Materials Data on Mo2S4N by Materials Project
Mo2NS4 crystallizes in the tetragonal I4/m space group. The structure is three-dimensional. Mo+5.50+ is bonded to four equivalent S2- atoms to form edge-sharing MoS4 tetrahedra. All Mo–S bond lengths are 2.28 Å. N3- is bonded in a square co-planar geometry to four equivalent S2- atoms. All N–S bond lengths are 3.63 Å. S2- is bonded in a 2-coordinate geometry to two equivalent Mo+5.50+ and one N3- atom.
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