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Ti2VMo crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ti2VMo ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to one V and one Mo atom. The Ti–V bond length is 2.63 Å. The Ti–Mo bond length is 2.15 Å. V is bonded in a linear geometry to two equivalent Ti atoms. Mo is bonded in a linear geometry to two equivalent Ti atoms.
TiV2Mo crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiV2Mo ribbons oriented in the (0, 1, 0) direction. Ti is bonded in a linear geometry to two equivalent V atoms. Both Ti–V bond lengths are 2.50 Å. V is bonded in a linear geometry to one Ti and one Mo atom. The V–Mo bond length is 2.92 Å. Mo is bonded in a linear geometry to two equivalent V atoms.
TiVMo2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiVMo2 ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Mo atoms. Both Ti–Mo bond lengths are 2.20 Å. V is bonded in a linear geometry to two equivalent Mo atoms. Both V–Mo bond lengths are 2.24 Å. Mo is bonded in a linear geometry to one Ti and one V atom.