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Materials Data on Tb5NiPb3 by Materials Project

Tb5NiPb3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded in a 7-coordinate geometry to two equivalent Ni and five equivalent Pb atoms. Both Tb–Ni bond lengths are 2.77 Å. There are a spread of Tb–Pb bond distances ranging from 3.20–3.67 Å. In the second Tb site, Tb is bonded in a 6-coordinate geometry to six equivalent Pb atoms. All Tb–Pb bond lengths are 3.28 Å. Ni is bonded to six equivalent Tb atoms to form face-sharing NiTb6 octahedra. Pb is bonded in a 9-coordinate geometry to nine Tb atoms.

36 MATERIALS SCIENCE↗

Materials Data on Tb12Ni6Pb by Materials Project

Tb12Ni6Pb crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Tb is bonded in a 1-coordinate geometry to four equivalent Ni and one Pb atom. There are a spread of Tb–Ni bond distances ranging from 2.65–3.50 Å. The Tb–Pb bond length is 3.48 Å. Ni is bonded in a 2-coordinate geometry to eight equivalent Tb and one Ni atom. The Ni–Ni bond length is 2.38 Å. Pb is bonded in a cuboctahedral geometry to twelve equivalent Tb atoms.

36 MATERIALS SCIENCE↗