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Nb2VRe crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2VRe ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one V and one Re atom. The Nb–V bond length is 2.33 Å. The Nb–Re bond length is 2.24 Å. V is bonded in a linear geometry to two equivalent Nb atoms. Re is bonded in a linear geometry to two equivalent Nb atoms.
NbV2Re crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbV2Re ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent V atoms. Both Nb–V bond lengths are 2.20 Å. V is bonded in a linear geometry to one Nb and one Re atom. The V–Re bond length is 2.22 Å. Re is bonded in a linear geometry to two equivalent V atoms.
NbVRe crystallizes in the orthorhombic Fmm2 space group. The structure is three-dimensional. Nb is bonded in a 8-coordinate geometry to six equivalent Nb, four equivalent V, and four equivalent Re atoms. There are four shorter (2.76 Å) and two longer (3.13 Å) Nb–Nb bond lengths. There are two shorter (2.75 Å) and two longer (3.20 Å) Nb–V bond lengths. There are two shorter (2.78 Å) and two longer (3.23 Å) Nb–Re bond lengths. V is bonded in a 2-coordinate geometry to four equivalent Nb and two equivalent Re atoms. Both V–Re bond lengths are 2.56 Å. Re is bonded in a 4-coordinate geometry to four equivalent Nb and two equivalent V atoms.
NbVRe2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbVRe2 ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent Re atoms. Both Nb–Re bond lengths are 2.26 Å. V is bonded in a linear geometry to two equivalent Re atoms. Both V–Re bond lengths are 2.13 Å. Re is bonded in a linear geometry to one Nb and one V atom.