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Hot Hydrogen Testing of W-coated dUN Kernels for Nuclear Thermal Propulsion

Tungsten-coated kernels of uranium nitride (UN) are a possible reactor fuel component for nuclear thermal propulsion. Hot hydrogen testing of such kernels (approx. 250μm diameter, coating thickness 5μm) has been performed at temperatures from 1800°C to 2300°C for 30min each, using depleted uranium nitride (dUN). In addition to direct observations and mass loss measurements, the samples were analyzed by XRD and SEM/EDS after each run. Decomposition of dUN and the formation of molten uranium happened at all temperatures tested with reaction rates increasing with temperature, despite the tungsten coating. At 2300°C, the kernels disintegrated and molten uranium seeped through the wall and bottom of the tungsten crucible employed. These hot hydrogen tests allowed to test the integrity of the tungsten coating and addressed the operating limits of the loose tungsten-coated dUN kernels. Improved results are expected upon consolidation of the tungsten-coated dUN kernels in a Mo-W alloy matrix.

nuclear fuels↗

Materials Data on MoW by Materials Project

WMo is beta Np-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two WMo sheets oriented in the (0, 1, 0) direction. W is bonded in a 8-coordinate geometry to four equivalent Mo atoms. All W–Mo bond lengths are 2.75 Å. Mo is bonded in a 8-coordinate geometry to four equivalent W atoms.

36 MATERIALS SCIENCE↗