Phase studies of the systems Mn-S, Mn-Se, and MnS-MnSe.
Phase analysis of systems Mn-S, Mn-Se and MnS-MnSe by X ray diffraction techniques, revealing homogeneity ranges
Sigai, A. G.↗
SEARCH · Engineering Papers
Results for “MnS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Phase studies of the systems Mn-S, Mn-Se, and MnS-MnSe
Phase equilibria in Mn-S, Mn-Se and MnS-MnSe systems by X ray diffraction after preparation by annealing
Sigai, A. G.↗
Vapor transport and crystal growth in the mixed system MnS-MnSe
Iodine concentrations, temperature gradients and transport ampules etching effects on mass transport rate and crystal growth of MnS-MnSe- iodine system
Sigai, A. G.↗
Memory behavior of an MNS capacitor.
Metal-/Si nitride/-Si/MNS/ capacitor memory behavior due to high voltage pulses, discussing charge transfer, stored charge location and tunneling conduction
Oconnell, M.↗
A statistical determination of the shape and position of the geomagnetic neutral sheet
Using 2.5-minute average field values from Imp 6, 7, and 8 magnetic field measurements, the standard magnetotail neutral sheet (MNS) model is examined. The best representation for the MNS is found to be an arched surface which crosses the solar magnetospheric equatorial plane on the flanks of the tail about 18 earth radii (ER) from the tail axis; the surface is anchored to the geomagnetic dipole at a hinging distance of 10.5 ER. In addition, the shape and position of the neutral sheet (NS) do not vary significantly with distance down the tail, but the NS is anchored somewhat closer to the earth during disturbed geomagnetic conditions.
Fairfield, D. H.↗
Flight Metal Plasma Thruster (MPT) Development, Qualification, and Thrust Measurement Campaign
A torsional thrust stand, calibrated for impulse bits in the range of 0.1mNs -0.5 mNs, was used to measure impulse bits during two campaigns at the NASA/GRC VF-3 Vacuum test Facility. Metal Plasma Thrusters (MPTs) with targets of Molybdenum, Copper and Stainless Steel (as used in upper stages of launch vehicles that are abandoned in LEO) were tested. This paper describes data from Mo targets (called pucks). The Cu and ss data will be presented elsewhere. Model predictions (based on a simple circuit model and published plasma parameters) were validated by data from the calibrated torsional thrust stand. The Metal Plasma Thruster uses solid metal propellant, hence requires no liquids, gases, flow valves or flow controls and has no moving parts. Total impulse ~5000Ns/U provides orbit raising and drag compensation capability.
Electric Propulsion↗
Flight MPT Development, Qualification and Thrust Measurement Campaign
A torsional thrust stand, calibrated for impulse bits in the range of 0.1mNs -0.5 mNs, was used to measure impulse bits during two campaigns at the NASA/GRC VF-3 Vacuum test Facility. Metal Plasma Thrusters (MPTs) with targets of Molybdenum, Copper and Stainless Steel (as used in upper stages of launch vehicles that are abandoned in LEO) were tested. This paper describes data from Mo targets (called pucks). The Cu and ss data will be presented elsewhere. Model predictions (based on a simple circuit model and published plasma parameters) were validated by data from the calibrated torsional thrust stand. The Metal Plasma Thruster uses solid metal propellant, hence requires no liquids, gases, flow valves or flow controls and has no moving parts. Total impulse ~5000Ns/U provides orbit raising and drag compensation capability.
Electric Propulsion↗
Phase studies in the system manganese sulfide- cadmium sulfide.
Temperature-composition phase diagram of MnS- CdS binary system, noting solid solutions formation mechanisms
Khan, A.↗
Inclusions, grain boundaries and hydrogen attack
Optical metallography, scanning electron microscopy, and X-ray spectrometry were used to study the roles of grain boundaries and inclusions in the nucleation process and fissure growth during the rapid stage of hydrogen attack on 1020 steel in the annealed condition at temperatures up to 600 C and a hydrogen pressure of 10.3 MN/sq m. It is found that intergranular fracture occurred when specimens were fractured at 77 K after hydrogen exposure and that macroscopically observable fissures formed due to the coalescence of bubbles which nucleated at inclusions in grain boundaries. The inclusions are tentatively identified as MnS.
