Materials Data on NaTl3O6 by Materials Project
NaTl2O4TlO2 crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two thallium molecules; four water molecules; and one NaTl2O4 sheet oriented in the (0, 0, 1) direction. In the NaTl2O4 sheet, Na is bonded in a square co-planar geometry to four equivalent O atoms. All Na–O bond lengths are 2.29 Å. Tl is bonded in a linear geometry to two equivalent O atoms. Both Tl–O bond lengths are 1.91 Å. O is bonded in a linear geometry to one Na and one Tl atom.
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