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TiMoMn2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TiMoMn2 ribbons oriented in the (0, 1, 0) direction. Ti is bonded in a linear geometry to two equivalent Mn atoms. Both Ti–Mn bond lengths are 2.35 Å. Mo is bonded in a linear geometry to two equivalent Mn atoms. Both Mo–Mn bond lengths are 2.86 Å. Mn is bonded in a linear geometry to one Ti and one Mo atom.
Ti2MoMn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ti2MoMn ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a distorted linear geometry to one Mo and one Mn atom. The Ti–Mo bond length is 2.23 Å. The Ti–Mn bond length is 2.62 Å. Mo is bonded in a linear geometry to two equivalent Ti atoms. Mn is bonded in a linear geometry to two equivalent Ti atoms.