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TiNb2W crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiNb2W ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Nb atoms. Both Ti–Nb bond lengths are 2.33 Å. Nb is bonded in a linear geometry to one Ti and one W atom. The Nb–W bond length is 2.30 Å. W is bonded in a linear geometry to two equivalent Nb atoms.
TiNbW2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiNbW2 ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent W atoms. Both Ti–W bond lengths are 2.30 Å. Nb is bonded in a linear geometry to two equivalent W atoms. Both Nb–W bond lengths are 2.29 Å. W is bonded in a linear geometry to one Ti and one Nb atom.