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Materials Data on Pm3Np by Materials Project

NpPm3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Np is bonded to twelve equivalent Pm atoms to form NpPm12 cuboctahedra that share corners with six equivalent NpPm12 cuboctahedra, corners with twelve equivalent PmPm8Np4 cuboctahedra, edges with eighteen equivalent PmPm8Np4 cuboctahedra, faces with eight equivalent NpPm12 cuboctahedra, and faces with twelve equivalent PmPm8Np4 cuboctahedra. There are six shorter (3.52 Å) and six longer (3.58 Å) Np–Pm bond lengths. Pm is bonded to four equivalent Np and eight equivalent Pm atoms to form PmPm8Np4 cuboctahedra that share corners with four equivalent NpPm12 cuboctahedra, corners with fourteen equivalent PmPm8Np4 cuboctahedra, edges with six equivalent NpPm12 cuboctahedra, edges with twelve equivalent PmPm8Np4 cuboctahedra, faces with four equivalent NpPm12 cuboctahedra, and faces with sixteen equivalent PmPm8Np4 cuboctahedra. There are a spread of Pm–Pm bond distances ranging from 3.53–3.64 Å.

36 MATERIALS SCIENCE↗

Materials Data on PmNp by Materials Project

NpPm is Magnesium-derived structured and crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Np is bonded to six equivalent Np and six equivalent Pm atoms to form NpPm6Np6 cuboctahedra that share corners with eighteen equivalent NpPm6Np6 cuboctahedra, edges with six equivalent NpPm6Np6 cuboctahedra, edges with twelve equivalent PmPm6Np6 cuboctahedra, faces with eight equivalent NpPm6Np6 cuboctahedra, and faces with twelve equivalent PmPm6Np6 cuboctahedra. All Np–Np bond lengths are 3.37 Å. All Np–Pm bond lengths are 3.55 Å. Pm is bonded to six equivalent Np and six equivalent Pm atoms to form PmPm6Np6 cuboctahedra that share corners with eighteen equivalent PmPm6Np6 cuboctahedra, edges with six equivalent PmPm6Np6 cuboctahedra, edges with twelve equivalent NpPm6Np6 cuboctahedra, faces with eight equivalent PmPm6Np6 cuboctahedra, and faces with twelve equivalent NpPm6Np6 cuboctahedra. All Pm–Pm bond lengths are 3.37 Å.

36 MATERIALS SCIENCE↗