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Nb2VMo crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2VMo ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one V and one Mo atom. The Nb–V bond length is 2.31 Å. The Nb–Mo bond length is 2.23 Å. V is bonded in a linear geometry to two equivalent Nb atoms. Mo is bonded in a linear geometry to two equivalent Nb atoms.
NbVMo2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbVMo2 ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent Mo atoms. Both Nb–Mo bond lengths are 2.29 Å. V is bonded in a linear geometry to two equivalent Mo atoms. Both V–Mo bond lengths are 2.25 Å. Mo is bonded in a linear geometry to one Nb and one V atom.
NbV2Mo crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbV2Mo ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent V atoms. Both Nb–V bond lengths are 2.22 Å. V is bonded in a linear geometry to one Nb and one Mo atom. The V–Mo bond length is 2.19 Å. Mo is bonded in a linear geometry to two equivalent V atoms.