in the specimen test section. No evidence of any compatibility problems between the specimens and the flowing lithium was found based on appearance, weight change, chemistry, and metallography. Direct exposure of the UN to the lithium through a simulated cladding crack resulted in some erosion of the UN in the area of the defect. The T-111 cladding was ductile after lithium exposure, but it was sensitive to hydrogen embrittlement during post-test handling.