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NbRh is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. Nb is bonded in a 12-coordinate geometry to eight equivalent Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.77–2.88 Å. Rh is bonded in a 12-coordinate geometry to eight equivalent Nb atoms.
Nb3Rh crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Nb is bonded in a 6-coordinate geometry to two equivalent Nb and four equivalent Rh atoms. Both Nb–Nb bond lengths are 2.59 Å. All Nb–Rh bond lengths are 2.90 Å. Rh is bonded to twelve equivalent Nb atoms to form a mixture of face and edge-sharing RhNb12 cuboctahedra.
NbRh is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Nb is bonded to eight equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. All Nb–Rh bond lengths are 2.81 Å. Rh is bonded to eight equivalent Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra.
Rh3Nb is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Nb is bonded to twelve equivalent Rh atoms to form NbRh12 cuboctahedra that share corners with twelve equivalent NbRh12 cuboctahedra, edges with twenty-four equivalent RhNb4Rh8 cuboctahedra, faces with six equivalent NbRh12 cuboctahedra, and faces with twelve equivalent RhNb4Rh8 cuboctahedra. All Nb–Rh bond lengths are 2.77 Å. Rh is bonded to four equivalent Nb and eight equivalent Rh atoms to form distorted RhNb4Rh8 cuboctahedra that share corners with twelve equivalent RhNb4Rh8 cuboctahedra, edges with eight equivalent NbRh12 cuboctahedra, edges with sixteen equivalent RhNb4Rh8 cuboctahedra, faces with four equivalent NbRh12 cuboctahedra, and faces with fourteen equivalent RhNb4Rh8 cuboctahedra. All Rh–Rh bond lengths are 2.77 Å.
NbRh is Tetraauricupride-like structured and crystallizes in the monoclinic P2/m space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded in a 12-coordinate geometry to eight Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.76–2.88 Å. In the second Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted edge, corner, and face-sharing NbRh8 cuboctahedra. There are four shorter (2.80 Å) and four longer (2.84 Å) Nb–Rh bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted edge, corner, and face-sharing RhNb8 cuboctahedra. In the second Rh site, Rh is bonded in a 12-coordinate geometry to eight Nb atoms.
Rh3Nb is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Nb is bonded to twelve Rh atoms to form NbRh12 cuboctahedra that share corners with six equivalent NbRh12 cuboctahedra, corners with twelve equivalent RhNb4Rh8 cuboctahedra, edges with eighteen RhNb4Rh8 cuboctahedra, faces with eight equivalent NbRh12 cuboctahedra, and faces with twelve RhNb4Rh8 cuboctahedra. There are six shorter (2.76 Å) and six longer (2.78 Å) Nb–Rh bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to four equivalent Nb and eight equivalent Rh atoms to form distorted RhNb4Rh8 cuboctahedra that share corners with four equivalent NbRh12 cuboctahedra, corners with fourteen RhNb4Rh8 cuboctahedra, edges with six equivalent NbRh12 cuboctahedra, edges with twelve equivalent RhNb4Rh8 cuboctahedra, faces with four equivalent NbRh12 cuboctahedra, and faces with sixteen RhNb4Rh8 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.73–2.82 Å. In the second Rh site, Rh is bonded to four equivalent Nb and eight Rh atoms to form distorted RhNb4Rh8 cuboctahedra that share corners with four equivalent NbRh12 cuboctahedra, corners with fourteen RhNb4Rh8 cuboctahedra, edges with six equivalent NbRh12 cuboctahedra, edges with twelve RhNb4Rh8 cuboctahedra, faces with four equivalent NbRh12 cuboctahedra, and faces with sixteen RhNb4Rh8 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.73–2.82 Å.
NbRh is Tetraauricupride-like structured and crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. There are six shorter (2.80 Å) and two longer (2.85 Å) Nb–Rh bond lengths. In the second Nb site, Nb is bonded to eight Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. There are a spread of Nb–Rh bond distances ranging from 2.79–2.83 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra. In the second Rh site, Rh is bonded to eight Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra.
NbRh2 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded in a 12-coordinate geometry to nine Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.70–2.82 Å. In the second Nb site, Nb is bonded in a 9-coordinate geometry to nine Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.68–2.86 Å. There are four inequivalent Rh sites. In the first Rh site, Rh is bonded to six Nb atoms to form a mixture of distorted edge, corner, and face-sharing RhNb6 cuboctahedra. In the second Rh site, Rh is bonded to four Nb atoms to form a mixture of distorted edge and corner-sharing RhNb4 cuboctahedra. In the third Rh site, Rh is bonded to six Nb atoms to form distorted RhNb6 cuboctahedra that share corners with ten RhNb4 cuboctahedra, edges with nine RhNb6 cuboctahedra, and faces with four RhNb6 cuboctahedra. In the fourth Rh site, Rh is bonded in a distorted water-like geometry to two Nb atoms.
NbRh2 crystallizes in the monoclinic P2/m space group. The structure is three-dimensional. Nb is bonded in a 12-coordinate geometry to nine Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.74–2.80 Å. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded to six equivalent Nb atoms to form a mixture of distorted corner, edge, and face-sharing RhNb6 cuboctahedra. In the second Rh site, Rh is bonded to four equivalent Nb atoms to form a mixture of distorted corner and edge-sharing RhNb4 cuboctahedra. In the third Rh site, Rh is bonded in a distorted linear geometry to two equivalent Nb atoms.
Nb4Rh crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded in a 2-coordinate geometry to two equivalent Nb and two equivalent Rh atoms. Both Nb–Nb bond lengths are 2.89 Å. Both Nb–Rh bond lengths are 2.71 Å. In the second Nb site, Nb is bonded in a distorted body-centered cubic geometry to eight Nb atoms. There are four shorter (2.84 Å) and two longer (2.91 Å) Nb–Nb bond lengths. Rh is bonded in a 12-coordinate geometry to four equivalent Nb atoms.
Rh3Nb is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Nb sites. In the first Nb site, Nb is bonded to twelve Rh atoms to form NbRh12 cuboctahedra that share corners with twelve NbRh12 cuboctahedra, edges with eighteen equivalent RhNb4Rh8 cuboctahedra, faces with six equivalent NbRh12 cuboctahedra, and faces with six equivalent RhNb4Rh8 cuboctahedra. All Nb–Rh bond lengths are 2.77 Å. In the second Nb site, Nb is bonded to twelve Rh atoms to form NbRh12 cuboctahedra that share corners with six equivalent RhNb4Rh8 cuboctahedra, corners with nine NbRh12 cuboctahedra, edges with twelve equivalent RhNb4Rh8 cuboctahedra, faces with seven NbRh12 cuboctahedra, and faces with nine equivalent RhNb4Rh8 cuboctahedra. There are a spread of Nb–Rh bond distances ranging from 2.72–2.82 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to four Nb and eight Rh atoms to form distorted RhNb4Rh8 cuboctahedra that share corners with two equivalent NbRh12 cuboctahedra, corners with ten equivalent RhNb4Rh8 cuboctahedra, edges with seven NbRh12 cuboctahedra, edges with eight equivalent RhNb4Rh8 cuboctahedra, faces with four NbRh12 cuboctahedra, and faces with ten equivalent RhNb4Rh8 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.74–2.78 Å. In the second Rh site, Rh is bonded in a distorted see-saw-like geometry to four Nb and four equivalent Rh atoms.