Materials Data on NbSNCl6 by Materials Project
NbCl5NSCl crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four niobium(v) chloride molecules and four NSCl clusters. In each NSCl cluster, N3+ is bonded in a single-bond geometry to one S2- atom. The N–S bond length is 1.46 Å. S2- is bonded in a distorted bent 120 degrees geometry to one N3+ and one Cl1- atom. The S–Cl bond length is 2.14 Å. Cl1- is bonded in a single-bond geometry to one S2- atom.
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