Materials Data on Mn2V3(AgO4)3 by Materials Project
V3Mn2(AgO4)3 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. V5+ is bonded to four equivalent O2- atoms to form VO4 tetrahedra that share corners with four equivalent MnO6 octahedra. The corner-sharing octahedral tilt angles are 45°. All V–O bond lengths are 1.76 Å. Mn3+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent VO4 tetrahedra. All Mn–O bond lengths are 2.08 Å. Ag1+ is bonded in a distorted body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.56 Å) and four longer (2.62 Å) Ag–O bond lengths. O2- is bonded in a 4-coordinate geometry to one V5+, one Mn3+, and two equivalent Ag1+ atoms.