Materials Data on Mn2Ru(CN)6 by Materials Project
Ru(Mn(CN)3)2 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one ruthenium molecule and one Mn(CN)3 sheet oriented in the (0, 0, 1) direction. In the Mn(CN)3 sheet, Mn2+ is bonded to six equivalent N3- atoms to form edge-sharing MnN6 octahedra. There are three shorter (2.25 Å) and three longer (2.26 Å) Mn–N bond lengths. C+1.33+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.19 Å. N3- is bonded in a distorted trigonal planar geometry to two equivalent Mn2+ and one C+1.33+ atom.
36 MATERIALS SCIENCE↗