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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Bio-markers and the search for extinct life on Mars

In order to predict what biomarkers could be used on Mars, several biomarkers, or key signatures, of extinct life on earth are identified. Some of these biomarkers which may be applicable to Mars include reduced carbon and nitrogen compounds, CO3(2-), SO4(2-), NO3(-), Mg, Mn, Fe, and the isotopic ratios of C, N, and S. It is suggested that a fully equipped Mars rover might be able to perform analyses to measure most of these biomarkers while on the Martian surface.

Schwartz, D. E.↗

Relative Detectability of Iron-Bearing Phases for the Mars 2020 Sherloc Deep UV Raman Instrument: 1. Focusing on Carbonates

A deep ultraviolet (DUV) Raman and fluorescence instrument is a surface standoff instrument mounted on the robotic arm of the Mars 2020 (M2020) rover Perseverance, and it is a key element of the Scanning Habitable Environments with Luminescence for Organics and Chemicals (SHERLOC) investigation [1]. Measurement and science objectives include mineralogical and organic images (~100 μm/pixel) that map sub-millimeter spatial distributions and characterization of primary and secondary minerals, potential organics, and their interaction/alteration products. The results of data analysis pertain to understanding igneous and alteration processes on Mars through time, assessing habitability, evidencing in situ biosignatures, and, along with results from other Perseverance instruments, selecting samples to cache for Mars sample return. Acceptance of the SHERLOC investigation for the NASA M2020 mission [2] created a need for Mars-relevant DUV Raman spectra, particularly for inorganic materials [e.g., 3, 4]. As reported previously [e.g., 4, 5], phases with Fe cations as essential elements (e.g., siderite (FeCO3) and ankerite (FeCa(CO3)2) for carbonates) significantly hinder detection by DUV Raman because of intense absorption of incident and scattered DUV laser radiation by Fe cations. We report here the relative detectability of carbonates (Mg,Ca,Fe,Mn)CO3 by DUV Raman using a SHERLOC analog laboratory instrument.

R V Morris↗

Chondrules and matrix in the Ornans CO3 meteorite - Possible precursor components

Bulk compositions of 17 chondrules and one sample of matrix from CO3 Ornans were determined by instrumental neutron activation analysis. Chondrule precursor components deduced from chondrule compositions are characterized by: (1) common and slightly volatile siderophiles, Cr and chalcophiles, (2) refractory lithophiles and Na, (3) Mn, Si and modal pyroxene, and (4) FeO and olivine. Component 4 may be closely related to matrix material. Precursor components have now been inferred for OC, EH, CV, CM and CO chondrules. An MN- and Si-rich component occurs exclusively among carbonaceous chondrite chondrules. Although there are significant intergroup differences, common to chondrules in all chondrite groups are refractory-lithophile-rich, common-siderophile-rich, and (with the exception of EH) common-lithophile-rich components. This indicates that the siderophile/lithophile and refractory lithophile/common lithophile fractionations recorded in chondrite whole-rocks were established prior to chondrule formation at all nebular locations.

Rubin, Alan E.↗