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NbWTc2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbWTc2 ribbons oriented in the (1, 0, 0) direction. Nb4+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both Nb–Tc bond lengths are 2.25 Å. W2+ is bonded in a linear geometry to two equivalent Tc3- atoms. Both W–Tc bond lengths are 2.26 Å. Tc3- is bonded in a linear geometry to one Nb4+ and one W2+ atom.
Nb2WTc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2WTc ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one W and one Tc atom. The Nb–W bond length is 2.34 Å. The Nb–Tc bond length is 2.25 Å. W is bonded in a linear geometry to two equivalent Nb atoms. Tc is bonded in a linear geometry to two equivalent Nb atoms.
NbW2Tc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbW2Tc ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent W atoms. Both Nb–W bond lengths are 2.32 Å. W is bonded in a linear geometry to one Nb and one Tc atom. The W–Tc bond length is 2.24 Å. Tc is bonded in a linear geometry to two equivalent W atoms.