Shih, H. M.↗
Infrared absorption spectra of metal carbides, nitrides and sulfides
The infrared absorption spectra of 12 kinds of metal carbides, 11 kinds of nitrides, and 7 kinds of sulfides, a total of 30 materials, were measured and the application of the infrared spectra of these materials to analytical chemistry was discussed. The measurements were done in the frequency (wave length) range of (1400 to 400/cm (7 to 25 mu). The carbides Al4C3, B4C, the nitrides AlN, BN, Si3N4, WB, and the sulfides Al2S3, FeS2, MnS, NiS and PbS were noted to have specific absorptions in the measured region. The sensitivity of Boron nitride was especially good and could be detected at 2 to 3 micrograms in 300 mg of potassium bromide.
Kammori, O.↗
Possible roles of manganese redox chemistry in the sulfur cycle
Sulfate reducing bacteria (SRB) are very potent MnO2 reducers by virtue of their sulfide production: H2S reacts rapidly with MnO2 to yield Mn(2), elemental sulfur, and water. In manganese rich zones, Mn cycles rapidly if sulfate is present to drive the reduction and the MnO2 precipitates and sinks into anaerobic zones. The production of sulfide (by organisms requiring organic carbon compounds) to reduce manganese oxides might act to couple the carbon and sulfur cycles in water bodies in which the two cycles are physically separated. Iron has been proposed for this provision of reducing power by (Jorgensen, 1983), but since MnS is soluble and FeS is very insoluble in water, it is equally likely that manganese rather than iron provides the electrons to the more oxidized surface layers.
Nealson, K. H.↗
Lunar and Planetary Science XXXVI, Part 6
Contents include the following: A Model for Multiple Populations of Presolar Diamonds. Characterization of Martian North Polar Geologic Units Using Mars Odyssey THEMIS Data. Effect of Flow on the Internal Structure of the Martian North Polar Layered Deposits. Elemental Abundance Distributions in Basalt Clays and Meteorites: Is It a Biosignature? Early Results on the Saturn System from the Composite Infrared Spectrometer. NanoSIMS D/H Imaging of Isotopically Primitive Interplanetary Dust Particles. Presolar (Circumstellar and Interstellar) Phases in Renazzo: The Effects of Parent Body Processing. Catastrophic Disruption of Hydrated Targets: Implications for the Hydrated Asteroids and for the Production of Interplanetary Dust Particles. Chemical and Mineralogical Analyses of Particles from the Stratospheric Collections Coinciding with the 2002 Leonid Storm and the 2003 Comet Grigg-Skjellerup Trail Passage. An Analysis of the Solvus in the CaS-MnS System. ESA s SMART-1 Mission at the Moon: First Results, Status and Next Steps. Europa Analog Ice-splitting Measurements and Experiments with Ice-Hunveyor on the Frozen Balaton-Lake, Hungary. Chromium on Eros: Further Evidence of Ordinary Chondrite Composition. Dust Devil Tracks on Mars: Observation and Analysis from Orbit and the Surface. Spatial Variation of Methane and Other Trace Gases Detected on Mars: Interpretation with a General Circulation Model. Mars Water Ice and Carbon Dioxide Seasonal Polar Caps: GCM Modeling and Comparison with Mars Express Omega Observations. Component Separation of OMEGA Spectra with ICA. Clathrate Formation in the Near-Surface Environment of Titan. Space Weathering: A Proposed Laboratory Approach to Explaining the Sulfur Depletion on Eros. Sample Collection from Small Airless Bodies: Examination of Temperature Constraints for the TGIP. Sample Collector for the Hera Near-Earth Asteroid Sample Return Mission. A Rugged Miniature Mass-Spectrometer for Measuring Aqueous Geochemistry on Mars. Martian and Lunar Pyroxene Microstructures Studied by Single-Crystal X-Ray Diffraction.
Source record↗
Constraints on the Neutron Star and Inner Accretion Flow in Serpens X-1 Using Nustar
We report on an observation of the neutron star low-mass X-ray binary Serpens X-1, made with NuSTAR. The extraordinary sensitivity afforded by NuSTAR facilitated the detection of a clear, robust, relativistic Fe K emission line from the inner disk. A relativistic profile is required over a single Gaussian line from any charge state of Fe at the 5 sigma level of confidence, and any two Gaussians of equal width at the same confidence. The Compton back-scattering "hump" peaking in the 10-20 keV band is detected for the first time in a neutron star X-ray binary. Fits with relativistically blurred disk reflection models suggest that the disk likely extends close to the innermost stable circular orbit (ISCO) or stellar surface. The best-fit blurred reflection models constrain the gravitational redshift from the stellar surface to be ZnS (is) greater than 0.16. The data are broadly compatible with the disk extending to the ISCO; in that case,ZnS(is) greater than 0.22 and RNS (is) less than12.6 km (assuming MnS = 1.4 solar mass and a = 0, where a = cJ/GM2). If the star is as large or larger than its ISCO, or if the effective reflecting disk leaks across the ISCO to the surface, the redshift constraints become measurements. We discuss our results in the context of efforts to measure fundamental properties of neutron stars, and models for accretion onto compact objects.
accretion↗
A New Look at Aubrites: Investigating 3D Modal Mineralogy with X-Ray Computed Tomography
The aubrites (approximately 30 known meteorites) are a unique group of differentiated meteorites that formed on asteroids with oxygen fugacities (ƒO2) from approximately 2 to approximately 6 log units below the iron-wustite buffer. At these highly reduced conditions, elements deviate from the geochemical behavior exhibited at terrestrial ƒO2, forming FeO-poor silicates and exotic sulfides. While previous studies have described the petrology and 2D modal abundances of aubrites, this work investigates the 3D modal mineralogies of silicate, metal, and sulfide phases in aubrite samples, which are then compared to the available 2D data. In addition to 3D modal mineralogies, we have examined the geochemistry of fourteen aubrites, including mineral major-element compositions, bulk-rock compositions, and oxygen isotopic compositions to understand their formation and evolution at extreme ƒO2 conditions. We utilize X-ray computed tomography (XCT) to non-destructively analyze the distribution and abundances of mineral phases in aubrites and locate composite clasts of sulfide grains for future analytical study. In order to better constrain elemental behavior under reduced conditions, we specifically target minerals phases that comprise moderately volatile elements (i.e. oldhamite [CaS], caswellsilverite [NaCrS2] and djerfisherite [K6Na(Fe,Cu,Ni)25S26Cl]) as it has been shown that their geochemical behavior changes as a function of ƒO2. Currently, we have produced 3D scans of the Norton County aubrite. The results of the XCT data have allowed for the determination of the abundances of silicate groundmass (i.e., enstatite, forsterite, albite, and diopside), light (based on electron density) sulfides (i.e. alabandite [MnS] and daubréelite [FeCr2S4]), heavy (based on electron density) sulfides (i.e., troilite [FeS]), and Fe,Ni metal by segmenting a density histogram in Volume Graphics Studio software. XCT scans of additional aubrites are underway. By combining the 3D representation of the exotic phases found in aubrites with existing 2D characterizations, we are able to better determine modal abundances. By integrating 3D and 2D modal abundances and geochemistry, we can ultimately better constrain aubrite petrogenesis and elemental partitioning under reduced conditions. Furthermore, application of this new 3D approach offers the opportunity to identify and select clasts for future study prior to cutting the sample, which will minimize sample loss of this precious material.
