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NbRh is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. Nb is bonded in a 12-coordinate geometry to eight equivalent Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.77–2.88 Å. Rh is bonded in a 12-coordinate geometry to eight equivalent Nb atoms.
NbRh is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Nb is bonded to eight equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. All Nb–Rh bond lengths are 2.81 Å. Rh is bonded to eight equivalent Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra.
NbRh is Tetraauricupride-like structured and crystallizes in the monoclinic P2/m space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded in a 12-coordinate geometry to eight Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.76–2.88 Å. In the second Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted edge, corner, and face-sharing NbRh8 cuboctahedra. There are four shorter (2.80 Å) and four longer (2.84 Å) Nb–Rh bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted edge, corner, and face-sharing RhNb8 cuboctahedra. In the second Rh site, Rh is bonded in a 12-coordinate geometry to eight Nb atoms.
NbRh is Tetraauricupride-like structured and crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. There are six shorter (2.80 Å) and two longer (2.85 Å) Nb–Rh bond lengths. In the second Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. There are a spread of Nb–Rh bond distances ranging from 2.79–2.83 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra. In the second Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra.