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Alkali Metal Thermoelectric Conversion (AMTEC) for space nuclear power systems

Performance parameters of the Alkali Metal Thermoelectric Converter (AMTEC) for a 100 kW electric power system have been calculated at four technological levels assuming a heat pipe-cooled nuclear reactor heat source. The most advanced level considered would operate between 1180 K converter temperature and 711 K radiator temperature at 16 percent efficiency, and would weigh 1850 kg with a radiator area of 43 sq m. In addition, electrode research studies for the AMTEC systems have been conducted utilizing an experimental test cell of Bankston et al. (1983) and Mo and several Mo-Ti electrodes. It was found that the Mo-Ti electrodes offered no improvement in lifetime characteristics over the pure Mo electrodes, however, oxygen treatment of a degraded Mo electrode restored its specific power output to 90 percent of its original specific power and maintained this level for 60 hr, thus offering a potential for lifetime stability.

Bankston, C. P.↗

Materials Data on TiMo by Materials Project

TiMo crystallizes in the orthorhombic Imma space group. The structure is one-dimensional and consists of two TiMo ribbons oriented in the (0, 1, 0) direction. Ti is bonded in a distorted T-shaped geometry to three equivalent Mo atoms. There are one shorter (2.59 Å) and two longer (2.62 Å) Ti–Mo bond lengths. Mo is bonded in a distorted T-shaped geometry to three equivalent Ti atoms.

36 MATERIALS SCIENCE↗

Materials Data on TiMo3 by Materials Project

TiMo3 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two TiMo3 sheets oriented in the (0, 0, 1) direction. Ti is bonded in a distorted body-centered cubic geometry to eight Mo atoms. There are four shorter (2.73 Å) and four longer (2.79 Å) Ti–Mo bond lengths. There are two inequivalent Mo sites. In the first Mo site, Mo is bonded in a 10-coordinate geometry to two equivalent Ti atoms. In the second Mo site, Mo is bonded in a 8-coordinate geometry to four equivalent Ti atoms.

36 MATERIALS SCIENCE↗