Wilbur, Zoe↗
On the 2018 Outburst of the Accreting Millisecond X-Ray Pulsar Swift J1756.9-2508 As Seen with NICER
We report on the coherent timing analysis of the 182 Hz accreting millisecond X-ray pulsar SwiftJ1756.92508during its 2018 outburst as observed with the Neutron Star Interior Composition Explorer (NICER). Combiningour NICER observations with Rossi X-ray Timing Explorer observations of the 2007 and 2009 outbursts, we alsostudied the long-term spin and orbital evolution of this source. We find that the binary system is well describedby a constant orbital period model, with an upper limit on the orbital period derivative of Pb < 7.4 ´ 10-13 ss1.Additionally, we improve upon the source coordinates through astrometric analysis of the pulse arrival times,finding R.A.=17h56m57 18±0 08 and decl.=25°0627 8±3 5, while simultaneously measuring thelong-term spin frequency derivative as n = -7.3 ´ 10-16 Hzs1. We briefly discuss the implications of thesemeasurements in the context of the wider population of accreting millisecond pulsars. We reported on the coherent timing analysis of the 2018 outburst of Swift J1756 as observed with NICER. Consistent with analyses of the previous outbursts (Krimm et al. 2007b; Patruno et al. 2010), we find that the X-ray pulsations have energy dependent amplitudes; the fractional amplitude of the fundamental increases with energy, whereas the fractional amplitude of the harmonic shows a slight decline with energy. This energy dependent behavior is not unusual in AMXPs (Patruno & Watts 2012) and can be interpreted in terms of the thermal emission from the stellar hotspot and reprocessing in the accretion column (e.g., Gierliński et al. 2002; Ibragimov & Poutanen 2009). The pulse arrival times of the 2018 outburst are well described by a timing model consisting of a circular orbit with a constant spin frequency. The pulse phases with respect to this model do not show spurious residuals with time or orbital phase, and no evidence is found that the pulse arrival times exhibit an additional delay associated with passing through the gravitational well of the companion star (Shapiro delay). We note, however, that the expected Shapiro delay is given as (Shapiro et al. 1971) Equation (5) where Φ is the orbital phase, G is the gravitational constant, c is the speed of light, and i is the inclination. Even for the maximum allowed companion mass, ${M}_{C}=0.030\,{M}_{\odot }$ (Krimm et al. 2007b, but see Section 4.2 for more details) and an inclination of 90°, the largest delay we can expect is only 4 μs. As this time-delay is smaller than the uncertainty on our phase residuals by nearly two orders of magnitude (see Figure 1), we are not sensitive to Shapiro delays in Swift J1756. Comparing our measurements for the 2018 outburst with those of the 2007 and 2009 outbursts as observed with RXTE, we analyzed the long-term evolution of this source. We found that the binary system is consistent with having a constant orbital period and that the pulsar shows a spin frequency derivative of $\dot{\nu }=-7.3\times {10}^{-16}\,\mathrm{Hz}\,{{\rm{s}}}^{-1}$. 4.1. Spin-down Evolution The long-term spin frequency derivative measured in Swift J1756 is of the same order as the spin frequency derivatives measured in other AMXPs (Hartman et al. 2008; Patruno 2010; Riggio et al. 2011). This frequency change is most likely driven by the neutron star's loss of rotational energy. If so, then the spin-down luminosity is given as Equation (6) where I represents the neutron star moment of inertia. The long-term spin-down of a neutron star is usually assumed to be dominated by the braking torque associated with a spinning magnetic field. Assuming this mechanism is responsible for the observed spin-down in Swift J1756, we can compute the magnetic dipole moment as (Spitkovsky 2006) Equation (7) where α is the misalignment angle between the rotational and magnetic poles. Considering α = 0°–90°, we then find a magnetic field strength of $B\simeq (4\mbox{--}6)\times {10}^{8}$ G at the stellar magnetic poles. This magnetic field strength estimate is in line with those obtained for other accreting millisecond pulsars (see Mukherjee et al. 2015 and references therein). 