Materials Data on Tl(TeMo)3 by Materials Project
(MoTe)3Tl crystallizes in the hexagonal P6_3/m space group. The structure is one-dimensional and consists of two thallium molecules and one MoTe ribbon oriented in the (0, 0, 1) direction. In the MoTe ribbon, Mo is bonded in a 10-coordinate geometry to six equivalent Mo and four equivalent Te atoms. There are two shorter (2.67 Å) and four longer (2.78 Å) Mo–Mo bond lengths. There are two shorter (2.84 Å) and two longer (2.89 Å) Mo–Te bond lengths. Te is bonded in a 4-coordinate geometry to four equivalent Mo atoms.
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