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Materials Data on RbVN2 by Materials Project

RbVN2 crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. Rb1+ is bonded in a 4-coordinate geometry to eight equivalent N3- atoms. There are four shorter (3.22 Å) and four longer (3.45 Å) Rb–N bond lengths. V5+ is bonded to four equivalent N3- atoms to form corner-sharing VN4 tetrahedra. All V–N bond lengths are 1.81 Å. N3- is bonded in a distorted linear geometry to four equivalent Rb1+ and two equivalent V5+ atoms.

36 MATERIALS SCIENCE↗