4.2. Orbit Evolution The observed long-term binary evolution of Swift J1756 is consistent with this source having a constant orbital period and a lower limit on the evolutionary timescale of Equation (8) Binary evolution theory predicts that systems of this type evolve due to angular momentum loss through gravitational radiation (Kraft et al. 1962; Rappaport et al. 1982; Verbunt 1993). For conservative mass transfer, the binary period derivative is given by di Salvo et al. (2008), Equation (9) where MNS is the neutron star mass, $q={M}_{C}/{M}_{\mathrm{NS}}$ is the binary mass ratio, and −1/3 < n < 1 is the mass–radius index of the companion star. Depending on the source inclination, Krimm et al. (2007b) derived a companion mass of ${M}_{C}\,=0.007\mbox{--}0.022\,{M}_{\odot }$ for a neutron star mass of 1.4 ${M}_{\odot }$. For a neutron star mass of 2.2 ${M}_{\odot }$, the allowed range increased to ${M}_{C}=0.009\mbox{--}0.030\,{M}_{\odot }$. In both cases, they assumed an upper limit on the inclination of i < 85°, motivated by the fact that Swift J1756 does not show eclipses in its light curve. Accounting for the extreme cases of stellar masses and n, the binary may either be contracting or expanding. In either case, however, the rate of change is limited to $| {\dot{P}}_{b}| \lesssim 7\times {10}^{-14}$ s s−1, which is well below the upper limit obtained in this work. Although the binary evolution timescale we obtain for Swift J1756 is consistent with theory, it is worth noting that this is not generally true for low-mass X-ray binaries (see Patruno et al. 2017, for a comprehensive discussion). The AMXP SAX J1808.4–3658, in particular, has been found to evolve on a much shorter timescale, with a first derivative on the orbital period of $3.5\times {10}^{-12}$ s s−1 (Hartman et al. 2008; Patruno et al. 2012; Sanna et al. 2017a). Two models have been proposed to explain this discrepancy: highly nonconservative mass transfer due to irradiation of the companion star by the pulsar (di Salvo et al. 2008; Burderi et al. 2009), and spin–orbit coupling in the companion star (Hartman et al. 2008, 2009). While the latter depends on the companion star, and may vary from source to source, the former should operate in all AMXPs (see also Patruno 2017; Sanna et al. 2017c), including Swift J1756. The spin-down luminosity impinging on the companion star can be estimated as Equation (10) where ${\dot{E}}_{\mathrm{abl}}$ is the ablation luminosity, RL2 is the Roche lobe radius of the companion (Eggleton 1983), and a the binary separation. The irradiation fraction is $f={\dot{E}}_{\mathrm{abl}}/{\dot{E}}_{\mathrm{sd}}$, which, accounting for the range of allowed neutron star and companion masses, evaluates to f = 0.15%–0.35%. The associated mass loss for the companion is given by Equation (11) such that, assuming an efficiency of η = 100%, ${\dot{M}}_{C}\,\sim -3\times {10}^{-10}\,{M}_{\odot }$ yr−1. The effect of this mass loss on the orbital period follows through the relation (Frank et al. 2002) Equation (12) giving a period derivative due to mass loss of ${\dot{P}}_{b,\mathrm{ML}}\,=5\times {10}^{-12}$ s s−1. This value is well above our limit on the period derivative. Hence, in order for this mechanism to be consistent with our observations of Swift J1756, the efficiency at which the companion star converts the incident luminosity into mass loss must be η < 15%. This value is very different from the 40% required in SAX J1808.4–3658 (Patruno et al. 2016) and is instead in line with the <5% efficiency determined for IGR J00291+5934 (Patruno 2017). This work was supported by NASA through the NICER mission and the Astrophysics Explorers Program, and made use of data and software provided by the High Energy Astrophysics Science Archive Research Center (HEASARC). P.B. was supported by an NPP fellowship at NASA Goddard Space Flight Center. D.A. acknowledges support from the Royal Society.
