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TiTaMo2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiTaMo2 ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Mo atoms. Both Ti–Mo bond lengths are 2.25 Å. Ta is bonded in a linear geometry to two equivalent Mo atoms. Both Ta–Mo bond lengths are 2.33 Å. Mo is bonded in a linear geometry to one Ti and one Ta atom.
TiTa2Mo crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiTa2Mo ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to two equivalent Ta atoms. Both Ti–Ta bond lengths are 2.37 Å. Ta is bonded in a linear geometry to one Ti and one Mo atom. The Ta–Mo bond length is 2.30 Å. Mo is bonded in a linear geometry to two equivalent Ta atoms.