Materials Data on NaLiO by Materials Project
NaLiO crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Na1+ is bonded to six equivalent O2- atoms to form a mixture of distorted face, edge, and corner-sharing NaO6 cuboctahedra. There are four shorter (2.54 Å) and two longer (2.62 Å) Na–O bond lengths. Li1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There is two shorter (1.94 Å) and one longer (1.95 Å) Li–O bond length. O2- is bonded in a distorted trigonal planar geometry to six equivalent Na1+ and three equivalent Li1+ atoms.
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