Materials Data on NaUF6 by Materials Project
NaUF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Na1+ is bonded to six equivalent F1- atoms to form NaF6 octahedra that share corners with six equivalent UF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Na–F bond lengths are 2.34 Å. U5+ is bonded to six equivalent F1- atoms to form UF6 octahedra that share corners with six equivalent NaF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All U–F bond lengths are 2.09 Å. F1- is bonded in a linear geometry to one Na1+ and one U5+ atom.
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