Results for “NiC2(SN3)2”

Materials Data on NiC2(SN3)2 by Materials Project

NiC2(N3S)2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two NiC2(N3S)2 clusters. Ni2+ is bonded in an octahedral geometry to six N1- atoms. There is two shorter (1.81 Å) and four longer (1.92 Å) Ni–N bond length. C4+ is bonded in a distorted linear geometry to one N1- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.59 Å. There are two inequivalent N1- sites. In the first N1- site, N1- is bonded in a single-bond geometry to one Ni2+ atom. In the second N1- site, N1- is bonded in a linear geometry to one Ni2+ and one C4+ atom. S2- is bonded in a distorted single-bond geometry to one C4+ atom.