Materials Data on NaBrO2 by Materials Project
NaO2Br crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Na is bonded in a body-centered cubic geometry to eight equivalent O atoms. All Na–O bond lengths are 2.66 Å. O is bonded to four equivalent Na and two equivalent Br atoms to form a mixture of edge, face, and corner-sharing ONa4Br2 octahedra. The corner-sharing octahedra tilt angles range from 0–66°. Both O–Br bond lengths are 2.04 Å. Br is bonded in a square co-planar geometry to four equivalent O atoms.
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