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DOE OSTI2020

Materials Data on Ni(AgO)2 by Materials Project

Ag2NiO2 is Calaverite-derived structured and crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three Ag2NiO2 sheets oriented in the (0, 0, 1) direction. Ni2+ is bonded to six equivalent O2- atoms to form edge-sharing NiO6 octahedra. All Ni–O bond lengths are 2.06 Å. Ag1+ is bonded in a 3-coordinate geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.42 Å. O2- is bonded to three equivalent Ni2+ and three equivalent Ag1+ atoms to form a mixture of edge and corner-sharing ONi3Ag3 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Confined Ni-In intermetallic alloy nanocatalyst with excellent coking resistance for methane dry reforming

Carbon dioxide and methane are two main greenhouse gases which are contributed to serious global warming. Fortunately, dry reforming of methane (DRM), a very important reaction developed decades ago, can convert these two major greenhouse gases into value-added syngas or hydrogen. The main problem retarding its industrialization is the seriously coking formation upon the nickel-based catalysts. Herein, a series of confined indium-nickel (In-Ni) intermetallic alloy nanocatalysts (In x Ni@SiO 2 ) have been prepared and displayed superior coking resistance for DRM reaction. The sample containing 0.5 wt.% of In loading (In 0.5 Ni@SiO 2 ) shows the best balance of carbon deposition resistance and DRM reactivity even after 430 h long term stability test. The boosted carbon resistance can be ascribed to the confinement of core–shell structure and to the transfer of electrons from Indium to Nickel in In-Ni intermetallic alloys due to the smaller electronegativity of In. Additionally, both the silica shell and the increase of electron cloud density on metallic Ni can weaken the ability of Ni to activate C–H bond and decrease the deep cracking process of methane. The reaction over the confined InNi intermetallic alloy nanocatalyst was conformed to the Langmuir-Hinshelwood (L-H) mechanism revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy (in-situ DRIFTS). This work provides a guidance to design high performance coking resistance catalysts for methane dry reforming to efficiently utilize these two main greenhouse gases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Report on Retrieval of the Reactor Pressure Vessel A-60 Surveillance Capsule from Palisades Nuclear Generating Station

Located on the shores of Lake Michigan, the Palisades Nuclear Generating Station (PNGS) was a nuclear power plant that operated in Covert Township, Michigan. The plant had a single pressurized water reactor that produced electricity for the region. The PNGS was shut down in 2022 after more than four decades of service. The PNGS included in its surveillance program a surveillance capsule, designated A-60, containing specimens of a weld metal with nickel content of about 1.36 wt% and copper content of about 0.20 wt%. The capsule was removed from its surveillance position in the early 1995 and has been resident in the spent fuel pool since that time. This capsule was irradiated to a fluence of 1.87×10 20 n/cm 2 (E> 1MeV) that is equivalent for more than 120 effective full power year (EFPY) for the US reactor pressure vessel (RPV) fleet. The material is also of special interest because of its very high nickel content and potential for development of NiMnSi (nickel-manganese-silicon) precipitates. Combination of very high fluence and very high Ni and Cu content makes the material in this capsule of the great interest as benchmark for currently developing embrittlement trend curves (ETC) aiming to predict embrittlement at high fluences. Thus, several years ago the Light Water Reactor Sustainability Program (LWRSP) initiated negotiations with Entergy to harvest this high fluence capsule since it did not present any regulatory interest for PNGS but could play a very important role for LWRSP efforts for developing ETC for very long-term operation. The negotiations resumed once PNGS ownership moved to the Holtec International in June 2022 which was very supportive to the LWRSP efforts to harvest the A-60 capsule from the spent fuel pool. As a result, the contract was placed with the Westinghouse Electric Company (WEC) to come to PNGS site, retrieve the A-60 capsule, bring it to WEC Churchill hot cell facility, open the capsule and send all surveillance specimens in the capsule to ORNL for future characterization. These specimens from the PNGS A-60 capsule have arrived to ORNL in July 2023 and this report summarizes activities to retrieve and deliver specimens to ORNL site for future evaluation.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