Bult, Peter↗
Long-Duration Wear Testing of the ASTRAEUS Thruster, Phase I: 50 kg Xe Throughput
The thruster component of the Ascendant Sub-kW Transcelestial Electric Propulsion System successfully completed a propellant throughput demonstration of 50 kg Xe. The thruster was operated for a total of 3,287 h, of which 97.9% was spent at 300 V – 1000 W, and generated 790 kN-s of total impulse. Thrust, telemetry, and temperature measurements periodically recorded at four operating conditions spanning 200 – 500 V and 200 – 1000 W revealed constant performance across the full test duration. High-fidelity plasma simulations of the erosion of the thruster’s downstream faces suggest a theoretical lifetime capability of >30 kh, corresponding to propellant throughput of >450 kg Xe and a total impulse of >7 MNs, at the 300 V – 1000 W operating condition. The test was voluntarily paused after 50 kg Xe throughput to take these erosion measurements before the test was resumed at a different operating condition.
Goebel, Dan↗
Long-Duration Wear Testing of the ASTRAEUS Hall Thruster, Phases II & III: 72 kg Xe Throughput & 1.2 MN-s Total Impulse
The thruster component of the Ascendant Sub-kW Transcelestial Electric Propulsion System successfully completed a propellant throughput demonstration of 72 kg Xe in a long-duration wear test planned to eventually exceed 100 kg. The thruster has been operated for a total of 5450 h over three operating conditions: 3287 h at 300 V – 1000 W, 1745 h at 500 V – 1000 W, and 417 h at 400 V – 600 W. A total of 1.2 MN-s of impulse has been demonstrated to date. Thrust, telemetry, and temperature measurements periodically recorded at four operating conditions spanning 200 – 500 V and 200 – 1000 W revealed constant performance across the full test duration. The erosion of the downstream faces of the thruster was observed to be higher than anticipated after the first 5032 h of thruster operation. This issue was traced to the application of sub-nominal magnetic field strengths throughout the LDWT, caused by an electrical-related ground-support equipment issue, which resulted in a downstream shift of the discharge plasma and enhanced erosion of the thruster’s pole covers. Nevertheless, the thruster performance and operational behaviour remained unaffected. High-fidelity plasma simulations of the erosion of the thruster’s downstream faces, supported by prior short-duration wear testing, suggest a theoretical lifetime capability of >30 kh, corresponding to propellant throughput of >450 kg Xe and a total impulse of >7 MNs, at the 300 V – 1000 W operating condition. The test was voluntarily paused after 68 kg Xe and 72 kg Xe throughput, respectively, to take these erosion measurements at the 500 V and 400 V operating conditions before the test was resumed at a different operating condition.
Goebel, Dan↗
NGHT-1X Pole Cover Erosion Measurements on Xenon and Krypton
Northrop Grumman’s NGHT-1X Hall thruster has completed the Engineering Model development phase and is progressing towards qualification and flight unit build and test. First flight of the NGHT-1X will occur in 2025 on Northrop Grumman’s Mission Extension Pod spacecraft. The NGHT-1X is a state of the art 1 kW-class Hall thruster which implements magnetic shielding to increase thruster lifetime by reducing discharge channel wall erosion. As a result, like other magnetically shielded Hall thrusters, the NGHT-1X exhibits erosion of the front-facing pole covers, which is the primary life-limiting failure mode of the thruster. During the development of the NGHT-1X, several Short Duration Wear Tests were performed to characterize erosion rates and forecast compliance to lifetime requirements in advance of the ongoing full-life Long Duration Wear Test. Erosion rate measurements from four tests at different operating conditions are presented and comparisons made between tests. Two tests were performed in the same background pressure environment at 700 W 300 V and 900 W 350 V throttle conditions, both using xenon propellant. A third test was performed again at 900 W 350 V with xenon propellant, but at a lower background pressure. Lastly, to assess the viability of potential future applications with alternate propellants, a wear test was conducted using krypton propellant at 900 W 250 V, the results of which are presented here. The erosion measurements from each test are compared with one another, and insights are discussed. All xenon wear tests support a thruster lifetime capability in excess of 16,000 hours, or 3.3 MNs at 900 W 350 V, which supports the Mission Extension Pod mission with margin as well as many other potential applications on small- to medium-sized spacecraft.
Hall↗